Basf Se Corporation

Basf Aktiengesellschaft

Yale University

Christoph Kiener

Markus Schubert

Ulrich Mueller

Ulrich Müller

Karl-Heinz Schumacher

William Bachop Dolan

Peter Preishuber-Pfluegl

Frank Poplow

Ingo Richter

Andrea Kuntz

Axel Meyer

Marcus Guzmann

Matthias Gerst

Dirk Wulff

John F Hartwig

Stefan Marx

Juergen Huff

Joerg Pastre

Emi Leung

Andrea Eisenhardt

Holger Kern

Joerg Krogmann

Faruk Özkirim

Markus Tonigold

Lars Heckhoff

James Reuben Brown

Gerhard Krennrich

Chutian Shu

Christine Tonhauser

Friedhelm Teich

Toshimichi Ohmura

Fernando Garcia Lopez

Richard Bociek

Martin Bek

Hans-Martin Herr Henning

Stefan Herr Henninger

Dolan William

Described herein is a protection film comprising a polyolefin carrier material, a precoating of the polyolefin carrier material with a primer selected from polyurethane dispersions and a pressure-sensitive adhesive layer of a radiation-crosslinked hotmelt adhesive. A process for producing such protection films is also described.

Protective films made of polyolefin support material, primer and radiation-crosslinkable hot melt adhesive

Described is a process for producing adhesive-coated articles, wherein an aqueous dispersion adhesive composition comprising a dispersed adhesive polymer and a dissolved polyvinylpyrrolidone is applied at high web speed to a film substrate using a coating machine having at least one rotating roller and wherein the coated film substrate may optionally be bonded to a further substrate. Also described is the use of polyvinylpyrrolidone as a defoamer for aqueous dispersion adhesive compositions applied to a film substrate using a coating machine having a rapidly rotating roller.

Method for producing articles coated with adhesive

A description is given of the use of a one-component laminating adhesive for composite film lamination, and also of a method for composite film lamination. The laminating adhesive comprises an aqueous polymer dispersion preparable by radical emulsion polymerization of monomers comprising (a) at least 60 wt %, based on the total amount of monomers, of at least one monomer selected from the group consisting of C1 to C20 alkyl acrylates, C1 to C20 alkyl methacrylates, vinyl esters of carboxylic acids comprising up to 20 carbon atoms, vinylaromatics having up to 20 carbon atoms, vinyl halides, vinyl ethers of alcohols comprising 1 to 10 carbon atoms, aliphatic hydrocarbons having 2 to 8 carbon atoms and one or two double bonds, and mixtures of these monomers, and (b) at least 0.1 wt %, based on the total amount of monomers, of at least one monomer having at least one acid group, and (c) 0.1 to 5 wt %, based on the total amount of monomers, of at least one ethylenically unsaturated compound having at least one functional group selected from keto groups and aldehyde groups; where the aqueous polymer dispersion comprises at least one compound A which has at least two functional groups that are able to enter into a crosslinking reaction with keto groups or with aldehyde groups; where the molar ratio of the groups of the compound A that are reactive with keto groups or with aldehyde groups to the keto and aldehyde groups of the monomer (b) is from 1:10 to 2:1; and where, in the composite film lamination, at least two films are bonded to one another with the laminating adhesive so firmly that the peel strength is 2.5 N/15 mm or more or that the films bonded to one another are partable only with destruction of at least one of the films. The composite films can be used for the packing of foods.

Use of a single-component laminating adhesive for composite film lamination

A description is given of the use of a polymer dispersion for cold sealing, the polymer dispersion comprising a polymer in dispersion in water and having a glass transition temperature in the range from &#x2212;20 to +10&#xb0; C., said polymer being preparable by emulsion polymerization of radically polymerizable monomers in the presence of at least one polymeric protective colloid, and the polymer being formed to an extent of 0.05 to less than 1 wt % of a monomer M, selected from the group consisting of (meth)acrylate monomers having a substituent of the formula where X is CH, O, NH or NR, and R is a C1 to C4 alkyl group. Descriptions are also given of a method for producing cold-sealed packaging, and of the packaging obtainable by said method.

Use of a polymer dispersion for cold sealing

The use of aqueous polyurethane dispersions is described for composite foil lamination, where at least 10% by weight of the polyurethane derives from at least one amorphous polyester polyol.

