Glaverbel

Christian Dauby

Pierre Laroche

Pierre Boulanger

Bernard Somerhausen

Albert Servais

Camille Dupont

Paul Claes

Luc Van Cangh

A process for forming a silver coating on a surface of a vitreous substrate is described. The process comprises an activating step in which said surface is contacted with an activating solution, a sensitising step in which said surface is contacted with a sensitising solution, and a subsequent silvering step in which said surface is contacted with a silvering solution comprising a source of silver to form the silver coating. The process is characterised in that said activating solution comprises ions of at least one of bismuth (III), chromium (II), gold (III), indium (III), nickel (II), palladium (II), platinum (II), rhodium (III), ruthenium (III), titanium (III), vanadium (III) and zinc (II).

Forming a silver coating on a vitreous substrate

A domestic or vehicle rearview silvered mirror having a silver coating which is not covered with a protective layer of copper. The silver mirror comprises a glass sheet, tin and preferably palladium at surface of the glass sheet, a silver coating of the surface of the glass sheet and at least one paint layer covering the silver coating. Optionally, tin may be present at the surface of the silver coating adjacent the paint layer and optionally traces of silane may be present at the surface of the silver coating adjacent to the paint layer. Alternate or additional materials may be present at a surface of the glass sheet and alternate or additional materials may be present at the surface of the silver adjacent to the paint layer.

Silver coated mirror

A mirror composed of a vitreous substrate having a silver coating formed on a surface thereof produced by a process including the steps of sensitizing the vitreous substrate; activating the vitreous substrate by contacting the vitreous substrate with a solution comprised of at least one ion selected from the group consisting of bismuth (III), chromium (II), gold (III), indium (III), nickel (II), palladium (II), platinum (II), rhodium (III), titanium (III), vanadium (III) and zinc (II); contacting the vitreous substrate with a silvering solution so as to form the silver coating; and applying at least one layer of paint over the silvered substrate. Preferably, the silver coating is not covered with a protective layer of copper.

In a process for forming a mirror which includes sensitizing and activating a vitreous substrate, subsequently silvering the vitreous substrate to provide a silver coating thereon, and applying paint to the silver coating, the improvement including activating the vitreous substrate by contacting the vitreous substrate with a solution comprised of at least one ion selected from the group consisting essentially of bismuth (III), chromium (II), gold (III), indium (III), nickel (II), palladium (II), platinum (II), rhodium (III), ruthenium (III), titanium (III), vanadium (III) and zinc (II); and silvering the vitreous substrate by spraying a silvering solution onto a surface of the sensitized and activated vitreous substrate to form a silver coating on the surface, so that a mirror is formed which has no copper layer.

A reflective article such as a mirror or an energy-screening transparent panel comprises a reflective metal coating deposited on a glass substrate. The metal coating comprises a reflective layer of silver and has been treated with a solution containing ions of at least one of the group consisting of: Cr (II); V (II or III); Ti (III or II); Fe (II); In (I or II); Cu (I); and Al (III). Such a treatment affords protection of the reflective coating against corrosion.

Reflective articles and methods of manufacturing same

A reflective article such as a mirror or an energy-screening transparent panel comprises a reflective metal coating deposited on a glass substrate. The metal coating comprises a reflective layer of silver and has been treated with a solution containing ions of at least one of the group consisting of: Cr(II); V(II or III); Ti(III or II); Fe(II); In(I or II); Cu(I); and Al(III). Such a treatment affords protection of the reflective coating against corrosion.

Reflective articles having improved corrosion resistance

A reflective article includes a glass substrate and a reflective metal coating deposited on the glass substrate including a reflective layer of silver and having a surface stratum which has a population of tin atoms which is augmented as compared with the population of tin atoms (if any) in an underlying subsurface stratum by at least one tin atom per hundred metal atoms thereby conferring on the reflective metal coating an enhanced resistance to corrosion. The reflective layer of silver is treated with an acidified aqueous solution of a stannous salt, which solution is free from opalescence, thereby to augment tin atom population in a surface stratum of the reflective metal coating.

Corrosion resistant reflective articles

A method of and apparatus for monitoring the redox state of one or more elements in glass are disclosed in which a working electrode 2 and an auxiliary electrode 7 are immersed in the glass 11 while the latter is molten. A scanning potential is applied to the working electrode, a series of potential pulses is superimposed on said scanning potential, and the resulting current between the electrodes is monitored to give an indication of the redox state of one or more elements in the glass.

Growing community of inventors

Gerpinnes, Belgium

Christian Dauby