Ppg Industries Ohio, Inc.

Ppg Industries, Inc.

Christopher A Verardi

Paul H Lamers

Jonathan T Martz

William A Humphrey

Lawrence D Meyers

Carolyn A Novak

Michele L Meli

Steven V Barancyk

Shanti Swarup

Kurt Gordon Olson

James Rowley

Gina M Terrago

Hongying Zhou

Marvis E Hartman

Richard J Sadvary

Caroline S Harris

Dennis L Faler

Susan Fundy Donaldson

Shiryn Tyebjee

John W Burgman

Jonathan P Breon

Wei Wang

Howard L Senkfor

Rodger G Temple

Victoria A Trettel

Karen A Morow

Gobinda Saha

Carolyn A K Novak

Michael P Makowski

Brian Endlich

Nicholas J Crano

Carolyn Ak Novak

Hilary Ann Kerchner

George William Mauer, Iii

Paul Hubert Lamers

Sara Ashley Friello

Dennis Leroy Faler

Steven Edward Bowles

David Robert Fenn

George W Mauer Iii

Carolyn AK Novak

Chester Szymanski

A coating composition includes: (a) a phosphorus acid functional polyol polymer having an acid value within a range of greater than 7 mg KOH/g and 33 mg KOH/g or less, and a hydroxyl value within a range of from 60 to 200 mg KOH/g; (b) an aminoplast derived crosslinker reactive with the phosphorus acid functional polyol polymer; and (c) a non-aqueous liquid medium. Further, if an external catalyst is present, the coating composition comprises less than 0.25 weight % of the external catalyst based on the total weight of the coating composition. The coating composition cures at a temperature of 100° C. or less.

Coating compositions containing phosphorus acid functional polyol polymers and coatings formed therefrom

The present invention is directed to film-forming compositions comprising: a) a non-chlorinated, linear polyolefin polymer comprising 0.5 to 10 percent by weight residues of an ethylenically unsaturated anhydride or acid; b) an aminoplast; and c) a component comprising: i) at least one non-chlorinated hydrocarbon having at least 18 carbon atoms and optionally aromatic groups and/or oxygen heteroatoms; and/or ii) an alkyd resin. The present invention is also drawn to methods of improving fuel resistance of a coated article, comprising: (1) applying the film-forming composition to a substrate to form a coated substrate; (2) optionally subjecting the coated substrate to a temperature for a time sufficient to cure the film-forming composition; (3) applying at least one curable film-forming composition to the coated substrate to form a multi-layer coated substrate; and (4) subjecting the multi-layer coated substrate to a temperature and for a time sufficient to cure all of the film-forming compositions.

Adhesion promoting compositions and method of improving fuel resistance of a coated article

The present invention is directed to a method for forming a composite coating on a substrate. The method comprises: Also provided are coated substrates prepared using the above method.

Method of forming multi-component composite coating compositions on substrates using compact processes

An aqueous dispersion comprising a reaction product of trimellitic anhydride and a polyol, wherein the molar ratio of trimellitic anhydride to polyol in the reaction product ranges from 1:2 to 1:4, and wherein the reaction product is further reacted with an anhydride to form another reaction product. A method of making a resin comprising the reaction product described above is also disclosed.

Aqueous dispersion comprising a branched triol having trimellitic anhydride and associated method

Aqueous resinous binders comprising graft copolymers, water-dilutable urethane polyols and epoxy-phosphorus acid reaction products are disclosed. The binders are useful in primer formulations for automotive applications.

Aqueous resinous binders

A coating composition, formed of a film-forming component comprising a functional group-containing resinous binder and, optionally, a crosslinking agent having at least two functional groups that are reactive with the functional groups of the film-forming component, wherein, when the composition is applied and cured to form a cured coating, the cured coating is characterized as having a bicontinuous morphology. Methods of making the coating composition and coatings prepared therefrom are also provided. The coating composition can provide improved physical properties, such as chip resistance, when incorporated into a coating.

