Commissariat a L'energie Atomique Et Aux Energies Alternatives

Orano Cycle

Electricite De France

Areva Nc

Commissariat a L'energie Atomique

Compagnie Generale Des Matieres Nucleaires

Commissariat a L'energie Atomique Et Aux Energies

Orano Recyclage

Christian Sorel

Manuel Miguirditchian

Pascal Baron

Gilles Bernier

Binh Dinh

Xavier Heres

Cécile Marie

Michel Masson

Michael Lecomte

Emilie Russello

Dominique Guillaumont

Eugen Andreiadis

Didier Saudray

Laurence Chareyre

Gaëlle Milanole

Estelle Ameil

Coralie Balaguer

Isabelle Bisel

Jean Bertin

Clément Hill

Michaël Lecomte

Vincent Vanel

Clémence Berger

Guillaume Mossand

Sylvain Costenoble

A dissymmetric RN,N-dialkylamides of formula (I) in which: Rrepresents a linear Cto Calkyl, Rrepresents a linear Cto Calkyl, and Rrepresents a linear or branched Cto Calkyl, where Ris different from a n-octyl, n-decyl, n-dodecyl, 2-ethylhexyl and 2-ethyloctyl group when Rrepresents a n-butyl group and Rrepresents an ethyl group. A method for synthesising the N,N-dialkylamides, and uses of same for extracting uranium and/or plutonium from an aqueous acid solution or for fully or partially separating the uranium from the plutonium contained in an aqueous acid solution and a solution resulting from the dissolution of spent nuclear fuel in nitric acid. A method for treating an aqueous solution resulting from the dissolution of spent nuclear fuel in nitric acid, which allows the uranium and the plutonium contained in the solution to be extracted, separated and decontaminated in a single cycle.

Dissymmetric N,N-dialkylamides used particularly for separating uranium(VI) from plutonium(IV), synthesis thereof and uses of same

The use of carbamides as extractants for fully or partially separating uranium(VI) from plutonium(IV) in an aqueous solution obtained by dissolving a spent nuclear fuel in nitric acid, by method of liquid-liquid extraction, without carrying out any reduction of the plutonium(IV) to plutonium(III). The invention also relates to new carbamides. Uses are the processing of spent nuclear fuels based on uranium (especially uranium oxides&#x2014;UOX) or uranium and plutonium (especially mixed uranium and plutonium oxides&#x2014;MOX).

Carbamides for separating uranium(VI) and plutonium(IV) without reducing the plutonium(IV)

A method for the treatment of an aqueous solution resulting from the dissolution of a spent nuclear fuel in nitric acid, allowing the uranium and plutonium contained in the solution to be extracted, separated and decontaminated in a single cycle, without requiring any operation involving a reductive stripping of plutonium. Applications for the method include the processing of uranium-based and/or plutonium-based spent nuclear fuels.

Method for the treatment of an aqueous nitric solution resulting from dissolving spent nuclear fuel, said method being performed in a single cycle and without requiring any operation involving reductive stripping of plutonium

A method for processing a spent nuclear fuel is disclosed which includes a step for decontaminating uranium(VI) from one or more actinides(IV) and more specially from neptunium and/or plutonium, by complexing this (these) actinide(s)(IV). This method includes a step for decontaminating uranium (VI) from at least one actinide(IV), which decontaminating step comprises at least one operation for stripping the actinide(IV) from an organic phase, not miscible with water, and wherein uranium(VI) and the actinide(IV) are present, by putting the organic phase into contact with an aqueous phase comprising nitric acid and at least one complexing agent which more strongly complexes actinides(IV) than uranium(VI), and then separating the organic phase from the nitric aqueous phase, wherein the at least one complexing agent is a diglycolamide.

Method for processing spent nuclear fuel comprising a step for decontaminating uranium (VI) from at least one actinide (IV) by complexing this actinide (IV)

A method with which uranium from a natural uranium concentrate may be purified, including The extractant is an N,N-dialkylamide and the ratio between the flow rate at which the organic phase obtained at the end of step b) and the aqueous phase A3 circulate in the apparatus where step c) occurs, is greater than 1.

Method for purifying the uranium from a natural uranium concentrate

The invention relates to a process for reprocessing spent nuclear fuel which, among other advantages, does not require a plutonium-reducing stripping operation. This process finds particular application in the processing of uranium oxide fuels and uranium and plutonium mixed oxide fuels.

Process for reprocessing spent nuclear fuel not requiring a plutonium-reducing stripping operation

A method with which americium may be selectively recovered from a nitric aqueous phase containing americium, curium and fission products including lanthanides and yttrium, but which is free of uranium, plutonium and neptunium or which only contains these three last elements in trace amounts. The method is applicable for treatment and recycling of irradiated nuclear fuels, in particular for removing americium from raffinates stemming from methods for extracting and purifying uranium and plutonium such as the PUREX and COEX&#x2122; methods.

Method for selectively recovering americium from a nitric aqueous phase

The invention relates to a method for separating uranium(VI) from one or more actinides selected from actinides(IV) and actinides(VI) other than uranium(VI), characterized in that it comprises the following steps: a) bringing an organic phase, which is immiscible with water and contains the said uranium and the said actinide or actinides, in contact with an aqueous acidic solution containing at least one lacunary heteropolyanion and, if the said actinide or at least one of the said actinides is an actinide(VI), a reducing agent capable of selectively reducing this actinide(VI); and b) separating the said organic phase from the said aqueous solution. Applications: reprocessing irradiated nuclear fuels, processing rare-earth, thorium and/or uranium ores.

Method for separating uranium (VI) from actinides(IV) and/or actinides (VI) and its uses

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Villeneuve-les-Avignon, France

Christian Sorel