Shenzhen Capchem Technology Co., Ltd.

Chang'an Zeng

Qiao Shi

Muchong Lin

Shiguang Hu

Jiaojiao Yun

Xionggui Lin

A non-aqueous electrolyte for a lithium-ion battery and a lithium-ion battery. The non-aqueous electrolyte includes an unsaturated phosphate compound and a cyclic unsaturated carboxylic anhydride compound. The unsaturated phosphate compound has a structure represented by structural formula (4). R, Rand Rare each independently selected from a hydrocarbon group having 1 to 5 carbon atoms, and at least one of R, Rand Ris an unsaturated hydrocarbon group having a double bond or a triple bond. The unsaturated cyclic carboxylic anhydride compound having a structure represented by Structural Formula 5. Ris selected from the group consisting of an alkenylene group having 2 to 4 carbon atoms or a fluorinated alkenylene group having 2 to 4 carbon atoms. By means of the synergistic effect of two compounds, the non-aqueous electrolyte has excellent high-temperature cycling performance and storage performance, and also has lower impedance and good low-temperature performance.

Non-aqueous electrolyte for lithium-ion battery and lithium-ion battery

A non-aqueous electrolyte for a lithium-ion battery and a lithium-ion battery. The non-aqueous electrolyte comprises unsaturated phosphate compounds and unsaturated cyclic carboxylic acid anhydride compounds. The unsaturated phosphate compounds have the structure illustrated in structural formula 4; structural formula 4: R, R, and Rare independently selected from hydrocarbon groups having 1-5 carbon atoms respectively, and at least one of R, R, and Ris an unsaturated hydrocarbon group containing double bonds or triple bonds; the unsaturated cyclic carboxylic acid anhydride compounds have the structure illustrated in structural formula 5; structural formula 5: Ris independently selected from vinylidene having 2-4 carbon atoms or fluoro-substituted vinylidene. By means of the synergistic effect of two compounds, the non-aqueous electrolyte has excellent high-temperature cycling performance and storage performance, and also has lower impedance and good low-temperature performance. 

In order to solve the problem of poor cycle performance (especially high temperature cycle performance) of the existing lithium ion battery electrolyte containing anhydride or anhydride derivatives, the disclosure provides a non-aqueous electrolyte for lithium ion battery. The non-aqueous electrolyte for lithium ion battery comprises a compound A represented by formula I and a compound B represented by formula II,  In the structural formula I, Ris C2-C4 alkylene or alkenylene, or C2-C4 fluoroalkylene or fluoroalkenylene; In formula II, R, R, R, R, Rand Rare each independently selected from one of hydrogen atom, fluorine atom and C1-C5 group. The non-aqueous electrolyte for lithium ion battery provided by the invention is obtained by combining the compound A and compound B, so that the lithium ion battery containing the non-aqueous electrolyte has better cycle performance and high-temperature storage performance.

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Guangdong, China

Chang'an Zeng