S.p.c.m. Sa

Snf Sa

University of Pittsburgh

Gcp Applied Technologies Inc.

Snf S.a.s.

Veolia Water Solutions & Technologies Support

Snf Group

Cedrick Favero

Christophe Rivas

Harold E Swift

Christopher C Capelli

Eric John Beckman

Lawrence L Kuo

Nathan A Tregger

Johann Kieffer

Morgan Tizzotti

Ludwig Gil

Mouloud Hendou

Camille Sagne

Christophe Roux

William Eamon Carroll

Nicolas Gaillard

Toby Chapman

Thierry Leblanc

Bruno Giovannetti

Trong Dang-Vu

Siham Telitel

Tody M Chapman

Dennis Marroni

Sylvain Darras

Amelia E Taylor

Scott Ramey

Frederic Daguerre

Bruno Giovanneti

Olivier Ratel

Pierrick Cheucle

Bruno Tavernier

Morgan Tizzoti

Alexandre Omont

The present invention is concerned with the treatment of produced water, that may be obtained from a chemically enhanced oil recovery process using viscosity-increasing polymeric compounds. Said treatment comprises particularly the steps of obtaining a produced water, such as from an oil-water mixture recovered from an oil-bearing formation, wherein the produced water comprises the viscosity-increasing polymeric compounds; and, of directing the produced water to a specific filtration device, and subjecting the produced water to filtration, for obtaining a retentate stream and a permeate stream. Said process allows particularly obtaining a permeate comprising the viscosity-increasing polymeric compounds, said permeate being substantially free of suspended solids, free oil and emulsified oil.

Treatment of produced water, particularly obtained from a chemically enhanced oil recovery process using viscosity-increasing polymers

The present invention is concerned with the treatment of produced water, obtained from a chemically enhanced oil recovery process using viscosity-increasing polymeric compounds. Said treatment comprises particularly the steps of obtaining a produced water, from an oil-water mixture recovered from an oil-bearing formation, wherein the produced water comprises the viscosity-increasing polymeric compounds; and, of directing the produced water to a specific filtration device, and subjecting the produced water to filtration, for obtaining a retentate stream and a permeate stream. Said process allows particularly obtaining a permeate comprising the viscosity-increasing polymeric compounds, said permeate being substantially free of suspended solids, free oil and emulsified oil.

Chemically enhanced oil recovery method using viscosity-increasing polymeric compounds

An apparatus for monitoring the effective dissolving of a polymer when the use region is not accessible. The apparatus includes a pipe on which are inserted, consecutively: a pump, a flowmeter, a water or brine inlet mechanism for diluting the mother solution flowing in the pipe, a mixer capable of in-line homogenization of the diluted mother solution, a first tube calibrated to simulate the distance and the conditions for moving the diluted solution in the main pipe between the point where the mother solution is diluted and the use region, a mechanism capable of reducing the pressure of the diluted solution flowing in the pipe upstream of the first tube that is calibrated from 10 to 10000 kPa (from 0.1 to 100 bar), a second calibrated tube for creating a head loss, and a device for measuring differential pressure between the inlet and the outlet of the second calibrated tube.

Device for in-line monitoring of the quality of a water-soluble polymer solution manufactured from invert emulsion or powder of said polymer

A composition for treating an aqueous suspension of mineral particles includes at least one water soluble polymer and at least one calcium salt, magnesium salt or both a Calcium salt and a Magnesium salt. The composition is in powder form.

Composition for treating suspensions of solid particles in water and method using said composition

The present invention provides methods and compositions for treating clay-bearing aggregates, particularly those used for construction purposes, whereby inclusion of fines is maximized due to minimization of clay washing which tends to remove such fines, and whereby performance of the aggregate-containing construction material is enhanced. Exemplary methods comprise introducing to clay a water-soluble, functionalized polyamine comprising a water-soluble polyamine formed by reacting an amine compound with an epoxy compound, the polyamine thus reacted being functionalized through the use of certain halide, sulfate, or epoxy compounds.

