Alcatel

Christelle Lavallade

Jean-Florent Campion

Jean-Maxime Saugrain

Pierryle Jourdier

Philippe Oskeritsian

Jean-Fran&ccedil;ois Chariot

Jean-Philippe Francois

Jacques Jolly

Jacques Goudeau

Rosine Meilleur

R&eacute;mi Fauche

Jean-Francois Chariot

Claire Wane Nguila

The invention relates to a method of doping silica with fluorine. The method described comprises mixing a powder of silica granules with a solid fluorine compound, thermally decomposing the solid fluorine compound under an inert atmosphere, and densifying the granules to obtain dense grains of doped silica. It is preferable to use ammonium bifluoride. The invention is applicable to preparing high index silica glass, in particular for fabricating optical fiber preforms.

Method of manufacturing a fluorine-doped silica powder

A method of manufacturing an optical fiber preform ( ) comprising: forming at least one silica-based outer deposition layer ( ) by depositing silica on a primary preform ( ) constituted by a bar mainly comprising silica and including a silica-based outer peripheral portion ( ), the method being characterized in that the viscosity of the outer deposition layer ( ) is adjusted to be substantially identical to the viscosity of the outer peripheral portion ( ) of the primary preform ( ) by adding to the silica, over a substantial portion of the outer deposition layer ( ), at least one compound selected from the group formed by the following compounds: CaF , MgF , AlF , B O , and Al O .

Method of depositing a layer of silica followed by a step of adding dopant to the layer

A process is described for making silica powder by a sol-gel process whereby an aqueous suspension is made of a silica-based raw material which includes particles containing chlorine, the pH of the suspension is adjusted to a value from 3 to 4.5 if necessary, the suspension is gelled, the gel obtained is dried and the dried gel is fractionated into silica granules. The silica-based raw material preferably includes particles containing chlorine having a specific surface area less than 80 m /g and less than 5 wt. % relative to the total quantity of particles containing chlorine of silica particles having a specific surface area from 150 m /g to 300 m /g. The use of such powder to manufacture an optical fiber preform is also described.

Process for making silica powder and use of such powder in the manufacture of an optical fiber preform

Silica granules made up of mutually agglomerated silica soot particles are treated by placing the granules in a crucible inside a furnace which contains an inert gas mixed with a chlorine-containing compound and in which the temperature lies in the range 1000&deg; C. to 1500&deg; C. According to the invention, a crucible is used that is made of porous graphite firstly to increase the surface area of the crucible through which the chlorine-containing compound diffuses. This gives rise to faster exchange between the granules and the gas for given partial pressure of the chlorine-containing compound, thereby improving purification. Secondly, the difference between the chemical natures of the silicas and the crucible make the two materials inert relative to each other so that the granules do not adhere to the walls of the crucible, thereby making it possible to recover the granules without having to apply any mechanical operation that might contaminate them.

Method and apparatus for treating silica granules using porous graphite crucible

In the method, a suspension of silica particles in water is provided, the suspension is gelled, the resulting gel is dried under microwaves, the dried gel is fractioned into silica granules having a diameter lying in the range 10 .mu.m to 1000 .mu.m, having an apparent density of about 0.5 g/cm.sup.3 to 0.6 g/cm.sup.3, and a porosity of less than 20%, and the granules are screened in the range 100 .mu.m to 500 .mu.m. The suspension in water of silica particles is made by mixing silica soots having a size of less than 0.1 .mu.m and silica grains having a size greater than 1 .mu.m. Its maximum concentration in total weight is greater than that of a suspension of synthetic soots on their own, thereby making it possible to increase the production capacity of the method. Advantageously, the out-of-range granules rejected by the screening are recycled as silica grains for the aqueous suspension, thereby making it possible to increase the accumulated production efficiency of the method.

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Courdimanche, France

Christelle Lavallade