Eastman Chemical Company

Chester Wayne Sink

Scott Donald Barnicki

Robert Thomas Hembre

Nick Allen Collins

Ruairi Seosamh O'Meadhra

Steven Thomas Perri

Christopher Hardacre

Bhaskar Krishna Arumugam

Charles Edwan Sumner, Jr

Shriram Bagrodia

Spencer Erich Hochstetler

Ramesh Chand Munjal

Jerry Steven Fauver

Tera Jill Hardin

Robert Melvin Schisla

Jingyi Liu

John C Hubbs

Michael R Cushman

Cheuk C Yau

Larry Wayne Blair

Mark Robert Shelton

George William Tindall

William H Heise

Brendan William Boyd

Transito Lynne Macias

Jeffrey Earl Grant Powell

David Anthony Larkin

Fei Qi

David William Rooney

Silu Wang

Daniel P Folk

This invention relates to solvents for extracting Cto Ccarboxylic acids from aqueous streams. More specifically, the extraction solvents include one or more salts composed of a tetraalkylphosphonium cation and a phosphinate anion. The extraction solvents may further include one or more co-solvents as an enhancer. The co-solvents may be selected from higher carboxylic acids, ethers, esters, ketones, aromatic hydrocarbons, chlorinated hydrocarbons, and nitriles. The extraction solvents are useful for extracting aqueous mixtures containing one or more lower carboxylic acids, such as monocarboxylic acids and organofluorine carboxylic acids.

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This invention relates to solvents for extracting Cto Ccarboxylic acids from aqueous streams. More specifically, the extraction solvents include one or more salts composed of a phosphonium cation and an arylcarboxylate anion. The extraction solvents may further include one or more non-ionic liquid organic solvents as an enhancer. The extraction solvents are useful for extracting aqueous mixtures containing one or more lower carboxylic acids, such as monocarboxylic acids, alkoxycarboxylic acids, and halogen-containing carboxylic acids.

Quaternary arylcarboxylate compositions for extracting C1 to C4 carboxylic acids from aqueous streams

This invention relates to solvents for extracting Cto Ccarboxylic acids from aqueous streams. More specifically, the extraction solvents include one or more salts composed of a tetraalkylphosphonium cation and a carboxylate anion. The extraction solvents may further include one or more non-ionic liquid organic solvents as an enhancer. The extraction solvents are useful for extracting aqueous mixtures containing one or more lower carboxylic acids, such as monocarboxylic acids, alkoxycarboxylic acids, and halogen-containing carboxylic acids.

Resol beads are disclosed that are prepared in high yield by reaction of a phenol with an aldehyde, with a base as catalyst, a colloidal stabilizer, and optionally a surfactant. The resol beads have a variety of uses, and may be thermally treated and carbonized to obtain activated carbon beads.

Resol beads, methods of making them, and methods of using them

Resol beads, methods of making them and methods of using them

Process for the recovery of organic acids from aqueous solutions

The present invention provides methods and an apparatus for the manufacture of an L-ascorbic acid product in high yield by direct conversion of an aqueous solution containing 2-keto-L-gulonic acid by contact with an acid catalyst or under thermal self-catalyzed conditions at a conversion level that maximizes the formation of L-ascorbic acid and minimizes decomposition of the L-ascorbic acid thus formed. The separation process for L-ascorbic acid and KLG is operated in such a way that an efficient separation process allows the majority of the KLG to be recycled for further conversion. The product stream from the separation process is then subjected to a recovery step to obtain crystalline L-ascorbic acid product.

Continuous process for producing L-ascorbic acid

Disclosed is a process wherein a solution of a carboxylic acid in a first solvent and an alcohol are fed to a simulated moving bed reactor (SMBR) containing a solid(s) to produce a first stream comprising a solution of an ester of the carboxylic acid and the alcohol and a second stream comprising the first solvent. The solid(s) present in the SMBR facilitates the esterification reaction and the separation of the first solvent from the carboxylic acid. The process is particularly valuable for the preparation of an alkanol solution of an alkyl 2-keto-L-gulonate ester (AKLG) from an aqueous fermentation broth containing dissolved 2-keto-L-gulonic acid (KLG) by feeding the fermentation broth and an alkanol to a simulated moving bed reactor which contains a solid acidic esterification catalyst to produce a stream comprising an alkanol solution of an ALKG. The alkanol solution of an ALKG may be used directly to convert the ALKG to ascorbic acid (Vitamin C).

Preparation of esters of carboxylic acids

Provided is a method useful for separating and removing impurities such as cyclohexane dimethanol (CHDM) and other additives from their mixture with dimethylterehthalate (DMT), formed during a depolymerization process such as methanolysis of poly(ethyene terephthalate) (PET), poly(cyclohexyldimethylene terephthalate) (PCT), or copolyers of PET and PCT. The separation and removal of CHDM is accomplished via either melt or solution crystallization of the DMT following excess methanol removal (via distillation) of the methanolysis reactor products.

Process for separating cyclohexane dimethanol from dimethyl terephthalate

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Kingsport, TN, United States of America

Chester Wayne Sink