Functionalized polyamines for clay mitigation

A method for the assisted recovery of petroleum in a deposit by means of the introduction of an aqueous solution of a hydrosoluble polymer into the deposit is characterized in that the aqueous solution is prepared by dissolving a polymer-based composition containing at least one hydrosoluble polymer, at least one radical capturing agent, and at least one sacrificial agent, in an aqueous solution subjected to a step of treatment with at least one deoxygenating agent, prior to the introduction of the polymer-based composition.

Method for the assisted recovery of petroleum

This invention concerns a sampling procedure for an aqueous hydrosoluble polymer solution flowing in a main circuit, enabling a sample to be collected to undergo at least one analysis under ambient air giving at least one property of the hydrosoluble polymer characterised in that a stabilizing solution is added to the aqueous hydrosoluble polymer solution, according to a discontinuous addition method, before or after sampling from the main circuit, so as to obtain a sample comprising a mixture of aqueous hydrosoluble polymer solution and stabilizing solution in which the hydrosoluble polymer is protected against attacks it may undergo in an atmosphere containing at least 10% by volume of oxygen.

Sampling procedure for polymer-based solutions used in underground formations

Process for the enhanced recovery of oil comprising introducing into an injection fluid at least one linear or structured water-soluble copolymer obtained by polymerization of 2-acrylamido-2-methylpropane sulfonic acid monomer in free acid and/or salified form with acrylamide derivative monomers having the formula HC&#x2550;CR&#x2014;C(&#x2550;O)-A in which R is H or CHor CHCOOR', wherein R&#x2032; is an alkyl containing not more than 3 carbon atoms, and A is selected from the group consisting of 2-pyrrolidone, pyrrolidine and 4-morpholine, and injecting the injection fluid, which is then viscosified, into a reservoir, and thereafter recovering the aqueous and oily and/or gaseous mixture.

Process for the enhanced recovery of oil by injection of a polymer solution

New water treatment chemicals and corresponding water treatment or more generally aqueous systems treatment processes are provided, which greatly attenuate the NDMA problem, that is, decrease the formation of NDMA during the water or aqueous system treatment namely in the presence of a disinfectant, and decrease too the level of NDMA in the so treated water of aqueous system, and in the end products such as drinking water.

Functionalized cationic polyamines and their use to reduce the NDMA formation during the treatment of aqueous systems, and applications in the water treatment industry, including wastewater and drinking water treatment processes

Method for recovering bitumen from tar sands, according to which sands are brought into contact with at least one partially hydrolyzed poly(vinyl acetate) (co)polymer A.

Method for recovering bitumen from tar sands

A process to produce N-vinylformamide includes the steps of: reacting hydroxyethyl formamide with a reactant comprising at least one cyclic anhydride group to form an ester, and dissociating the ester via heat in a thin film evaporation to synthesize N-vinylformamide and a compound comprising at least one diacid group, the N-vinylformamide separating from the diacid during the thin film evaporation. The reactant including at least one cyclic anhydride group can, for example, be succinic anhydride, maleic anhydride, phthalic anhydride, (2-docecen-1-yl)succinic anhydride, exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride or a polymer including at least one cyclic anhydride group. A process to produce N-vinylformamide comprises the steps of: mixing acetaldehyde, formamide and a source of anhydride in a single reaction vessel, reacting the acetaldehyde, formamide and the source of anhydride in the reaction vessel under pressure, dissociating an ester formed by a reaction between the source of anhydride and hydroxyethyl formamide formed in the reaction vessel to synthesize N-vinylformamide and a compound comprising at least one diacid group.

Synthesis of N-vinylformamide

A process to produce N-vinylformamide includes the steps of: reacting hydroxyethyl formamide with a reactant including at least one cyclic anhydride group to form an ester, and dissociating (or cracking) the ester to synthesize N-vinylformamide and a compound including at least one diacid group. The ester can be dissociated using heat. The reactant including at least one cyclic anhydride group can, for example, be succinic anhydride, maleic anhydride, phthalic anhydride, a polymer including at least one cyclic anhydride group, or a solid support to which at least one cyclic anhydride group is covalently tethered. Preferably, the cyclic anhydride is regenerated from the diacid formed in the synthesis of the ester by heating the diacid to dehydrate the diacid. The temperature required to dehydrate diacid groups is preferably higher than the temperature use to dissociate the ester.

Synthesis of N-vinyl formamide

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Saint Romain le Puy, France

Cedrick Favero