Wanhua Chemical Group Co., Ltd.

Wanhua Chemical (Ningbo) Co., Ltd.

Chengyue Yan

Bin Shi

Yonghua Shang

Nuancheng Wang

Yuan Li

Wei Liu

Yuqi Wang

Lidong Sun

Bing Zheng

Zhicheng Zhu

Li Li

Haijun Li

Weijing Fan

The present invention provides an isocyanurate-containing polyisocyanate composition with stable chromaticity, and a preparation method thereof, belonging to the technical field of polyisocyanate composition preparation. The preparation method comprises: an isocyanate monomer being polymerized in the presence of a catalyst, after the reaction is terminated, obtaining a prepolymer, subjecting the prepolymer to separation treatment and heat treatment, and obtaining the polyisocyanate composition containing isocyanurate; based on the weight of the polyisocyanate composition, the cleavable amine content of the polyisocyanate composition is less than or equal to 20 ppm. By means of controlling the cleavable amine content of the polyisocyanate composition, the present invention causes the resulting isocyanurate-containing polyisocyanate composition to have stable storage chromaticity, and the present invention has a chrominance increase of ≤10 Hazen when stored at 40° C. for 12 months.

Isocyanurate-containing polyisocyanate composition with stable chromaticity, and preparation method thereof

The present application provides a storage-stable polyisocyanate composition and a preparation method. The polyisocyanate composition is obtained by selecting one or more diisocyanate from aliphatic diisocyanates and alicyclic diisocyanates, and reacting same with an alcohol compound; the polyisocyanate composition contains an isocyanurate group, a uretdione group, a carbamate group, and an allophanate group; within the polyisocyanate composition, the molar ratio of the carbamate group/(uretdione group+isocyanurate group) is 0.01-0.2, and preferably 0.01-0.1. Compared to existing techniques, the present application has the advantage of a noticeable increase in system viscosity of uretdione polyisocyanate during storage. With the present application, by means of controlling the ratio of the carbamate group/(uretdione group+isocyanurate group) within the system, the increase in viscosity of a product during storage is inhibited, thereby improving the storage stability of the product.

Storage-stable polyisocyanate composition and preparation method

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Shandong, China

Chengyue Yan