Texaco Inc.

Abb Lummus Global Inc.

Other

Chih-Hao Mark Tsang

Pei-Shing E Dai

Randall Hughes Petty

Laurence D Neff

Thomas Frederick Leininger

John D Winter

Chi-Lin O'Young

Roy E Pratt

Charles H Schrader

Hsu-Hui Hsing

Glenn Allen Clausen

Pravit Vassantachart

Katherine S Lee

Rajasekar Kamarthi

The present invention relates to an apparatus and method for withdrawing and dewatering slag from a gasification system. In particular, the present invention relates to a conveying lockhopper and method of using the conveying lockhopper to collect slag and other waste byproducts from the gasifier of a gasification system. The conveying lockhopper is configured to receive slag from a gasifier, simultaneously extract and dewater the slag, and expel the processed slag directly into an awaiting container suitable for carrying the processed slag away. The conveying lockhopper generally comprises a housing with inlet and outlet valves to receive and expel slag, respectively. The housing is inclined at an angle typically between 5 and 60 degrees to the horizontal so that the outlet is at a higher elevation than the inlet. Inside the housing, an auger or similar conveying mechanism conveys the slag from the inlet towards the outlet while simultaneously dewatering the slag. As a result, the processed slag that is discharged at the outlet is fully processed and ready to be transported away.

Method for withdrawing and dewatering slag from a gasification system

In accordance with the present invention, a basic material, preferably ammonia, is injected into the stream of soot water leaving the gasification reactor prior to being processed in a filtration-type soot removal unit. The elevated pH of the soot water causes more metals to remain in the filter cake. Thus, the metals content of the grey water is reduced. More grey water can then be recycled back to the gasification unit, with less grey water being handled by the wastewater treatment unit.

Ammonia injection for minimizing waste water treatment

Disclosed is a novel binary sieve catalyst useful for olefin upgrading and fluid catalytic cracking which comprises

FCC process using binary molecular sieves having a core and shell of

Disclosed is a novel binary sieve catalyst useful for olefin upgrading and fluid catalytic cracking which comprises a crystalline zeolite metallosilicate core and a shell selected from an aluminum phosphate molecular sieve (AlPO.sub.4), a silicon-substituted aluminophosphate (SAPO), a metal aluminophosphate (MeAPO), and a crystalline metal aluminophosphate (MeAPSO) and is generally synthesized by a method comprising:

Binary molecular sieves having a core and shell of different structures

Disclosed is a process for converting olefinic hydrocarbons using spent FCC catalysts which comprises using spent FCC catalysts, optionally containing spent FCC additives, in the reactor/stripper part of the FCCU, instead of or in addition to a separate olefin upgrader, to upgrade C.sub.2 -C.sub.8 oligomerizable olefins, preferably propylene and ethylene, into C.sub.4 /C.sub.5 olefins and isoparaffins as well as gasoline, wherein feedstock can be product streams of the FCCU containing propylene/ethylene such as, for example, the absorber and depropanizer overheads.

Process for converting olefinic hydrocarbons using spent FCC catalyst

Disclosed is a fluid catalytic cracking process for cracking gas oils and naphtha which provides improved selectivity for C.sub.3 -C.sub.5 olefins employing a catalyst comprising a novel zeolite characterized by a large number of secondary pores, a substantially decreased Lattice Constant of below about 24.19 .ANG., and a substantially decreased Acid Site Density, attained by hydrothermal and acid-treating of an ultrastable Y-zeolite.

FCC process employing low unit cell size y-zeolites

Disclosed is a process for converting a hydrocarbon charge to a product containing improved yields of C.sub.4 /C.sub.5 olefins with a reduction in the loss of gasoline yield which comprises:

FCC process for producing enhanced yields of C.sub.4 /C.sub.5 olefins

A hydrocarbon feedstock is catalytically cracked at an elevated temperature in a cracking zone with a zeolite cracking catalyst. The cracking catalyst employed comprises a crystalline aluminosilicate zeolite catalyst and a hybrid [Al,B]-zeolite catalyst. In this process the hydrocarbon feedstock is contacted with the zeolite catalyst in, for example, a fluidized bed catalytic cracking unit to yield cracked products containing increased amounts of C.sub.3 /C.sub.8 olefins.

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Houston, TX, United States of America

Chih-Hao Mark Tsang