Coatings with improved chip resistance and methods of making the same

Aqueous resinous binders comprising graft copolymers, water-dilutable urethane polyols, epoxy-phosphorus acid reaction products, and an aqueous dispersion comprising the reaction product of trimellitic anhydride and a polyol, wherein the molar ratio of trimellitic anhydride to the polyol in the reaction product ranges from 1:2 to 1:4, and wherein the reaction product is further reacted with an anhydride to form another reaction product are disclosed. The binders are useful in primer formulations for automotive applications.

A polyurethane material, the coatings prepared therefrom, and methods of making the same are provided. An anionic self-crosslinkable polyurethane material has a weight average molecular weight of less than 15,000 grams per mole and, when cured, has a toughness of at least 20 MPa according to TOUGHNESS TEST METHOD at a temperature of 25&deg; C.

Curable polyurethanes, coatings prepared therefrom, and method of making the same

A polyurethane material, the coatings prepared therefrom, and methods of making the same are provided. A polyurethane material may be formed from components comprising at least one polyisocyanate, at least one active hydrogen-containing material, at least one material having at least one primary or secondary amino group and at least one hydroxyl group, and at least one acid functional material or anhydride having a functional group reactive with isocyanate or hydroxyl groups of other components from which the polyurethane material is formed. The polyurethane can provide improved physical properties, such as chip resistance, when incorporated into a coating composition.

The present invention provides methods for forming composite coatings on substrates including the steps of: (A) applying an aqueous primary coating composition to at least a portion of a surface of a substrate, the primary coating composition including: (1) at least one thermosettable dispersion including polymeric microparticles having functionality adapted to react with a crosslinking material, the microparticles including: (a) at least one acid functional reaction product of ethylenically unsaturated monomers; and (b) at least one hydrophobic polymer having a number average molecular weight of at least about 500; and (2) at least one crosslinking material, to form a substantially uncured primary coating thereon; (B) applying a secondary coating composition to at least a portion of the primary coating formed in step (A) without substantially curing the primary coating to form a substantially uncured secondary coating thereon; and (C) applying a clear coating composition to at least a portion of the secondary coating formed in step (B) without substantially curing the secondary coating to form a substantially uncured composite coating thereon.

Methods for forming composite coatings on substrates

A liquid coating composition has: from about 5 to 45 percent by weight of resin solids of substantially saturated polyhydroxylated polydiene polymer having terminal hydroxyl groups; from about 10 to 50 percent by weight of resin solids of crosslinking material; from about 5 to 85 percent by weight of resin solids of polymeric film forming resin; and solvent. The solvent has at least 5 percent by weight of the solvent composition consisting of water; and/or at least one organic solvent having Hansen Solubility Parameters Sp.sub.o from about 8.0 to 10.0 (cal/cm.sup.3).sup.1/2, Sp.sub.h from about 0.5 to 5.0 (cal/cm.sup.3).sup.1/2 ; and Sp.sub.p from about 0.2 to 3.0 (cal/cm.sup.3).sup.1/2 ; and/or mixtures thereof. The liquid coating composition can be solvent-based or aqueous-based and can additionally contain at least one pigment. The liquid coating composition can be coated directly onto thermoplastic and thermosetting plastic substrates, such as TPO and RIM, without the aid of flame or corona pretreatment, or the use of an adhesion promoter. A method of coating plastic substrates comprising the use of the liquid coating composition and a plastic article coated with the liquid coating composition are also disclosed.

