Schlumberger Technology Corporation

Christopher Daeffler

Mohan Kanaka Raju Panga

Carlos Abad

Dominic Joseph Brady

Dominic Vincent Perroni

Xiangdong Qiu

Andrey Yakovlev

Bipin Jain

Olga Vladimirovna Nevvonen

Li Jiang

Balkrishna Gadiyar

Anatoly Vladimirovich Medvedev

Sergey Makarychev-Mikhailov

Philippe Enkababian

Juan-Carlos Santamaria

Jack Li

Anatoly Medvedev

Kong Teng Ling

Xuehao Tan

Merlyn Xavier Pulikkathara

Kinga Hendum

Nirupama Vaidya

Julia Fernandez Del Valle

Elvin Yusifzada

Ziad Al-Jalal

Olga Nevvonen

Tausif Khizar Ahmed

Annie Yi Sun

Treatment of subterranean formations using acid blends that contain alcohols and surfactants is described herein. The alcohols and surfactants are used together to retard the activity of acid on acid-susceptible species of rock formations.

Single-phase alcohol-based retarded acid

A method includes placing, via a bailer, a slurry into a wellbore to deposit a slurry downhole. The slurry includes a solids mixture and a fluid. The method also includes terminating placement of the slurry for a period of time. A viscous pill inhibits settling of the solids mixture, and the slurry displaces the viscous pill in contact with a surface of a screen.

High solids content fluid techniques

Methods for shortening the waiting-on-cement (WOC) time during primary and remedial cementing operations are disclosed. A fluid pill is injected into the wellbore that comprises reactants. The reaction is exothermic and heat is conducted into the cement sheath, thereby accelerating hydration and shortening the time necessary for the slurry to set and harden.

Methods for shortening waiting-on-cement time in a subterranean well

Described herein are methods for treating a subterranean formation penetrated by a wellbore with a retarded acidizing fluid containing an acid and an acid retarding agent, the concentrations of which are adjusted based on measured parameter values of the formation. Also described is a method for treating a subterranean formation by introducing an acid to the formation following the introduction of an acid retarding agent to the formation. Also described is a method for acid fracturing a subterranean formation including reducing the concentration of an acid retarding agent contained in a retarded acidizing fluid over the course of the acid fracturing operation.

Methods for making and using retarded acid compositions for well stimulation

Methods for shortening the waiting-on-cement (WOC) time during primary and remedial cementing operations are disclosed. A fluid pill is injected into the wellbore that comprises reactants. The reaction is acclerating hydration and shortening the time necessary for the slurry to set and harden.

Described herein is a multi-phase aqueous composition containing a surfactant; a first phase comprising water, an acid, and a water-soluble acid retarding agent; and a second phase selected from the group consisting of an immiscible organic phase, a gas, and combinations thereof. Further described are methods of making and using such compositions.

Emulsions containing water-soluble acid retarding agents and methods of making and using

Described herein are aqueous composition(s) containing water; a viscoelastic surfactant; an acid; and a water-soluble acid retarding agent. Further described are methods of making and using such compositions.

Diversion acid containing a water-soluble retarding agent and methods of making and using

An aqueous solution is disclosed including water, an acid, a nitrogen-containing compound, and a functionalizing agent (FA), which can be a ketone, diketone, aldehyde, dialdehyde, organic acid, and combinations thereof. An additional aqueous solution is disclosed including water, an acid, and an acid neutralizing agent which can be a reaction product of at least a portion of the nitrogen-containing compound and the functionalizing agent. Methods of treating a formation are also disclosed including treating a formation fluidly coupled to a wellbore with an oilfield treatment fluid comprising either or both of the aqueous solutions.

Aqueous solution and method for use thereof

A method is described for treating a subterranean formation penetrated by a wellbore including injecting into the formation a treatment fluid including a rheological modifier; at least one viscoelastic surfactant (VES) at a concentration of between about 0.1 and about 10 percent by weight; and a formation-dissolving agent selected from the group consisting of hydrochloric acid, formic acid, acetic acid, lactic acid, glycolic acid, sulfamic acid, malic acid, citric acid, tartaric acid, maleic acid, methylsulfamic acid, chloroacetic acid, aminopolycarboxylic acids, 3-hydroxypropionic acid, polyaminopolycarboxylic acids, salts thereof and mixtures of said acids and salts.

Methods of controlling viscosity of acids

Described herein are methods for on the fly mixing of retarded acidizing fluids containing acid, a water-soluble acid retarding agent (RA), and optionally a viscoelastic surfactant (VES), and for on the fly mixing of diversion fluids containing VES and RA in the same equipment. Also described are methods of controlling the preparation of such fluids based on feedback composition analyses.

On the fly mixing of acids and diversion fluids with water-soluble retarding agents

Methods include combining an amount of water and an acid retarding agent (RA), where the amount of water is present in an amount up to about 5 times the mass of the RA, inclusive, and wherein the RA includes at least one salt compound. An amount of acid is dissolved in the combined amount of water and RA to form a composition, where the amount of acid is a molar ratio of acid:RA of between 4.0 and 0.2, inclusive, and wherein the amount of acid is up to about 36% by weight of total weight of the composition. The composition is injected into a wellbore penetrating a subterranean formation at a pressure, which may be less than the fracture initiation pressure of the subterranean formation in some cases, while in other cases equal to or greater than the fracture initiation pressure.

Aqueous retarded acid solution and methods for use thereof

An aqueous composition comprising a mineral acid, a fixing agent and water present in an amount sufficient to dissolve the mineral acid and the fixing agent. The fixing agent comprises at least one of an amine and/or an amide containing compound having a dipole moment of at least 3 when in the aqueous composition.

Growing community of inventors

Houston, TX, United States of America

Christopher Daeffler