Bayer Aktiengesellschaft

Bayeraktiengesellschaft

Christian Weber

Peter Haas

Klaus Seel

Hermann Schafer

Werner Rasshofer

Hans Wirtz

Christian Lindner

Rolf Dhein

Klaus Konig

Manfred Schmidt

Hanns-Peter Muller

Eberhard Konig

Holger Meyborg

Joachim Wagner

Alexander Karbach

Ulrich Eisele

Reiner Paul

Geza Avar

Hartwig Grammes

Erhard Michels

Erich Meier

Klaus Brecht

Eberhard Jurgens

Karl-Heinz Dorner

Hans G Weber

A process for the CFC-free production of cellular polyurethane molded parts/articles with solid surfaces by reacting a reaction mixture of per se known starting materials in sealed molds, to yield polyurethane foams. Carbamates obtainable from aliphatic aminoalcohols and carbon dioxide are used as blowing agents, optionally in conjunction with other blowing agents. The process is suitable for producing foam coverings on steering wheels, spoilers and protective upholstery in car interiors, and for producing soles of shoes or shoe components.

Process for the CFC-free production of cellular polyurethane molded parts

The use of solutions of zinc carboxylates having 8 to 24 carbon atoms in aliphatic polyamines having molecular weights of from 131 to 500 having a total of 2 or 3 primary, secondary and/or tertiary amine nitrogen atoms as additives for the formation of a compact surface in the production of molded foams having a maximum gross density of 500 kg/m.sup.3 from organic polyisocyanates, polyether polyols, chain lengthening agents, water and optionally other auxiliary agents and additives.

Process for producing integral skin molded foams

Open-celled, cold-formable polyurethane foams are made by reacting a specific crude MDI with a polyol component which includes hydroxyl polyethers having an OH number of from about 28 to about 600, a difunctional phthalic acid hydroxyl polyester having an OH number of from about 150 to about 440, glycerol, a blowing agent (water is preferred), a tertiary amine catalyst and optionally a silicone foam stabilizer. These foams generally have a density of from about 23 to about 30 kg/m.sup.3 and may be molded into articles having intricate shapes (e.g., roof for automobiles) using known cold-forming techniques.

Process for the production of open-cell, cold-formable rigid

Modified polyisocyanates having an NCO group content of from 10 to 45% by weight, comprising a a) a polyisocyanate component consisting essentially of an organic polyisocyanate having an NCO group content of from 15 to 50% by weight which is liquid at room temperature, and b) 2 to 100% by weight, based on the weight of component a), of a polymer modifier consisting of at least one graft rubber which is dispersed in swollen form in component a), and a process for the production of the new modified polyisocyanates are described. The modified polyisocyanates are also useful in the production of plastics by the isocyanate polyaddition process.

Modified polyisocyanates, a process for their production and their use

The present invention relates to a process for the preparation of moldings or films based on polyisocyanate polyadducts comprising thermoplastically molding, at a temperature of at least 50.degree. C. and at a pressure of at least 5 bar, polyisocyanate polyadducts obtained by reacting in closed molds using the reaction injection molding technique aromatic polyisocyanates; compounds having a molecular weight of from 1800 to 12,000 and containing on a statistical average at least 2.5 isocyanate-reactive groups; and one or more components selected from a diamine containing two primary and/or secondary aromatically bound amino groups and and an aliphatic or cycloaliphatic polyol or polyamine; with the provisos that the quantity of isocyanate-reactive compound is at least 30% by weight based on the total quantity of the components and that at least one of the diamine, polyol, or polyamine components comprises at least 5% by weight based on the weight of the isocyanate-reactive compound.

Process for production of moldings or films from polyisocyanate

The present invention is directed to a process for the production of polyurethane or polyurea elastomeric molded articles according to the reaction injection molding process by reacting a polyisocyanate, a high molecular weight isocyanate reactive component and optionally a diamine chain extender, wherein the improvement is based on the use of the reaction product of a polyepoxide containing at least two epoxide groups with at least one mol of an aromatic diamine per epoxide group wherein the polyepoxide is present in an amount sufficient to provide about 0.5 to 25% by weight of the polyepoxide based on the weight of all the isocyanate reactive components. The present invention is also directed to the isocyanate reactive components for use in this process and to the molded articles produced in accordance with this process.

Process for the production of molded articles, mixtures of isocyanate

Elastic molded articles having a closed surface layer are made from polyurea elastomers by the reaction injection molding technique. These polyurea elastomers are prepared from a polyisocyanate in which all of the isocyanate groups are aromatically bound, a polyether and a diamine. The polyether has at least two isocyanate-reactive groups and a molecular weight from 1800 to 12,000. At least 50% of the isocyanate-reactive groups in the polyether are pjrimary and/or secondary amino groups. The diamine has a molecular weight from 108 to 400 and primary and/or secondary aromatically bound amino groups. Known auxiliary agents and additives may also be employed.

Process for the production of elastic molded articles

Elastic molded articles having a closed surface layer are made from polyurea elastomers by the reaction injection molding technique. These polyurea elastomers are prepared from a polyisocyanate in which all of the isocyanate groups are aromatically bound, a polyether and a diamine. The polyether has at least two isocyanate-reactive groups and a molecular weight from 1800 to 12,000. At least 50% of the isocyanate-reactive groups in the polyether are primary and/or secondary amino groups. The diamine has a molecular weight from 108 to 400 and primary and/or secondary aromatically bound amino groups. Known auxiliary agents and additives may also be employed.

The present invention is directed to mold release compositions based on a solution which is liquid at room temperature and contains

Mold release composition, mixtures containing this mold release

The present invention is directed to a mold release composition which is a solution, liquid at room temperature, of

The present invention is directed to a process for the production of urea- and/or biuret-modified polyisocyanates by reacting organic polyisocyanates with a mixture of high molecular weight isocyanate-reactive compounds and low molecular weight isocyanate-reactive compounds, wherein at least 25% of the isocyanate-reactive groups are primary amino groups. The present invention is further directed to the products obtained by this process and their use for the production of polyisocyanate polyaddition products, especially for the preparation of molded articles by the RIM process.

Process for the production of polyisocyanates containing urea and/or

The present invention relates to a new process for the production of elastomeric polyurethane moldings which may be microcellular having a sealed surface layer and an average density of from 0.8 to 1.4 g/cm.sup.3, wherein specific condensation products of ricinoleic acid are used as internal mold release agents.

Process for the production of moldings

This invention relates to an improved single-stage process for the production of elastic shaped articles having an impervious surface layer by the reaction injection molding technique in which highly reactive systems of polyisocyanates, relatively high molecular weight polyhydroxyl compounds and aromatic polyamines are used.

Process for the production of elastic shaped articles

The instant invention relates to a one-step process for the production of elastomeric moldings which have a compact surface by the technique of reaction injection molding, using highly reactive systems of specific polyisocyanates, polyhydroxyl compounds and specific active aromatic polyamines. The instant invention further relates to active hydrogen containing blends useful in preparing elastomeric moldings, said blends comprising polyhydroxyl compounds, and specific active aromatic diamines. The blends herein may also contain catalyst for the reaction between hydroxyl groups and isocyanate groups.

Rim process for the production of elastic moldings

This invention relates to a process for making polyurethane elastomer moldings from

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Leverkusen, Germany

Christian Weber