Advanced Softmaterials Inc.

Sumitomo Seika Chemicals Co., Ltd.

The University of Tokyo

Nissan Motor Company Limited

Toyoda Gosei Co., Ltd.

Fuji Manufacturing Co., Ltd.

Asm Inc.

Changming Zhao

Hiroki Okazaki

Yuki Hayashi

Mariko Suzuki

Tomoaki Yamasaki

Kohzo Ito

Tatsuya Suzuki

Shigeki Hamamoto

Shinya Okazaki

Minoru Iwata

Christian Ruslim

Keiji Mase

Jun Araki

Toru Kobayashi

Shozo Ishibashi

Masahiko Yamanaka

Hiromitsu Takeuchi

Akira Kimura

Kentarou Watanabe

Masatoshi Kidowaki

Junko Suda

Hirofumi Nakayama

Yuzo Sakurai

Yuki Amamoto

Tetsurou Kikugawa

Tetsurou Kigugawa

The present invention aims to provide an industrially advantageous method of producing a powdery pseudopolyrotaxane with a high inclusion ratio. The present invention relates to a method for producing a pseudopolyrotaxane, including: an inclusion step of mixing a polyethylene glycol and a cyclodextrin in an aqueous medium to form an aqueous dispersion of pseudopolyrotaxane that contains pseudopolyrotaxane particles in which the polyethylene glycol is included in the cavities of the cyclodextrin molecules in a skewered manner; and a drying step of drying the aqueous dispersion of pseudopolyrotaxane produced in the inclusion step to obtain the pseudopolyrotaxane. In the drying step, the aqueous dispersion of pseudopolyrotaxane is sprayed and dried in a heated gas-stream.

Method for producing pseudopolyrotaxane

The present invention aims to provide a method for producing a polyrotaxane which enables industrially advantageous production of a polyrotaxane with a high inclusion rate. The present invention relates to a method for producing a polyrotaxane that includes a cyclodextrin; a compound having a repeating structural unit represented by the following formula (1), and threading through a cavity of the cyclodextrin in a skewered manner to be included in the cyclodextrin; and capping groups individually placed at each end of a molecule of the compound having a repeating structural unit represented by the formula (1) to prevent the cyclodextrin from separating, the method comprising: a step 1 of mixing the compound having a repeating structural unit represented by the formula (1) and the cyclodextrin in an aqueous medium to prepare an aqueous dispersion of pseudopolyrotaxan particles in which the compound having a repeating structural unit represented by the formula (1) is included in a cavity of a cyclodextrin molecule in a skewered manner; and a step 2 of mixing a triazine compound represented by the formula (2), a compound having at least one tertiary amino group, the aqueous dispersion of pseudopolyrotaxane particles prepared in the step 1, and a capping agent to introduce capping groups individually at each end of a molecule of the compound having a repeating structural unit represented by the formula (1) in the pseudopolyrotaxane particles, wherein, in the formula (2), Rand Rare each independently a C1-C4 alkyl group or a C6-C8 aryl group, and X represents a halogen atom.

Method for manufacturing polyrotaxane

The present invention aims to provide an industrially advantageous method for producing an aqueous dispersion of pseudopolyrotaxane enabling to produce an aqueous dispersion of pseudopolyrotaxane having good fluidity and excellent dispersion stability of the pseudopolyrotaxane particles therein. The present invention relates to a method for producing an aqueous dispersion of pseudopolyrotaxane. The method includes: a mixing step of a dissolving polyethylene glycol and a cyclodextrin in an aqueous medium to prepare a mixed solution; and a cooling step of continuously or intermittently cooling the mixed solution in a state of flux to precipitate pseudopolyrotaxane particles. The pseudopolyrotaxane particles contain the polyethylene glycol which is included in the cavities of the cyclodextrin molecules in a skewered manner.

Method for producing pseudopolyrotaxane aqueous dispersion

The present invention aims to provide a polyrotaxane composition having excellent storage stability. The present invention relates to a polyrotaxane composition comprising: a polyrotaxane containing a cyclodextrin, a polyethylene glycol which is included in the cavities of the cyclodextrin molecules in a skewered manner, and a capping group that is placed at each end of the polyethylene glycol and prevents dissociation of the cyclodextrin molecules from the polyethylene glycol; and a polyphenol antioxidant.

Polyrotaxane composition

The present invention aims to provide a hydrophilic modified polyrotaxane composition having excellent storage stability. The present invention relates to a hydrophilic modified polyrotaxane composition comprising: a hydrophilic modified polyrotaxane produced by modifying, with hydrophilic modifying groups, all or part of hydroxy groups on a cyclodextrin of a polyrotaxane containing the cyclodextrin, a polyethylene glycol which is included in the cavities of the cyclodextrin molecules in a skewered manner, and a capping group that is placed at each end of the polyethylene glycol and prevents dissociation of the cyclodextrin molecules from the polyethylene glycol; and a polyphenol antioxidant.

