Owens Corning Fiberglas Technology, Inc.

Owens-corning Fiberglas Corporation

Kigre, Inc.

Schott Optical Glass, Inc.

Charles F Rapp

Russell M Potter

Stephanie M Mattson

Peter Bernard McGinnis

Neil M Cameron

William H Fausey

James Roger Jackson

Ron W Mayhew

J Ronald Gonterman

Harry Pennington

Robert A Herrick

George D Baybutt

A mineral fiber is disclosed having a composition including the following components in about the indicated weight percents:

Biosoluble, high temperature mineral wools

A process for making mineral wool fibers having high-temperature stability consisting essentially of: (a) preparing a mixture containing basalt and a quantity of uncalcined raw bauxite sufficient to provide the resulting fibers with an alumina content of at least 18 weight percent, preferably of from 19 to 23 weight percent; (b) heating the mixture to a temperature sufficient to form a substantially homogeneous melt, e.g., in a cupola furnace using coke in a quantity of from about 11 to 25 percent by weight of the mixture; and (c) forming the melt into fibers. The mixture may optionally contain a flux, e.g., limestone and/or dolomite, such as a flux providing a weight ratio of limestone plus dolomite to basalt of less than about 0.6, e.g., 0.1-0.4. The mixture may also contain slag in a weight ratio of slag:basalt of less than about 1.0, more preferably about 0.6. At least about 90% of the uncalcined raw bauxite is of a particle size capable of passing through a 150-mm mesh screen but incapable of passing through a 25-mm mesh screen, more preferably capable of passing through a 125-mm mesh screen but not a 50-mm mesh screen. Preferably, the bauxite has a bound-water content of 10-33 weight percent. The weight ratio of alumina to silica in the fibers is preferably greater than 0.35.

Process for making mineral wool fibers from lumps of uncalcined raw

The glass compositions of the present invention contain at least 2.0 wt % Al.sub.2 O.sub.3 to give resulting glass fiber an acceptable chemical durability for product performance, but no more than 3.0 wt % to ensure the fiber maintains a relatively high biosolubility. The compositions further include relatively high amount of Na.sub.2 O+K.sub.2 O+MgO+CaO, which tends to increase fiber biosolubility and allows for the use of reduced amounts of B.sub.2 O.sub.3 in the composition. The glass compositions have KI values that generally equal or exceed a KI value of 40 and are suitable for rotary processing. The compositions have liquidus temperatures below about 1800.degree. F. and viscosities above 300 Poise at the liquidus temperature. For higher B.sub.2 O.sub.3 compositions the liquidus temperatures are below 1650.degree. F., and the viscosities are above 1,000 Poises at the liquidus temperatures.

Glass fiber composition

Mineral fiber compositions are disclosed which, in a first embodiment, include the following components, indicated in weight percents: about 54 to about 70 percent SiO.sub.2, about 0 to about 4 percent Al.sub.2 O.sub.3, about 0 to about 6 percent Na.sub.2 O, about 0 to about 6 percent K.sub.2 O, about 0 to about 6 percent MgO, about 10 to about 28 percent CaO, about 6 to about 17 percent total iron as FeO, and about 0 to about 5 percent TiO.sub.2, wherein the total weight percent of SiO.sub.2 and Al.sub.2 O.sub.3 ranges from about 56 percent to about 72 percent, the total weight percent of MgO and CaO ranges from about 12 percent to about 28 percent, the total weight percent of Na.sub.2 O and K.sub.2 O does not exceed 6 percent, and the total weight percent of all components, including trace elements, if any, is 100 percent. In a second embodiment, the compositions include the following components, indicated in weight percents: about 50 to about 68 percent SiO.sub.2, about 0 to about 4 percent Al.sub.2 O.sub.3, about 0 to about 6 percent K.sub.2 O, about 0 to about 6 percent Na.sub.2 O, about 0 to about 10 percent MgO, about 10 to about 28 percent CaO, about 6 to about 16 percent total iron as FeO, about 0 to about 5 percent TiO.sub.2, and about 0.5 to about 12 percent ZrO.sub.2, wherein the total weight of Na.sub.2 O and K.sub.2 O does not exceed 6 percent and the total weight of all components, including trace elements, if any, is 100 percent.

