Kraton Corporation

Kraton Chemical, LLC

Charles D Moses

Lloyd A Nelson

Gerald Heebner

Jeremie G Pichereau

Sara Frattini

The disclosure relates to viscosity improver concentrates comprising a bio-based liquid decarboxylated rosin acid as a solubilizer, and a viscosity index improver. The viscosity improver concentrate is used in lubricating oil compositions comprising base oil and optional additives. The decarboxylated rosin acid component has at least one or more of: one or more C═C groups, and 40-100 wt. % of tricyclic compounds having 18-20 carbon atoms; a sum of tricyclic compounds as aromatic and cycloaliphatic of 50-100 wt. %, based on total weight of the decarboxylated rosin acid; and an amount of cycloaliphatic compounds of 15-100 wt. %, based on total weight of the decarboxylated rosin acid. The viscosity improver concentrates comprising the solubilizer have comparable properties, including compatibility, kinematic viscosity, and viscosity index, to other commonly used fossil based solubilizers.

Lubricating oils with viscosity index improver concentrates

The disclosure relates to fuel compositions comprising a base fuel, a lubricity modifier, and optional additives, and methods for using same. The base fuel is a middle distillate having a sulfur content of <500 ppm. The lubricity modifier comprises a plant-derived liquid decarboxylated rosin acid and optionally at least one of a fatty acid, a fatty acid derivative, and mixtures thereof. The decarboxylated rosin acid has a flash point of 95-180° C., a density of 0.9 to 1.0 g/cm3 at 20° C., a viscosity of 15 to 60 cSt at 40° C., and an acid value of <50 mg KOH/g. The fuel compositions have desired tribological properties, such as wear scar diameter, coefficient of friction, and percent film, as well as cloud point performance.

Fuel composition with lubricity modifier

The disclosure relates to a lubricating composition consisting essentially of a decarboxylated rosin acid (DCR), a base oil, and optional additives, and methods for using same. The decarboxylated rosin acid has a density of 0.9 to 1.0 g/cm3 at 20° C., a viscosity of 15 to 60 cSt at 40° C., and an acid value of <50 mg KOH/g. The lubricating compositions containing the DCR is characterized as having improved anti-wear and friction reducing properties, as well as improved electrical properties, and cooling performance for use in electric and hybrid vehicles. In embodiments, the lubricating composition exhibits a wear scar diameter of <350 μm, according to ASTM D6079.

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Savannah, GA, United States of America

Charles D Moses