Digital Solid State Propulsion LLC

Aerojet-general Corporation

Charles E Grix

Arthur Katzakian

Wayne N Sawka

George Merrill Clark

A composition capable of producing either solid propellant grains, liquid or gel monopropellants, all of which are electrically ignitable and capable of sustained controllable combustion at ambient pressure. Additional compositions capable of sustained controllable combustion at elevated pressures are described. Applications for the compositions disclosed herein are provided, and include among other applications use in small micro thrusters, large core-burning solid propellant gains, shaped explosives charges for military application, and pumpable liquids and gel monopropellants or explosives for military, commercial mining or gas and oil recovery. In alternative embodiments the above compositions may also incorporate an energetic nitrate polymer, bum rate modifiers, and/or metal fuel(s). The HIPEP formulation makes it possible to ignite and sustain combustion at ambient and vacuum conditions (a) without continuous electrical power and (b) while providing faster bum rates.

Family of modifiable high performance electrically controlled propellants and explosives

Apparatus for providing electrically initiated and/or controlled combustion of electrically ignitable propellants is provided. In one example, the apparatus includes a volume of electrically ignitable propellant (liquid and/or gas) capable of self sustaining combustion, and electrodes operable to ignite the propellant. The apparatus may further include a power supply and controller in electrical communication with the electrodes for supplying a potential across the electrodes to initiate combustion of the propellant and/or control the rate of combustion of the propellant. Various configurations and geometries of the propellant, electrodes, and apparatus are possible. In one example, the electrodes are supplied a direct current, which causes combustion of the propellant at the positive electrode. In another example, the electrodes are supplied an alternating current, which initiates combustion of the propellant at both electrodes.

Electrode ignition and control of electrically ignitable materials

The present invention is an electrically controlled propellant comprising a binder, an oxidizer, and a cross-linking agent. The boric acid (the cross-linking agent) has been found to function as a cross-linking agent for the high molecular binder used to make the propellant, thereby improving the composition's ability to withstand combustion without melting. The present invention also may include 5-aminotetrazole (5-ATZ) as a stability-enhancing additive. The binder of the present invention may include polyvinylalcohol (PVA) and/or the co-polymer of polyvinylalcohol/polyvinylamine nitrate (PVA/PVAN).

Method for controlling a high performance electrically controlled solution solid propellant

A new process for forming MICs as well as three exemplary categories of MIC formulations is disclosed. MICs disclosed herein include a first exemplary category for which combustion can be initiated and sustained by either a heat (flame) source or electrical power, a second exemplary category of formulations that can be ignited and that sustain combustion at low pressures only with electrical power and a third exemplary category of formulations that can be ignited and extinguished at low pressures only with electrical power. The new process of MIC formulation provides energetic liquid oxidizers in place of traditional solvents, thus eliminating the need for solvent extraction. The energetic liquid oxidizer serves as a medium in which to suspend and grow the 3D nanostructure formed by the cross linked polymer (PVA). As a consequence, the 3D nanostructure entraps the liquid oxidizer, preventing it from evaporating and thereby eliminating the need for solvent extraction, preserves the 3D nanostructure shape. Further, the liquid oxidizer matrix produces provides a mechanism through which ignition and combustion may be controlled. The material combustion rate may be adjusted/throttled through adjustments in the amount electrical power supply and may even be extinguished by complete removal of the electrical power supply. Repeated on/off ignition/extinguishment is possible through repeated application and removal of electrical current.

Family of metastable intermolecular composites utilizing energetic liquid oxidizers with nanoparticle fuels in sol-gel polymer network

High performance electrically controlled solution solid propellant

Solid energetic compositions are prepared from powdered solid components such as metallic aluminum fuel and liquid oxidizers by forming a coating of polyvinyl alcohol over the powdered solid by precipitation from a solution of polyvinyl acetate, and combining the coated particles with liquid oxidizer which will permeate and swell the particle coating, causing the particles to agglomerate into a solid rubbery mass.

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Citrus Heights, CA, United States of America

Charles E Grix