Taiwan Semiconductor Manufacturing Comp. Ltd.

Cheng-Chieh Tu

Ming-Hsi Yeh

Kuo-Feng Yu

Jian-Hao Chen

Hui-Chi Chen

Ming-Chi Huang

Yung-Hsiang Chan

An-Hung Tai

Yen-Ta Lin

Tefu Yeh

Hao-Hsin Chen

Jui Fu Chueh

Disclosed is a method of forming gate structures for n-type and p-type transistors. The method includes: forming an interfacial layer and high-K (HK) dielectric layer for the gate structures; forming an n-type metal layer over the HK dielectric layer; forming a hard capping layer over the n-type metal layer while simultaneously strengthening the HK dielectric layer by fluorine passivation; patterning photo resist (PR) material over the hard capping layer that exposes a portion of the hard capping layer over the p-type transistor; removing the n-type metal layer and the hard capping layer over the p-type transistor via wet etching operations using high selectivity chemicals that are highly selective to the hard capping layer and the n-type metal layer; removing the patterned PR material while insulating, by the hard capping layer, gate structures from aluminum oxidation; and forming a p-type metal layer over the hard capping layer and the p-type transistor.

Metal gate patterning

In a method of manufacturing a semiconductor device, a gate space is formed by removing a sacrificial gate electrode formed over a channel region, a first gate dielectric layer is formed over the channel region in the gate space, a second gate dielectric layer is formed over the first gate dielectric layer, one or more conductive layers is formed on the second gate dielectric layer, the second gate dielectric layer and the one or more conductive layers are recessed, an annealing operation is performed to diffuse an element of the second gate dielectric layer into the first gate dielectric layer, and one or more metal layers are formed in the gate space.

Method of manufacturing semiconductor devices and semiconductor devices

Growing community of inventors

Hsinchu, Taiwan

Cheng-Chieh Tu