3M Innovative Properties Company

Chia-Tie Ho

Clarence Fullbright, Jr

Carl W McMullen

Raymond M Sawka

Stefan Weigl

The present invention provides a flexible two component polyurethane and method for producing the polyurethane. The cured polyurethane is flexible, durable and weather resistant. The polyurethane is suitable for use as a protective layer on various substrates. The flexible polyurethane is the reaction product of solvent-free reaction components. The first component includes one or more polyols, optionally, one or more diols, and a catalyst. The second component includes a primary aliphatic isocyante crosslinker.

Flexible polyurethane material

Reactive two-part polyurethane compositions and optionally self-healable

A multilayer graphic article comprises a substrate, at least one color layer disposed on the substrate, and a protective surface layer that overlies the substrate and the color layer. The color layer is visible through the surface layer and comprises a color agent in a copolymeric binder. The binder comprises the copolymerization product of an olefinic monomer and a second monomer having a pendant carboxyl group. The substrate may be a polymeric film, an adhesive or a temporary, removable liner. The protective surface layer may be formulated to impart interior surface protection properties to the graphic article or it may be formulated to render the graphic article weatherable and resistant to chemical exposure.

Multilayer graphic article with color layer

An embossed multilayer film comprises an embossed base layer and a conformable, substantially uniformly thick protective surface layer that overlies the base layer. In one embodiment, the embossed multilayer film can be re-embossed. In another embodiment, the surface layer is provided by a polyurethane-based material. The invention also relates to a method of providing such an embossed multilayer film.

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Woodbury, MN, United States of America

Chia-Tie Ho