Thermosettable primer and topcoat for plastics a method for applying and

A liquid coating composition has: from about 5 to 45 percent by weight of resin solids of substantially saturated polyhydroxylated polydiene polymer having terminal hydroxyl groups; from about 10 to 50 percent by weight of resin solids of crosslinking material; from about 5 to 85 percent by weight of resin solids of polymeric film forming resin; and solvent. The solvent has at least 5 percent by weight of the solvent composition consisting of water; and/or at least one organic solvent having Hansen Solubility Parameters Sp.sub.o from about 8.0 to 10.0 (cal/cm.sup.3).sup.1/2, SP.sub.h from about 0.5 to 5.0 (cal/cm.sup.3).sup.1/2, and Sp.sub.p from about 0.2 to 3.0 (cal/cm.sup.3).sup.1/2 ; and/or mixtures thereof. The liquid coating composition can be solvent-based or aqueous-based and can additionally contain at least one pigment. The liquid coating composition can be coated directly onto thermoplastic and thermosetting plastic substrates, such as TPO and RIM, without the aid of flame or corona pretreatment, or the use of an adhesion promoter. A method of coating plastic substrates comprising the use of the liquid coating composition and a plastic article coated with the liquid coating composition are also disclosed.

Thermosettable primer and topcoat for plastics, a method for applying

A flexible, aminoplast-curable film-forming composition can serve as a transparent coating composition for a multi-component composite coating composition having the transparent coating on a pigmented or colored base coat. The film-forming composition comprises at least two polymeric components. One is a polyether polymer containing a plurality of terminal and/or pendant carbamate groups of the structure: ##STR1## Another is at least one additional carbamate functional polymer along with urethane oligomer or is a polyurethane polyol. The former include carbamate functional polyester, acrylic polymer, and polyurethane, where each contains a plurality of terminal and/or pendant carbamate groups of the Structure I depicted above. Also the urethane oligomers has a plurality of carbamate groups of Structure I that are pendant and/or terminal. The latter polyurethane polyol has a plurality of pendant and/or terminal hydroxyl groups and optionally can be used with the urethane polyol and/or any of the aforementioned carbamate functional polymers. Optionally an additional polymer that is present is an acrylic polymer containing a plurality of amide groups with or without a plurality of terminal and/or pendant carbamate groups of Structure I. Also with the presence of the amide functional acrylic polymer, silica can be employed. Additionally for crosslinking the film-forming composition contains an aminoplast crosslinking agent.

Flexible aminoplast-curable film-forming compositions and composite

A liquid coating composition, comprising (a) from about 5 to 100 percent of resin solids of a mixture of (i) a substantially saturated polyhydroxylated polydiene polymer, having terminal hydroxyl groups, and (ii) a chlorinated polyolefin, wherein the weight of the polydiene polymer is between about 5 and 95 percent of the total weight of the mixture of polyhydroxylated polydiene polymer and chlorinated polyolefin; (b) about 0 to about 95 percent by weight of resin solids of a film forming polymer selected from liquid and carrier-reducible film forming polymers; and (c) a carrier material. The liquid coating composition can be solvent-based or aqueous based and can additionally contain at least on pigment. The liquid coating composition can be coated onto plastic substrates to improve the adhesion of subsequently applied coatings and to substantially improve the solvent resistance, especially to gasoline, of the finally coated plastic part.

Coating composition for plastic substrates and coated plastic articles

A flexible, aminoplast-curable film-forming composition and a process for preparing multi-layered coated articles coated with a pigmented or colored base coat and a transparent or clear topcoat are disclosed. A pigmented or colored base coat is first applied to a substrate followed by the application of a transparent topcoat to the base coat. The transparent topcoat composition is a flexible, curable film-forming composition comprising (i) a polyether polymer containing a plurality of terminal or pendant carbamate groups of the structure: ##STR1## (ii) a polymer selected from the group consisting of a polyester polymer, a polyurethane polymer, an acrylic polymer, and mixtures thereof wherein each polymer contains a plurality of terminal or pendant carbamate groups of the structure depicted above; and (iii) an aminoplast crosslinking agent. In a particularly preferred embodiment, the film-forming composition contains a polyester polymer derived from a cycloaliphatic acid or anhydride. The topcoat composition provides a flexible composite coating with improved acid etch resistance, making the composite coating particularly useful as a topcoat for plastic automotive parts.

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Pittsburgh, PA, United States of America

Christopher A Verardi