Mineral fiber compositions

Irregularly shaped glass fibers and insulation therefrom comprise two different glasses having differing coefficients of thermal expansion. These glasses also have physical properties which allow current processes to fabricate them into insulation. The glasses also meet German recommendations regarding a KI value of 40 or above.

Irregularly shaped glass fibers and insulation therefrom

Irregularly shaped glass fibers and insulation therefrom comprise two different glasses having differing coefficients of thermal expansion. The irregularly shaped dual-glass fibers are made from wool glass compositions with the addition of at least one of BaO, SrO, K.sub.2 O, Li.sub.2 O, ZnO, TiO.sub.2 and Fe.sub.2 O.sub.3.

Irregularly-shaped glass fibers and insulation therefrom comprising two different glasses having differing coefficients of thermal expansion. The irregularly-shaped dual-glass fibers exhibit a substantially uniform volume filling nature, and provide improved recovery and thermal conductivity abilities even in the absence of a binder material.

Irregularly-shaped glass fibers and insulation therefrom

Fiberizable glass composition with increased levels of BaO are suitable for insulation. These glasses have physical properties which allow current processes to fabricate them into insulation. The glasses also meet proposed German regulations regarding KI.gtoreq.40.

Glass compositions and fibers therefrom

Crystallization-resistant, low liquidus, fluoride glasses are disclosed which consist essentially of ZrF.sub.4, optionally HfF.sub.4, BaF.sub.2, at least one of CsF or NaF, preferably AlF.sub.3 and LaF.sub.3, and at least one of InF.sub.3, YF.sub.3 and GaF.sub.3. The glasses are of utility as optical components because of their high IR transmission.

Low liquidus, stable heavy metal fluoride glass compositions

Ion exchangeable glass compositions containing from 50 to 90 mole percent GeO.sub.2, from 5 to 30 mole percent Al.sub.2 O.sub.3, from 3 to 30 mole percent Li.sub.2 O, up to 30 mole percent Na.sub.2 O and up to 30 mole percent K.sub.2 O are provided. In another aspect, minor amounts of anhydrous fluorides and chlorides corresponding to these oxides are added to the glass compositions to aid in water removal. Glass articles formed of the germanate glass compositions of the present invention are readily ion exchangeable when contacted with certain salts. Strengthened germanate glass articles are also provided having an inner tension region and an outer compressive surface layer which provide good mechanical strength for the formed glass article. The strengthened germanate glass articles are made using the ion exchangeable germanate glass compositions of the present invention. The compressive surface layer of the strengthened germanate glass articles are formed by contacting the surface of the glass article with a suitable salt, preferably a molten alkali salt, in an ion exchange process. The surface compressive layer of the strengthened germanate glass article has a lower concentration of lithium ions than the inner tension region and has a higher concentration of select ions provided by the salt bath.

Ion-exchangeable germanate method for strengthened germanate glass

Provided is a process for making metal coated non-crystallized, amorphous glass fibers. The process fiberizes a glass containing a metal oxide such as cuprous oxide. The process then heat-treats the fibers to form a semi-conductive layer of copper oxide on the surface. A subsequent reactive reduction step produces a semi-continuous film of metallic copper. This is conductive enough for many radar applications.

Metal coated glass fibers

A method of removing boron from gases which comprises passing the gas stream in contact with solid sodium bicarbonate.

Method of removing boric oxide from flue gases

Fiberizable basalt compositions are disclosed. The fibers are produced from natural basalt rock modified with alkaline earth metal oxides. The fibers can be used to make low density composites for ceiling tile or boards.

Basalt compositions and their fibers

Disclosed is a process for preparing fluorescent inorganic glasses containing Nd.sub.2 O.sub.3 as a fluorescent species and containing MnO as a sensitizer but containing essentially no higher oxides of manganese. In the disclosed process an internal reducing agent is employed in the melting of the glass and such agent reduces the higher oxides of manganese upon cooling of the melt.

Method of making manganese sensitized neodymium fluorescent glasses

Fiberizable glass compositions are disclosed. The glass compositions are boron-free wool glasses which are useful as insulation. The glass batch used to prepare these glass compositions contains high amounts of iron oxide.

Growing community of inventors

Newark, OH, United States of America

Charles F Rapp