Conoco Inc.

Continental Oil Company

E.i. Dupont De Nemours and Company

Charles R Clark

Carl D Kennedy

Oliver C Kerfoot

D Philip Cords

Edward Francis McBride

Harold E Bellis

Patrick H Fitzgerald

Gifford G McClaflin

Donald L Whitfill

Burton M Casad

Nicholas O Wolf

Lisa A Cantu

M Duane Gregory

Delmar D Krehbiel

Robert R Matthews

A method of emulsion breaking comprising contacting an emulsion with a substrate having adhered thereto an alkylphenol-polyethylene oxide-acrylate polymer. The emulsion breaking material is used to separate water-in-oil emulsion by coalescence.

Emulsion breaking using alkylphenol-polyethylene oxide-acrylate polymer

Oil field chemicals are incorporated in polymeric particles of the condensation product of hydroxyacetic acid or the co-condensation product of hydroxyacetic acid and other compounds containing hydroxy-, carboxylic acid-, or hydroxycarboxylic acid moieties. The particles are introduced into an oil well bore and/or subterranean oil formation where the polymeric particles dissolve over a period of time and release the oil field chemicals.

Placement process for oil field chemicals

A melted polymer of hydroxyacetic acid with itself or with other hydroxy-, carboxylic acid-, or hydroxycarboxylic acid-containing moieties is subjected to high shear and injected into an organic liquid which is inert to the polymer to form an organic liquid dispersion of very fine polymer particles. In one aspect the melted polymer is combined with the organic liquid and the combination is thereafter subjected to high shear to form the fine particle polymer dispersion. A dispersion agent may also be used to aid in dispersing the particles. The dispersion is used for fluid loss control and gel breaking in subterranean formations.

Process for the preparation of fluid loss additive and gel breaker

Stoppage of gas-water streams due to the formation of gas hydrates is prevented by incorporating in such streams a surface active agent which inhibits the formation of gas hydrates and/or the agglomeration of hydrate crystallites into large crystalline masses.

Inhibition of hydrate formation

An improvement in the method of transporting viscous hydrocarbons through pipes is disclosed. Briefly, the method comprises adding water containing an effective amount of a combination of an alkaryl sulfonate having a molecular weight of 415 to 470 and a C.sub.1 -C.sub.4 alcohol.

Method of transporting viscous hydrocarbons

An improved anionic waterflood additive is prepared by partially chlorinating a normal alkane having about 10 to about 18 carbon atoms to about 2 to about 15 weight percent chlorine content, employing the chlorinated alkane to alkylate an aromatic hydrocarbon, such as benzene; sulfonating the thus formed alkylate or a fraction thereof to form a sulfonic acid; converting the sulfonic acid to a sulfonate by reacting with a base component, such as an alkali metal hydroxide, ammonium hydroxide, or an alkali metal carbonate; and overbasing the sulfonate by admixing with an excess of base component such that the ratio: 'weight of excess base component/weight of sulfonate' is about 0.03 to about 3.0. The anionic waterflood additive is injected into a petroliferous formation, the formation is waterflooded, and oil is recovered.

Waterflood method using overbased normal alkylaromatic sulfonates

An improved anionic overbased waterflood additive comprises a base component, a first sulfonate component derived from an alkylation reaction product employing a branched-chain alkene as the alkylating agent, and a second sulfonate component derived from an alkylation reaction product employing a partially chlorinated normal alkane as the alkylating agent, wherein the base component is present in the weight ratio range of 3/100 to 300/100, base component to total sulfonate, and wherein the weight ratio of the first sulfonate component to the second sulfonate component is in the range of 1/9 to 9/1. The overbased waterflood additive may be formed prior to injection into a petroliferous formation or may be formed in situ by first injecting the total sulfonate followed by the base component.

Oil recovery method using overbased waterflood additive containing

An improved anionic waterflood additive is prepared by alkylating an aromatic hydrocarbon such as benzene with a branched-chain alkene having about 10 to about 35 carbon atoms such as a propylene tetramer dimerization reaction product in the presence of an alkylation catalyst such as AlCl.sub.3 ; sulfonating the thus formed alkylate product or a fraction thereof to form a sulfonic acid; converting the sulfonic acid to a sulfonate by reacting with a base component such as an alkali metal hydroxide, ammonium hydroxide, or an alkali metal carbonate; and overbasing the sulfonate by admixing with an excess of base component such that the ratio; 'weight of excess base component/weight of sulfonate' is about 0.03 to about 3.0. The anionic waterflood additive is injected into a petroliferous formation, the formation is waterflooded, and oil is recovered.

Growing community of inventors

Ponca City, OK, United States of America

Charles R Clark