Praxair Technology, Inc.

Other

Cem E Celik

Mark William Ackley

James Smolarek

Jeffert John Nowobilski

Arthur C Selover

Sesha Hari Vemuri

Matthias Grahl

Helko Schneider

James Stanley Schneider

Ashwin Desai

Salil Uday Rege

Ralph J Mancini

James R Handley

James R Dray

Ralph Joseph Mancini

Brian S Powell

Mohamed Hashi

Olivier Dube

Thomas A McNamara

Michael Victor Barsottelli

Devang Ashok Dasani

Richard C Cyganovich

A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers. Alternatively, the pre-purification systems and methods employ a hopcalite catalyst layer and a noble metal catalyst layer separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layer.

System for pre-purification of a feed gas stream

A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers.

Method and system for pre-purification of a feed gas stream

A system and method of regenerating a pre-purification vessel is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit that uses an oxygen-enriched purge gas stream for regeneration of the pre-purification unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the water, carbon dioxide and other impurities from a feed air stream, optionally including hydrogen and carbon monoxide impurities. The method of regenerating a pre-purification vessel preferably involves regenerating the pre-purification vessel with an oxygen-enriched purge gas after depressurization of the vessel and thereafter partially repressurizing the pre-purification vessel with an auxiliary purge gas thereby diluting the oxygen concentration of the gases contained in the pre-purification vessel and optionally depressurizing the partially repressurized vessel.

Method for regenerating a pre-purification vessel

The present invention relates to a method of controlling prepurifier cycle time by monitoring ambient COlevel in order to prevent CObreakthrough occurrences caused by extreme instantaneous variations in ambient COlevel. Rather than operating solely by prepurifier design bed capacity, the method of the invention continuously updates bed capacity for the contaminants using the feed temperature, pressure and contaminants composition, calculating the total amount of contaminants that were fed to the prepurifier during the feed step and estimates the perturbation front velocity, i.e., the velocity at which the contaminants front coming from an extreme instantaneous variations of ambient level is going to propagate inside the adsorbents bed. Estimating the perturbation front velocity allows for a more precise estimate of the maximum time remaining for the feed step before starting to experience CObreakthrough. This eliminates the need to switch the online bed unnecessarily early and risking shorter regeneration for the offline bed.

Control of swing adsorption process cycle time with ambient COmonitoring

In a cyclic adsorptive gas purification process, an impurity laden adsorbent is regenerated by exposing it first to an unheated gas for a pre-determined time period to desorb at least some of the impurity, followed by heating the adsorbent using a flowing stream of a heated gas to desorb the remaining impurities over another pre-determined time period, further followed by cooling of the adsorbent using a flowing stream of gas for yet another pre-determined time period to make it ready for repeating the adsorptive cycle. Introducing an unheated purge stream reduces the energy requirements for the regeneration step compared to a traditional TSA process.

Adsorbent regeneration method

The present invention relates generally to methods and systems for mixing at least two different solid materials (e.g., adsorbents) and loading the mixture into a vessel, such as an adsorption vessel or reactor.

Methods and systems for mixing material

Methods and systems for mixing materials

A modular and compact adsorbent bed structure is disclosed for use in an adsorption-based gas separation plant. The conventional adsorbent bed in a gas separation plant is replaced with a plurality of modular adsorbent bed units connected to make the adsorbent bed structure. The modular design requires lower fabrication and maintenance costs; is easier to transport; and is easier to load with adsorbent material.

Modular compact adsorption bed

The present invention relates generally to radial flow vessels and processes to achieve even fluid flow distribution through the bed during purification, separation or reaction processes. The radial bed vessel is designed such that the ratio of the cross-sectional flow areas of the flow channels is in proportion to the ratio of the mass flow rates of the process gas with the proportionality constant between 0.7 and 1.4. In addition, the channels each have a cross-sectional flow areas such that the pressure change within each channel is less than or equal to 10% of the pressure drop across the bed of active material under the process operating conditions for the particular gas employed.

Radial bed vessels having uniform flow distribution

A modular and compact adsorbent bed structure is disclosed for use in an adsorption-based gas separation plant. The conventional adsorbent bed in a gas separation plant is replaced with a plurality of modular adsorbent bed units connected to make the adsorbent bed structure. Modular adsorbent bed units of this invention provide higher capacity of product per unit volume of adsorbent material (i.e., increased adsorbent utilization) as compared to that obtained from conventional adsorbent beds. The modular design requires lower fabrication costs; is easier to transport; has less maintenance and repair requirements; and is easier to load with adsorbent material.

A radial flow reactor vessel is disclosed for use in gas purification, separation or reaction processes and most suitably used in prepurification processes. The reactor has internal baskets for confining a bed of active material. The baskets are rigidly supported at both the top and bottom ends of the reactor and have walls that are axially flexible and radially rigid. The vessel has multiple movable support columns designed to facilitate pre-stressing of the baskets to offset axial compressive loads induced from thermal cycling.

Radial flow reactor with movable supports

A radial flow reactor is disclosed for use in gas purification, separation or reaction processes and most suitably used in prepurification processes. The reactor has two concentric internal baskets which are rigidly supported at both the top and bottom ends of the reactor. The reactor has a removable section in the inner basket to accommodate rotating arms to dense load one or more layers of active materials between the concentric baskets.

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Grand Island, NY, United States of America

Cem E Celik