Hydrophilic modified polyrotaxane composition

The present invention aims to provide an industrially advantageous method of producing a pseudopolyrotaxane with a high inclusion ratio. The present invention relates to a method for producing a pseudopolyrotaxane, including: an inclusion step of mixing a polyethylene glycol and a cyclodextrin in an aqueous medium to form an aqueous dispersion of pseudopolyrotaxane that contains pseudopolyrotaxane particles in which the polyethylene glycol is included in the cavities of the cyclodextrin molecules in a skewered manner; and a drying step of drying the aqueous dispersion of pseudopolyrotaxane produced in the inclusion step to obtain the pseudopolyrotaxane. In the drying step, the aqueous dispersion of pseudopolyrotaxane is dried in a thin film state.

The present invention aims to provide a method for producing a refined polyrotaxane which includes an industrially advantageous method of producing a polyrotaxane that has excellent storage stability. The method for producing a refined polyrotaxane includes the step of heat-cleaning a polyrotaxane with a cleaning medium, the polyrotaxane containing cyclodextrin molecules, a polyethylene glycol which is included in the cavities of the cyclodextrin molecules in a skewered manner, and a capping group that is placed at each end of the polyethylene glycol and prevents dissociation of the cyclodextrin molecules from the polyethylene glycol.

Method for producing refined polyrotaxane

There is provided a microparticle/polyrotaxane-containing coating with high abrasion resistance and chemical resistance. There are also provided a microparticle/polyrotaxane-containing coating film and a coated article. The microparticle/polyrotaxane-containing coating includes a solvent-based coating material, a modified polyrotaxane having a caprolactone modification group (&#x2014;CO(CH)OH) and microparticles having an average particle size of smaller than 380 nm. The microparticle/polyrotaxane-containing coating film is in the form of a layer of the microparticle/polyrotaxane-containing coating on an article to be coated. The coated article includes the microparticle/polyrotaxane-containing coating film and an article to be coated.

Microparticle/polyrotaxane&#x2014;containing coating, microparticle/polyrotaxane&#x2014;containing coating film and coated article

It is intended to provide a crosslinked polyrotaxane formed by crosslinking polyrotaxane molecules via chemical bonds which exhibits excellent optical properties in water or in an aqueous solution of sodium chloride; a compound having this crosslinked polyrotaxane; and a process for producing the same. The above object can be achieved by a crosslinked polyrotaxane having at least two polyrotaxane molecules, wherein linear molecules are included in a skewered-like state at the opening of cyclodextrin molecules and blocking groups are provided at both ends of the linear molecules, so as to prevent the cyclodextrin molecules from leaving, and cyclodextrin molecules in at least two polyrotaxane molecules being bonded to each other via chemical bond, characterized in that hydroxyl (&#x2014;OH) groups in the cyclodextrin molecules are partly substituted with non-ionic groups.

Compound having crosslinked polyrotaxane and process for producing the same

An abrasive that can impart a mirror finish, glossiness, or the like to a surface of a workpiece by blasting is provided. A crosslinked polyrotaxane compound having a network structure where crosslinking points are circular molecules of polyrotaxane and also having abrasive grains dispersedly mixed therein is obtained by causing chemical bonding between the circular molecules of the polyrotaxane in a state where the abrasive grains and the polyrotaxane are mixed. Then, the crosslinked polyrotaxane compound is granulated to a predetermined grain diameter to obtain a gel-like abrasive where a part of the dispersedly mixed abrasive grain is exposed at the surface. By using the thus-obtained gel-like abrasive in blasting by projecting the abrasive at an angle tilted with respect to a surface of a workpiece, mirror finishing or the like is possible without making the surface of the workpiece pearskin-like.

Process for producing gel-like abrasive material and gel-like abrasive material

An actuator includes a spirally rolled cylindrical sheet body. The sheet body is formed by attaching an electrode on each side of a dielectric elastomer layer. When a voltage is applied to the electrodes, the sheet body is contracted along the direction of its thickness, and expanded in directions perpendicular to its thickness. The actuator is actuated by applying a voltage to the electrodes and stopping the voltage application, so that the cylindrical sheet body is extended and contracted along the direction of the axis. The material forming the dielectric elastomer layer has a low strain region, where the value of a strain based on a stress acting on the dielectric elastomer layer varies from zero to a value that is greater than and close to zero, and a high strain region, where the value of the strain is greater than that in the low strain region. The Young's modulus in the low strain region is less than the Young's modulus in the high strain region.

Elastomer actuator

A process for producing a polyrotaxane in a high yield and at a satisfactory cost without using a large excess of a pseudopolyrotaxane and/or without using a large excess of an activated reagent. The process for polyrotaxane production comprises: an inclusion step in which a carboxylated polyethylene glycol which is a polyethylene glycol carboxylated at each end is mixed with cyclodextrin molecules to obtain a pseudopolyrotaxane which comprises cyclodextrin molecules which include the carboxylated polyethylene glycol in their cavities as if the cyclodextrin molecules are spitted with the carboxylated polyethylene glycol; and a capping step in which the pseudopolyrotaxane is reacted with capping groups having &#x2014;NHor &#x2014;OH to obtain a polyrotaxane terminated at each end by a &#x2014;CO&#x2014;NH-(capping group) or &#x2014;CO&#x2014;O-(capping group).

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Chiba, Japan

Changming Zhao