Lg Chem, Ltd

Korea Advanced Institute of Science and Technology

Choong Hoon Lee

Eun Jung Lee

Sang Eun Park

Jin Sam Gong

In Sung Park

Seung Hwan Jung

Jung Ho Jun

Hyun Jin Ju

Rae Keun Gwak

Sung Ho Choi

Seul Ki Kim

Yoon Hee Cho

Hae Woong Park

Young Shil Do

Seungwhan Jung

Hyo Ju Kim

Bun Yeoul Lee

Ji Yoon Woo

Hyo Jung Han

Jong Joo Ha

Young Woo Lee

Ki Won Han

Hoon Chae

Boram Lee

Ki Soo Lee

Sangwoo Lee

Eun-Jung Lee

Ju Young Lee

Tae Su Kim

Dae June Joe

A Rim Kim

Eun Jung Joo

Dae Young Shin

Kyung Soo Park

Sun Chang Kim

Sung Don Hong

Young Whan Park

Bong Hyun Sung

Beom Doo Seo

Kyung Bok Bae

Ik Je Choe

Don Ho Kum

Yun Jin Lee

Jae Kwon Jang

Young Hoon Na

Beomdoo Seo

Jung A Lee

Ui Gab Joung

Eunjung Lee

Yutaek Sung

Hyojoon Lee

Youn Sun Nam

Dong Eun Kim

Sungho Choi

Young Chul Won

Jung Bin Lee

Ji Joong Moon

Jun Hyoung Lee

Byoung Soo Kim

Seung Whan Jung

Jeongyong Lee

Hyosun Lee

Byung Jo Yu

Seung Ki Park

Myung Keun Park

Jin Ho Jung

Yoonhee Cho

Youngshil Do

JiYoon Woo

HyoJu Kim

Soojeong Lee

Seungwoo Choi

Sang Hee Lee

Juho Yoon

Kui Hyeon Kang

The present invention relates to a polypropylene-based composite, including (A) polypropylene, and (B) an olefin-based polymer satisfying the following conditions: (1) a melt index (MI, 190° C., 2.16 kg load conditions) is from 0.1 g/10 min to 10.0 g/10 min, (2) a melting temperature when measured by differential scanning calorimetry (DSC) is from 20° C. to 70° C., and (3) a high temperature melting peak is confirmed at 75° C. to 150° C. when measured by a differential scanning calorimetry precise measurement method (SSA), and a total enthalpy of fusion ΔH(75) of a corresponding region is 1.0 J/g or more. The polypropylene-based composite of the present invention may show excellent impact strength.

Polypropylene-based composite

The present invention relates to a polypropylene-based composite, including (A) polypropylene, and (B) an olefin-based polymer satisfying the following conditions: (1) a melt index (MI, 190° C., 2.16 kg load conditions) is from 0.1 g/10 min to 10.0 g/10 min, (2) a density (d) is from 0.860 g/cc to 0.880 g/cc, and (3) T(90)-T(50)≤50 and T(95)-T(90)≥10 are satisfied, wherein T(50), T(90) and T(95) are temperatures at which 50%, 90%, and 95% are melted, respectively, when fractionating a temperature-heat capacity curve from measurement results by the differential scanning calorimetry precise measurement method (SSA). The polypropylene-based composite of the present invention may show excellent impact strength.

An olefin-based polymer and method of making the same is disclosed herein. In some embodiments, the olefin-based polymer has multiple crystallinity and satisfies the following: (1) two or more peaks in a temperature range of −20° C. to 120° C. when measured by cross-fractionation chromatography (CFC), and T(90)−T(50)<8.0° C., (2) a soluble fraction (SF) of 1 wt % or less at −20° C. in CFC, (3) 15° C.<elution temperature (Te)<50° C., and Te has a linear correlation with a density (d) of the polymer, and satisfies the following Equation 1, Te=1,220×d−A, wherein 1,031≤A≤1,039. The olefin-based polymer according to the present invention is an olefin-based polymer having relatively increased the ratio of high crystal regions, and exhibits excellent mechanical properties such as improved tensile strength, tear strength, and flexural modulus.

Olefin-based polymer

The present invention relates to an olefin-based polymer satisfying conditions as follow: (1) a melt index (MI, 190° C., 2.16 kg load conditions) is from 0.1 g/10 min to 10.0 g/10 min, (2) a density (d) is from 0.860 g/cc to 0.880 g/cc, and (3) T(90)−T(50)≤50 and T(95)−T(90)≥10 are satisfied when measured by a differential scanning calorimetry precise measurement method (SSA). The olefin-based polymer according to the present invention is a low-density olefin-based polymer introducing a highly crystalline region and showing high mechanical rigidity.

The present invention relates to a polypropylene-based composite material having improved physical properties including impact strength at low temperature and at room temperature, flexural strength, flexural modulus, etc., and a method for preparing the same.

