The Dow Chemical Company

Dow Global Technolgoies LLC

Dow Technology Investments LLC

Rohm & Haas Electronic Materials LLC

Union Carbide Chemicals & Plastics Technology Corporation

The Firestone Tire & Rubber Company

Christopher P Christenson

Martin C Cornell

Alan K Schrock

Harvey E Andresen

Charles William Lipp

Victor R Fey

John R Mayer

Michael L Hutchison

Thomas J Kling

Laurence G Britton

Michael J Rangitsch

Charles W Lipp

Zenon Lysenko

John L Burba, Iii

Ralph D Priester, Jr

Robert E O'Neill

Gary M McNamee

Wayne R Willkom

Kyung W Suh

Jerry E White

Mark F Sonnenschein

Clark H Cummins

David H West

Jozef Bicerano

Deodatta Vinayak Shenai-Khatkhate

Chung Poo Park

John G Pendergast, Jr

Hua Bai

Martin H Tusim

Ravindra S Dixit

Fred L Vance, Jr

Bob R Maughon

Robert A Ware

Curtis D Modtland

Artashes Amamchyan

Rafael E Guerra

Kenneth M Crouch

Robert F Polcari

John Michael Maher

Francois M Casati

Gary Lee Jialanella

David H Bank

Bruce D Hook

Robert B Turner

Marvin L Dettloff

Sudhakar Balijepalli

Ha Q Pham

Timothy Charles Frank

Kenneth A Burdett

Sten A Wallin

Valeriy V Ginzburg

Matthias Schaefer

Thomas M Knobel

Andrew F Sandford

Lirong Zhou

Paul J Moses

Hanno R Van Der Wal

Anil Mehta

Istvan Lengyel

Avis L McCrary

Benjamin L Wendt

Wilfred C Meyer

Toni Ristoski

Eric E Cole

Walter W Henslee

P J Thomas

Peter A Doty

Richard Dicran Varjian

Steve A Sims

Arthur E Read, Jr

Dan Tirtowidjojo

Joseph H Tazewell

Joey W Storer

Edgar F Hoy

Stanley J Morrow

Henri J M Gruenbauer

Jean Paul Chauvel, Jr

Craig J Carriere

John S Lindsey

Sean C Tobin

Steve Gluck

Manuel Gonzales, Jr

Fabio Aguirre

Zoran R Jovanovic

Mark Cox

Andrea H Hazlitt

Susan K Falcone

Stanley F Simpson

Frank Koester

Betty J Smith

Sunil K Chaudhary

John W Faller

Celio Lume Pereira

Ralph H Delaune

Glenn Lord

Christine Lundstroem

Hans H Schwantje

Annett Horn

Josef Bicerano

Marvin L Dettlof

An apparatus for continuously manufacturing organometallic compounds is provided where the apparatus has a source of a first reactant stream wherein the first reactant comprises a metal; a source of a second reactant stream; a laminar flow contacting zone for cocurrently contacting the first reactant stream and the second reactant stream; a mixing zone comprising a turbulence-promoting device; and a heat transfer zone.

Organometallic compound preparation

A method of continuously manufacturing organometallic compounds is provided where two or more reactants are conveyed to a reactor having a laminar flow contacting zone, a heat transfer zone, and a mixing zone having a turbulence-promoting device; and causing the reactants to form the organometallic compound.

The invention is an adhesive composition comprising: a) an isocyanate functional polyether base prepolymers having a z molecular weight average (Mz) of about 10,000 to about 80,000 g/mole; a carbon black having an average oil absorption number of at least about 80 to at most about 400 cubic centimeters of dibutyl phthalate per 100 grams of the carbon black; (c) reactive silicon in an amount from about 0.001% to about 10% by weight of the adhesive composition; and (d) one or more catalysts for the reaction of isocyanate with hydroxyl groups. The adhesive compositions of the invention surprisingly may have improved sag performance (i.e., decreased sag) when heated, while also making them more easily pumped.

