Basf Se Corporation

Christiane Giesker

Mark Elbing

Holger Seifert

Johann Klassen

Joerg Krogmann

Markus Schütte

Patrick Lax

Jörg Krogmann

Markus Schutte

Jorg Krogmann

The present invention relates to a process for the production of a rigid polyurethane foam or rigid polyisocyanurate foam, comprising the reaction of at least one polyisocyanate and of a polyol composition (PZ), where the polyol composition (PZ) comprises at least one compound having at least two hydrogen atoms reactive toward isocyanate groups and at least one compound (I) selected from the group consisting of dicarboxylic diesters of dicarboxylic acids having from 2 to 18 C atoms and tricarboxylic triesters of tricarboxylic acids having from 3 to 18 C atoms, where at least one blowing agent is used during the reaction. The present invention further relates to rigid polyurethane foams or rigid polyisocyanurate foams obtainable or obtained by such a process, and also to a polyol composition (PZ) at least comprising one compound having at least two hydrogen atoms reactive toward isocyanate groups and at least one compound (I) selected from the group consisting of dicarboxylic diesters of dicarboxylic acids having from 2 to 18 C atoms and tricarboxylic triesters of tricarboxylic acids having from 3 to 18 C atoms. The present invention also relates to the use of such a polyol composition (PZ) for the production of rigid polyurethane foams or rigid polyisocyanurate foams, and also to the use of a rigid polyurethane foam or rigid polyisocyanurate foam of the invention as, or for the production of, insulation materials, preferably insulation sheets, sandwich elements, hot-water tanks, boilers, coolers, insulation foams, refrigerators or freezers.

Method for producing a rigid polyurethane foam

The present invention relates to a process for producing rigid polyurethane foams by reaction of a) at least one organic polyisocyanate with b) at least one polyol component in the presence of a blowing agent mixture comprising water and halogenated alkenes, wherein the amount of water is at least 1.40 mol/kg of polyol component b) and the amount of halogenated alkene is at most 2.00 mol/kg of polyol component b), and also to the use of such a blowing agent mixture for producing corresponding rigid polyurethane foams and for increasing the adherence and reducing the thermal conductivity of corresponding rigid polyurethane foams. The present invention further relates to a rigid polyurethane foam obtainable by the process of the present invention.

HFO/water-blown rigid foam systems

Growing community of inventors

Osnabrück, Germany

Christiane Giesker