Polypropylene-based composite material and method for preparing the same

The present invention relates to an olefin-based copolymer of which soluble fraction at a low temperature has a high weight average molecular weight, and which has high flowability and improved physical properties of hardness, flexural strength, tearing strength, etc., and a method for preparing the same.

Olefin-based copolymer and method for preparing the same

A transition metal compound having a novel structure is disclosed herein. The transition metal compound can have improved structural stability by forming a stable coordination site of a transition metal through controlling a bond angle formed by the amido group of a phenylene bridge, a cyclopentadienyl ring, and a transition metal. The transition metal compound has excellent copolymerization properties and may produce an olefin polymer having a high molecular weight in a ultra low density region.

Transition metal compound, catalyst composition including the same and method for preparing polymer using same

An olefin-based copolymer and method of making the same are disclosed herein. In some embodiments, the olefin-based copolymer includes a repeating unit derived from an alpha-olefin, wherein the alphas-olefin is present in the copolymer at 15 wt % to 45 wt %, wherein the copolymer has a density (d) of 0.85 to 0.89 g/cc, a melt index (MI), measured at 190&#xb0; C. and 2.16 kg load, of 15 g/10 min to 100 g/10 min, and a hardness defined by Equation 1. The olefin-based copolymer has improved hardness and is highly flowable, and may show improved physical properties of tensile strength, elongation rate and flexural modulus.

The present invention provides an ethylene/alpha-olefin copolymer having narrow molecular weight distribution together with a low density and an ultra low molecular weight, having minimized number of unsaturated functional groups, and having uniform crystallinity, thereby showing excellent physical properties, and a method for preparing the same.

Ethylene/alpha-olefin copolymer and method for preparing the same

The present invention provides an ethylene/alpha-olefin copolymer having narrow molecular weight distribution together with a low density and an ultra low molecular weight, minimized number of unsaturated functional groups, and particularly a small amount of vinylidene among the unsaturated functional groups to show excellent physical properties, and a method for preparing the same.

An olefin-based copolymer and a method of making the same are disclosed herein. In some embodiments, an olefin-based copolymer has a density (d) of 0.85 to 0.89 g/cc, a melt index (MI), measured at 190&#xb0; C. and 2.16 kg load, of 15 g/10 min to 100 g/10 min, a number of unsaturated functional groups (total V) per 1,000 carbon atoms of 0.8 or less, a vinylene content, and a vinyl content, wherein the vinylene content, the vinyl content and the total V satisfy (a) vinylene content/total V=0.1 to 0.7 and (b) vinylene content/vinyl content=0.8 to 1.6. The olefin-based copolymer has controlled content and kind of an unsaturated functional group in the olefin-based copolymer and thus, has high flowability, and may show improved physical properties of hardness, flexural strength and tensile strength.

The present invention relates to a method for preparing ethylene vinylacetate copolymer that can improve the mechanical strength of copolymer by controlling the polymerization conditions using an autoclave reactor.

Method for preparing ethylene vinylacetate copolymer

Provided are an ethylene-vinyl acetate copolymer having a high degree of crosslinking by controlling a temperature difference in an autoclave reactor and an input ratio of an initiator during polymerization, even though a reduced amount of a crosslinking agent is used, and a preparation method thereof.

Ethylene-vinyl acetate copolymer and preparation method thereof

The present invention relates to an olefin-based polymer, which has (1) a density (d) ranging from 0.85 to 0.90 g/cc, (2) a melt index (MI, 190&#xb0; C., 2.16 kg load conditions) ranging from 0.1 g/10 min to 15 g/10 min, (3) the density (d) and the melt temperature (Tm) satisfying Tm (&#xb0; C.)=a&#xd7;d&#x2212;b of Equation 1 (2,350&#x3c;a&#x3c;2,500, and 1,900&#x3c;b&#x3c;2,100), and (4) a ratio (hardness/Tm) of the hardness (shore A) to the melt temperature (Tm) in a range of 1.0 to 1.3. The olefin-based polymer according to the present invention exhibits excellent anti-blocking properties due to having improved hardness as a low-density olefin-based polymer.

The present invention relates to an olefin-based polymer, which has (1) a density (d) ranging from 0.850 to 0.865 g/cc, (2) a melt index (MI, 190&#xb0; C., 2.16 kg load conditions) ranging from 0.1 g/10 min to 3.0 g/10 min, and (3) a soluble fraction (SF) of 10 wt % or more at &#x2212;20&#xb0; C. in cross-fractionation chromatography (CFC), in which a weight average molecular weight (Mw) of the soluble fraction is in a range of 50,000 g/mol to 500,000 g/mol. The olefin-based polymer according to the present invention exhibits improved anti-blocking properties as a low-density olefin-based polymer.

Growing community of inventors

Daejeon, South Korea

Choong Hoon Lee