Vehicular glass adhesive and method of adhering said glass

A gas mixer () for mixing a first gas stream with a second gas stream includes an impact labyrinth () in the first gas stream having structures (), e.g., corrugated walls, forming a tortuous path through which the first gas stream must pass en route to a mixing point () in the gas mixer. The labyrinth fosters ignition of particles entrained in the first gas stream. Elongate, straight pipes () receive the first gas stream from the impact labyrinth () and carrying the first gas stream to the mixing point () the pipes () are positioned with a vessel () carrying the second gas stream. The pipes () have openings which are substantially aligned with the flow direction of the second gas stream at the mixing point () thereby introducing the first gas stream into the second gas stream in a low shear manner.

Low shear gas mixer

A method of mixing an oxygen gas with a hydrocarbon-containing gas includes the steps of wet scrubbing the oxygen gas in a wet scrubber, supplying oxygen gas from the wet scrubber to a gas mixer and mixing the oxygen gas with the hydrocarbon-containing gas in the gas mixer. Wet scrubbers for use in the method may take various forms, including packed-tower, bubble cap, and sparger-type wet scrubbers. The removal of the particulate matter reduces the risk of ignition of the hydrocarbon-containing gas in the gas mixer. The use of a wet scrubber in the oxygen supply line overcomes many problems currently faced with screen and filters, as per current practice.

Wet scrubbing for removing particulate solids from oxygen supply line

A hydrocarbon-containing gas is mixed with an oxygen-containing gas in a gas mixer in the presence of a water mist. The water mist surrounds and contacts entrained particles in either the oxygen-containing gas stream or the hydrocarbon-containing gas stream. The water acts to suppress and prevent ignition of the hydrocarbon gas in the mixer by serving as a sink for heat created by energetic collisions between such particles and structures within the gas mixer. The water mist also acts to quench ignition caused by such collisions. The water mist can be introduced into the gas mixer in a number of different configurations, including via nozzles injecting a mist into a hydrocarbon gas manifold or an oxygen gas manifold, nozzles placed within the gas mixer adjacent to ends of the oxygen supply pipes, and nozzles placed coaxially within the oxygen supply pipes in the gas mixer.

Hydrocarbon/oxygen industrial gas mixer with water mist

A gas mixer is disclosed which includes a vessel () (e.g., pipe) containing a stream () of a first hydrocarbon-containing gas. The mixer includes a hollow pipe () located internal to the vessel containing a stream of a second gas, e.g., an oxygen-containing gas stream such as a stream of pure oxygen gas or air enriched with oxygen. The internal pipe further includes a mixer tip () at the peripheral end thereof. The mixer tip includes a body having an internal passage for conducting the second gas out of the pipe and an opening introducing the second gas stream into the first gas stream in a radial plane at an acute angle relative to the longitudinal axis of the pipe. The pipe further includes a deflector () on its external surface in longitudinal alignment with the opening of the mixer tip. The deflector serves to deflect any entrained particles within the first gas stream away from the mixing zone where the two streams mix, minimizing the risk of ignition of the hydrocarbon-containing gas.

Oxygen/hydrocarbon rapid (high shear) gas mixer, particularly for the production of ethylene oxide

Process and apparatus for reducing organic content of brine comprising subjecting a brine solution to at least two purification treatments selected from electrochemical treatment, chlorinolysis, or other chemical oxidation treatment, carbon adsorption, extraction, biological treatment and chrystallizing treatment; wherein the organic content of purified brine is sufficiently low to enable sense of the purified brine in an industrial process.

Brine purification

A hydrocarbon-containing gas is mixed with an oxygen gas in a gas mixer in the presence of coarse water droplet environment, e.g., a 'rainy' or 'driving rainstorm' environment in which the water droplets generally have a size greater than 200 microns SMD. The water droplets surround and contact entrained particles in either the oxygen gas stream or the hydrocarbon-containing gas stream. The water acts to suppress, prevent and quench ignition of the hydrocarbon gas in the mixer which would otherwise be caused by energetic collisions between such particles and structures within the gas mixer. In one configuration the gas mixer includes water pipes having coarse water droplet-producing nozzles at the peripheral end thereof concentrically located within oxygen supply pipes. Additionally, nozzles introduce coarse water droplets into a pipe carrying the hydrocarbon gas and forming a mixing chamber for the hydrocarbon and oxygen gases.

