Phosphonics Limited

Other

Christopher North

Paul M Murray

Robin Wilkes

Laura C Forfar

Alexander Watson

Nicholas P Taylor

A substantially insoluble compound having a polysaccharide backbone which is derivatised at one or more of its hydroxyl groups with a ligand (L) bound to the sugar moiety by a sulphur atom which may be tailored according to a wide range of applications. The compound is useful as a catalyst and in removal of contaminants from a feed containing particularly metal ions.

Functionalised compounds

A process for the selective removal of a component from a liquid phase and subsequently returning the component to a liquid phase is disclosed. A novel compound of formula (I) [SUP]-[[L]-[G]]a (I) in which L is a linking group, G is an aryl group having a leaving group LG selected from Cl, Br, I, sulfonate such as triflate, a diazo group, a nitrile, an ester and an alkoxy group and substituent Q is selected from H, NR2, OR, CO2R, F, Cl, NO2 CN and SUP is a support having a plurality of groups -[L]-[G] bound to the support is contacted with the liquid phase to bind the component to the compound I thereby forming a captured component which is separated from and may be returned to the liquid phase. The compound I is especially useful in binding homogeneous catalysts to remove it from a reaction medium and selectively returning the catalyst to the reaction medium at a later stage. The compound is particularly useful for cross-coupling reactions, for example in Suzuki reactions.

Process for the removal and return of a catalyst to a liquid phase medium

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Oxford, United Kingdom

Christopher North