Southwest Research Institute

Other

Charles K Baker

Stephen Thomas Wellinghoff

Benjamin R Furman

Mohan R Ram

Stephen T Willinghoff

Joel J Kampa

Ruell F Solberg, Jr

Steven P Saulnier

Charles H Parr

Patrick J Siemsen

Robert D Gutierrez

Christopher N Tiftickjian

Dayle D Winnie

The present disclosure relates to luminescent phosphors and more particularly, to fluoride-based luminescent phosphors, and methods for their preparation in deep eutectic solvent (DES) systems. The luminescent phosphors are formed with accompanying particle size control, relatively higher crystallinity and relatively higher fluorescence intensity.

Fluoride-based luminescent phosphors

The present invention is directed to composite films containing nanostructures within a polymer or monomeric matrix which composite may be formed on a metallic substrate and subsequently removed to provide bulk material. The nanostructures and polymer or monomer matrix may be assembled electrophoretically by initially providing a mixture of the nanostructures and polymer or monomer matrix material within generally anhydrous environments such as polar aprotic solvents followed by deposition of the composite film material.

Electrophoretic formation of nanostructured composites

A method of electrophoretic deposition of adsorbent media onto an electrically conducting substrate. The adsorbent media may include one or more porous coordination polymers and/or one or more secondary adsorbing particles. The adsorbent media may be continuously applied from a liquid composition at a selected thickness and at a controlled rate and as a function of voltage profiles.

Electrophoretic deposition of adsorbent media

A direction-finding antenna constructed from polymer composite materials which are electrically conductive is shown with the polymer composite materials replacing traditional metal materials. An inherent advantage of replacing metal materials is significantly lower radar reflectivity (radar cross section) and lower weight. The reduced radar reflectivity reduces the range of detectability of the antenna by possible adversaries. Despite significantly lower radar reflectivity, the antenna assembly has direction-finding characteristics which are essentially equivalent to traditional metal antennas.

Polymer, composite, direction-finding antenna

A thin film solid state amperometric detector for nitric oxide is provided based upon a mobile cation electrolyte that selectively transmits nitrosonium cations (NO*) therethrough. The presently most preferred embodiment employs NO-.beta.-alumina as the mobile cation electrolyte. The electrodes of the detector are preferably arranged in a bipotentiostat arrangement. The first and second working electrodes share a common reference electrode and a common counter electrode, which are positioned such that the potentials of the first and second working electrodes can be independently controlled. The first working electrode is exposed to a fluid (liquid or gaseous), whereas the second working electrode is normally isolated from the fluid. The first working electrode is set at a potential capable of oxidizing NO to NO+, the NO+ moves through the mobile cation solid electrolyte to the second electrode, and the second working electrode is set at a potential capable of reducing the NO+ back to NO. The detector has a diffusion barrier for the nitric oxide so that the voltage-current characteristics of the detector under diffusion limiting conditions are proportional to the concentration of nitric oxide in a fluid.

Selective electrochemical detector for nitric oxide and method

A thin film, solid sate amperometric detector for mac oxide is provided based upon a mobile cation electrolyte that selectively transmits nitrosonium cations (NO.sup.+) therethrough. The presently most preferred embodiment employs NO-.beta.-alumina as the mobile cation electrolyte. The electrodes of the detector are preferably arranged in a bipotentiostat arrangement. The first and second working electrodes share a common reference electrode and a common counter electrode, which are positioned such that the potentials of the first and second working electrodes can be independently controlled. The first working electrode is exposed to a fluid (liquid or gaseous), whereas the second working electrode is normally isolated from the fluid. The first working electrode is set at a potential capable of oxidizing NO to NO.sup.+, the NO.sup.+ moves through the mobile cation solid electrolyte to the second electrode, and the second working electrode is set at a potential capable of reducing the NO.sup.+ back to NO. The detector has a diffusion barrier for the nitric oxide so that the voltage-current characteristics of the detector under diffusion limiting conditions are proportional to the concentration of nitric oxide in a fluid.

A thin film, solid state amperometric detector for nitric oxide is provided based upon a mobile cation electrolyte that selectively transmits nitrosonium cations (NO.sup.+) therethrough. The presently most preferred embodiment employs NO-.beta.-alumina as the mobile cation electrolyte. The electrodes of the detector are preferably arranged in a bipotentiostat arrangement. The first and second working electrodes share a common reference electrode and a common counter electrode, which are positioned such that the potentials of the first and second working electrodes can be independently controlled. The first working electrode is exposed to a fluid (liquid or gaseous), whereas the second working electrode is normally isolated from the fluid. The first working electrode is set at a potential capable of oxidizing NO to NO.sup.+, the NO.sup.+ moves through the mobile cation solid electrolyte to the second electrode, and the second working electrode is set at a potential capable of reducing the NO.sup.+ back to NO. The detector has a diffusion barrier for the nitric oxide so that the voltage-current characteristics of the detector under diffusion limiting conditions are proportional to the concentration of nitric oxide in a fluid.

An electrically conducting self-doped carbazole polymer of the formula: ##STR1## wherein A is a bifunctional molecule capable of bonding to a positively charged molecule at one end and is capable of bonding to a flexible spacer group Z at another end, Z is a flexible spacer group capable of bonding to an anionic group A at one end and is capable of bonding either to a nitrogen or aromatic electron withdrawing or electron donating group at another end, E is a bifunctional molecule capable of bonding to nitrogen at one end and is capable of bonding to a flexible spacer group Z at anther end, X is a positively charged counterion, and n is at least 2.

Electrochemical drug release and article

An electrochemical drug release article containing an electrically conducting self-doped carbazole polymer of the formula: ##STR1## wherein A is a bifunctional molecule capable of bonding to a positively charged molecule at one end and is capable of bonding to a flexible spacer group Z at another end, Z is a flexible spacer group capable of bonding to an anionic group A at one end and is capable of bonding either to a nitrogen or aromatic electron withdrawing or electron donating group at another end, E is a bifunctional molecule capable of bonding to nitrogen at one end and is capable of bonding to a flexible spacer group Z at another end, X is a positively charged counterion, and n is at least 2.

Growing community of inventors

San Antonio, TX, United States of America

Charles K Baker