Hydrocarbon/oxygen industrial gas mixer with coarse water droplet environment to reduce ignition potential

Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain &#x3b1;-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain &#x3b1;,&#x3c9;-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an &#x3b1;,&#x3c9;-hydroxy acid or &#x3b1;,&#x3c9;-hydroxy ester, which may be (trans)esterified with a polyol to form an &#x3b1;,&#x3c9;-polyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an &#x3b1;,&#x3c9;-amino acid or &#x3b1;,&#x3c9;-amino ester, which may be (trans)esterified to form an &#x3b1;,&#x3c9;-polyester polyamine.

Integrated chemical processes for industrial utilization of seed oils

Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain &#x3b1;-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain &#x3b1;,&#x3c9;-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an &#x3b1;,&#x3c9;-hydroxy acid or &#x3b1;,&#x3c9;-hydroxy ester, which may be (trans)esterified with a polyol to form an &#x3b1;,&#x3c9;polyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an &#x3b1;,&#x3c9;-amino acid or &#x3b1;,&#x3c9;-amino ester, which may be (trans)esterified to form an &#x3b1;,&#x3c9;polyester polyamine.

Integrate chemical processes for industrial utilization of seed oils

A polyurethane-polymer composition suitable for preparing a lightweight tire support includes at least one isocyanate, at least one polyol, and at least one chain extender. A polyurethane-polymer composition can also include an additive such as a catalyst, a filler, a surfactant, a colorant, and a mold-release agent. A lightweight tire support can be prepared from a polyurethane-polymer composition by, for example, reaction injection molding. Such a tire support desirably has temperature stability and load-bearing capability.

Lightweight tire support and composition and method for making a tire support

A transparent polyurethane-hydrogel composition includes a reaction product in aqueous solvent of a prepolymer and a water-soluble crosslinker in the substantial absence of organic solvent, and such a composition can be prepared by admixing a prepolymer and a water-soluble crosslinker in aqueous solvent and in the substantial absence of organic solvent. A prepolymer is present in an amount of no greater than about 5 weight percent based on total weight of all hydrogel components. The prepolymer is generally prepared from at least one water-soluble polyol and an isocyanate. A water-soluble crosslinker generally has a crosslinker functionality of at least 2 and is selected to provide a site ratio of initial isocyanate to crosslinker (i.e., moles NCO&#xd7;functionality/moles crosslinker&#xd7;functionality) of at least about 1.5 and no greater than about 2.6. In one embodiment, a crosslinker is effective to react with and solubilize residual isocyanate concurrently with the reaction between prepolymer and crosslinker. A transparent polyurethane-hydrogel composition has desirable gel physical properties and is useful for an air-freshener application.

Transparent polyurethane-hydrogel composition, method of making transparent polyurethane-hydrogel composition, and air-freshener application

The invention is a catalytic device comprised of a catalyst support of fused ceramic grains and a catalyst that is surface-bound to at least a portion of the ceramic grains, incorporated into at least a portion of the ceramic grains or combinations thereof, wherein the grains and catalyst form a surface structure that has a box counting dimension of greater than 1.00 or the box counting dimension has at least one step change when measured from a box size 'd' of at least about 1 micrometer to at most about 1 millimeter. The invention is particularly useful in making a catalytic converter or catalytic converter-soot trap.

Catalytic devices and method of making said devices

A process is disclosed for producing resilient polyurethane foams by foaming an organic polyisocyanate, an iso-cyanate-reactive compound and a fusible polymer. The improvement in the hardness of the foams is achieved without adversely affecting the other properties of the foams, such as tensile strength and elongation.

Polyurethanes containing dispersed crystalline polyesters

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Lake Jackson, TX, United States of America

Christopher P Christenson