Dentsply Sirona Inc.

Dentsply Detrey G.m.b.h.

Christian Scheufler

Joachim E Klee

Caroline Renn

Florian Szillat

Oliver Elsner

Xiaoming Jin

Maximilian Maier

Christoph Weber

Helmut Ritter

Uwe Walz

Thomas Tigges

Andrew Murray Lichkus

Hui Lu

Christoph P Fik

Jörg Brenneisen

Matthias Worm

Julia Gansel

Jorg Brenneisen

Kira Neuhaus

Mattias Worm

Maxmilian Maier

Bassam Usta

Ulrich Lampe

Helmut Prof Dr Ritter

Elsner Oliver

Lampe Ulrich

Maximilian Dr Maier

Joachim E Prof Dr Klee

Christoph Dr Weber

Described herein is a dental composition containing a polymerizable compound having at least one optionally derivatized β-hydroxy urethane unit. The polymerizable compound having at least one optionally derivatized β-hydroxy urethane unit is obtained without use of organo-metal catalysts and isocyanates and by a reaction between an at least one component A having at least one cyclic carbonate group with an at least one component B having at least one of primary amine functional group and secondary amine functional group. The present disclosure relates to use of the polymerizable compound having at least one optionally derivatized β-hydroxy urethane unit for the preparation of a dental composition, in particular a dental composite, a glass ionomer, a dental cement, a dental sealant, and a dental adhesive.

Dental composition

The present invention relates to a dental composition comprising a specific radically polymerizable compound and a radical initiator system. Furthermore, the present invention relates to the specific radically polymerizable compound and its use in a dental composition. The specific radically polymerizable compound of the present invention has an allyl (meth)acrylamide group and a phosphoric acid ester group.

The present invention relates to a dental composition comprising a radically polymerizable compound, a redox initiator system comprising one or more clathrate compounds comprising a host molecule and one or more guest molecules, wherein the host molecule is selected from cyclodextrines, crown ethers, cucurbituriles and calixarenes and the one or more guest molecules are reducing agents, and an oxidizing agent. Furthermore, the present invention relates to a use of the redox initiator system in a dental composition.

The present invention relates to a dental composition comprising a photoinitiator system comprising a particulate carrier supporting a coinitiator covalently bonded to the surface of the carrier. Furthermore, the present invention relates to a use of the particulate carrier in a dental composition. The particulate carrier displays multiple covalently bonded tertiary amino groups and/or tertiary phosphine groups on the surface, for crosslinking monomers, oligomers and/or polymers having one or more polymerizable double bonds.

Dental composition comprising a particulate carrier supporting a coinitiator

The present invention relates to an initiator modified polyacidic polymer having a covalently bonded initiator compound, and to a dental resin-modified glass ionomer composition comprising this polyacidic polymer. Furthermore, the present invention relates to a use of the initiator modified polyacidic polymer for the preparation of a dental composition. The covalently bonded initiator compound of the initiator modified polyacidic polymer may be any compound of a redox initiator system, a photoinitiator system, for example a Norrish type I or II photoinitiator, an electron donor component, a sensitizer component or a coinitiator component.

Photoinitiator modified polyacidic polymer

Described herein are a polymerizable antibacterial nanogel and hydrolytically stable antibacterial nanogel composition and methods of preparing such compositions, use of polymerizable antibacterial nanogels and hydrolytically stable antibacterial nanogels as additives to a dental product, such as a resin monomer, a cement, an adhesive and composite formulations. Methods and compositions for forming hydrolytically stable antibacterial monomers are also described.

Compositions and methods to antibacterial nanogel and hydrolytically stable antibacterial nanogel for dental compositions

The present invention relates to a dental composition which is a resin modified dental cement composition, comprising a radically polymerizable compound and a redox initiator system comprising one or more clathrate compounds comprising a host molecule and one or more guest molecules, wherein the guest molecule is an oxidising agent selected from organic peroxides and organic hydroperoxides. Furthermore, the present invention relates to a use of the redox initiator system in a dental composition which is a resin modified dental cement composition.

The present invention relates to a dental composition comprising a specific polymerizable compound and a polymerization initiator system. Furthermore, the present invention relates to the specific polymerizable compound as such and its use in a dental composition. The specific polymerizable compound of the present invention has an N-allyl (meth)acrylamide group, which nitrogen atom is substituted with an alkyl or alkenyl group optionally substituted by a group selected from a hydroxyl group, a Calkoxy group, a tertiary amino group and a carboxyl group, wherein 1 to 8 carbon atoms in the main chain of the alkyl or alkenyl group may independently from each other be replaced by a heteroatom selected from an oxygen atom and a sulfur atom.

The present disclosure relates to methods and compositions to stabilize a nanogel and use of such nanogel as additives in dental compositions.

Methods and compositions to stabilize a nanogel and dental compositions therefrom

The present invention relates to a polymerizable polyacidic polymer and to a process for preparing the polymerizable polyacidic polymer. Furthermore, the present invention relates to an aqueous dental composition comprising the polymerizable polyacidic polymer, to a use of the polymerizable polyacidic polymer for the preparation of a dental composition and to an acrylic acid derivative copolymer.

Polymerizable polyacidic polymer

A dental composition comprising a polymerizable acidic compound of the following formula (I): 

The present invention relates to an aqueous dental glass ionomer composition comprising

Aqueous dental glass ionomer composition

The present disclosure relates to an aqueous dental glass ionomer composition comprising a reactive particulate glass, a water-soluble, polymerizable polymer which is reactive with the particulate glass in a cement reaction, a hydrolysis-stable, water-soluble monomer having a single polymerizable double bond and optionally a carboxylic acid group or hydroxyl group; and a polymerization initiator system, wherein the polymerizable polymer is obtainable by a process comprising a step of polymerizing a mixture comprising a first polymerizable monomer comprising at least one optionally protected carboxylic acid group and a first polymerizable organic moiety, and optionally a second copolymerizable monomer comprising one or more optionally protected primary and/or secondary hydroxyl and/or amino group(s) and a second polymerizable organic moiety, for obtaining an water-soluble polymer; a step of coupling to the water-soluble polymer a compound having a polymerizable moiety and a functional group reactive with an optionally protected carboxylic acid group of repeating units derived from the first polymerizable monomer or an optionally protected hydroxyl and/or amino group of repeating units derived from the second copolymerizable monomer in the water-soluble polymer obtained in step a), wherein the optionally protected carboxylic acid group and the optionally protected hydroxyl and/or amine group are deprotected, so that polymerizable pendant groups are linked to the backbone by ester groups, urethane groups and/or amide groups, and, optionally, a step of deprotecting the protected carboxylic acid group for obtaining a polymerizable polymer.

An aqueous dental glass ionomer composition comprising (A) a reactive particulate glass, (B) a water-soluble polymer comprising acidic groups, which is reactive with the particulate glass in a cement reaction, (C) a water-soluble, hydrolysis-stable monomer having a single polymerizable double bond and optionally a carboxylic acid group or hydroxyl group; (D) a water-soluble, hydrolysis-stable polymerizable crosslinker having at least two polymerizable carbon-carbon double bonds; and (E) a polymerization initiator system.

Growing community of inventors

Engen, Germany

Christian Scheufler