Use of aqueous polyurethane dispersions for composite foil lamination

Porous metal organic frameworks formed by Alions to which fumarate ions are coordinated to produce a framework structure; shaped bodies comprising such porous metal organic frameworks, and also the preparation and use thereof for the uptake of a substance for the purposes of its storage, controlled release, separation, chemical reaction or as support.

Metal organic frameworks based on aluminum fumarate, the preparation thereof, shaped bodies comprising such frameworks, and uses therefor

The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of&#x2014;contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.

Process for the separation of unbranched hydrocarbons from their branched isomers

A vacuum insulation unit having at least one thermally insulating, evacuatable porous core material which is sealed in an airtight manner and a sorption medium, wherein the sorption medium containing at least one porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion.

Vacuum insulation units comprising getter materials

The present invention relates to a porous metal-organic framework material comprising a bidentate organic compound bound by coordination to a metal ion, the metal ion being Aland the bidentate organic compound being 2,6-naphthalenedicarboxylate, wherein the X-ray diffractogram (XRD) of the framework material has a first reflection in the range from 6.5&#xb0;&#x3c;2&#x398;&#x3c;7.5&#xb0; and a second reflection in the range from 13.8&#xb0;&#x3c;2&#x398;&#x3c;15.0&#xb0;, the area of the first reflection being greatest in relation to the area of all reflections in the range from 2&#xb0;&#x3c;2&#x398;&#x3c;70&#xb0; and the area of the second reflection being second greatest, and the sum of the areas of the first and second reflections giving at least 50% in relation to the total area of all reflections in the range from 2&#xb0;&#x3c;2&#x398;&#x3c;70&#xb0;. The invention further relates to shaped bodies comprising such a framework material, processes for production of the framework material and also to the use of the framework material or of the proposed shaped body.

Aluminum naphthalenedicarboxylate as porous metal-organic framework material

The present invention relates to the use of a porous metal-organic framework material comprising at least one, at least bidentate, organic compound bound to at least one metal ion by coordination, the at least one metal ion, the at least one, at least bidentate, organic compound, or if appropriate a further component, being a coloring component, as sorbent and for permanent color marking of a filter.

Use of porous metal-organic framework materials for color marking of filters

A process for the industrial isolation of propene from a gas stream comprising at least propene and propane, which involves contacting of the gas stream with an adsorbent having a porous metal organic framework having at least one at least bidentate organic compound coordinated to at least one metal ion, with the adsorbent becoming laden with propane and the gas stream therefore having an increased proportion of propene, wherein the W least bidentate organic compound is an imidazolate which is unsubstituted or has one or more substituents selected independently from of halogen, C-alkyl, phenyl, NH, NH(C-alkyl), N(C-alkyl), OH, O-phenyl and O&#x2014;C-alkyl.

Process for the industrial isolation of propene

Method of using a metal organic frameworks based on aluminum fumarate

A porous metal organic framework containing an at least bidentate organic compound coordinated to a metal ion, wherein the metal ion is Aland the at least bidentate organic compound is 2-aminoterephthalic acid, and wherein the framework is in powder form and has a specific surface area determined by the Langmuir method (N2, 77 K) of at least 2500 m/g. In addition, a shaped body containing the metal organic framework, processes for preparing the metal organic framework and shaped body, and processes for storing and separating gases with the metal organic framework and shaped body.

Aluminum aminocarboxylates as porous metal organic frameworks

The present invention is directed to a catalyst composition, comprising: (1) a catalyst precursor having the general structure MSXwherein M is a transition metal selected from the group consisting of iridium, molybdenum, and tungsten; S is a coordinating ligand; X is a counterion; and n is an integer from 0 to 5; and (2) a phosphoramidite ligand having the structure wherein O&#x2014;C&#x2014;O is an aliphatic or aromatic diolate and wherein R, R, Rand Rare selected from the group consisting of substituted or unsubstituted aryl groups, substituted or unsubstituted heteroaryl groups, substituted or unsubstituted aliphatic groups, and combinations thereof, with the proviso that at least one of R, R, R, or Rmust be a substituted or unsubstituted aryl or heteroaryl group. The present invention is also directed to activated catalysts made from the above catalyst composition, as well as methods of allylic amination and etherification using the above catalysts.

Enantioselective amination and etherification

The present invention relates to a method for the separation of carbon dioxide from a gas mixture containing carbon dioxide comprising the steps of

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Weisenheim am Sand, Germany

Christoph Kiener