Canon Kabushiki Kaisha

Leibniz-institut Fuer Neue Materialien Gemeinnuetzige Gmbh

Leibniz-institut Fur Neue Materialien Gemeinnutzige Gmbh

Universitaet Des Saarlandes

Leibniz-institut Fuer Neue Materialien Gemeinnuetzige Gesellschaft MIT Beschraenkter Haftung

Tenaris Connections B.v.

Universität Des Saarlandes

Inm - Leibniz-institut Für Neue Materialien Gemeinnützige Gmbh

Carsten Becker-Willinger

Helmut Schmidt

Norio Ohkuma

Etsuko Hino

Pamela Kalmes

Yoshikazu Saito

Mitsutoshi Noguchi

Akihiko Shimomura

Michael Veith

Hikaru Ueda

Gerhard Wenz

Sener Albayrak

Steffen Pilotek

Frank Hollmann

Devid Hero

Peter Müller

Oral Cenk Aktas

Jessica Hilschmann

Harley Eisenbarth

Gergely Kali

Marlon Jochum

Michael Opsoelder

Sabine Schmitz-Stoewe

Douglas Espin

Jessica Brunke

Budiman Ali

Gisela Heppe

Christoph Kasper

Emilie Marie Perre

Dirk Bentz

David Hafner

Peter-William De Oliveira

Nina Mueller

Martin Kluke

Akihiko Canon Kabushiki Kaisha Shimomura

Etsuko c/o Canon Kabushiki Kaisha Hino

Noguchi c/o Canon Kabushiki Kaisha Mitsutoshi

Saito c/o Canon Kabushiki Kaisha Yoshikazu

Norio c/o Canon Kabushiki Kaisha Ohkuma

Etsuko Canon Kabushiki Kaisha Hino

Norio Canon Kabushiki Kaisha Ohkuma

Hikaru Canon Kabushiki Kaisha Ueda

Michael OPSÖLDER

Sabine Schmitz-STÖWE

Teresa PÉREZ

Sabine Schmitz-Stowe

Michael Opsolder

Teresa Perez

Paolo Bortot

Maurizio Bellingardi

Géraldine Durand

Alan Taylor

Mirko Bukowski

A self-healing composite material includes at least one cross-linked polyrotaxane and at least one organically modified inorganic hybrid material which comprises functional groups (B) or at least one type of surface-modified inorganic particles which have functional groups (B) on their surface. The polyrotaxane is a cross-linked polyrotaxane and at least two of the threaded ring-shaped molecules are cross-linked by linking of the functional groups (A) and (B).

Nanostructured composite materials with self-healing properties

A highly structured composite material, which can be applied and cured as a protective layer on corroding metal substrates, particularly on steel is provided. Due to its highly structured composition it is a particularly effective barrier to protect metals against attack by corrosive substances such as hydrogen sulfide, carbon dioxide and sea water, if necessary under hydrothermal conditions. At the same time it is also abrasion stable, for example against a grinding effect by sand, as well as resistant to the impact of mechanical load e.g. by tools. This is achieved by a coating composition comprising a binder comprising at least one cross-linkable resin, wherein the resin comprises at least one of polar group; at least one type of hydrophilic flakes with an aspect ratio of more than 10, wherein the surface of the flakes at least partially comprises a metal oxide; and an organic solvent.

Highly structured composite material and process for the manufacture of protective coatings for corroding substrates

In one embodiment the invention relates to a method of preparing a polyrotaxane, said method comprising: performing a radical copolymerization of at least (a) a first polymerizable monomer having a stopper group, and of at least (b) a second polymerizable hydrophobic monomer, wherein said second monomer is complexed by a ring-shaped molecule, and of at least (c) a third polymerizable hydrophilic monomer; wherein during said copolymerization a copolymer threading said ring-shaped molecule is formed, wherein during said copolymerization said first monomer having a stopper group is incorporated into the chain of said copolymer at least partially between the ends thereof, and wherein said stopper groups prevent said ring-shaped molecule from disassembling from the copolymer; and wherein the amount of said first monomer having a stopper group is of from 0.1 mol % to 20 mol % based on 100 mol % of the total amount of polymerizable monomers. In another embodiment the invention relates to a method of preparing a polyrotaxane, said method comprising: performing a radical copolymerization of at least (a) a first polymerizable monomer having a stopper group, and of at least (b) a second polymerizable partially hydrophilic monomer, wherein said second monomer is complexed by a ring-shaped molecule, and wherein said second monomer has a solubility in water at 20&#xb0; C. of from 5 g/L to 40 g/L; wherein during said copolymerization a copolymer threading said ring-shaped molecule is formed, wherein during said copolymerization said first monomer having a stopper group is incorporated into the chain of said copolymer at least partially between the ends thereof, and wherein said stopper groups prevent said ring-shaped molecule from disassembling from the copolymer; and wherein the amount of said first monomer having a stopper group is of from 0.1 mol % to 20 mol % based on 100 mol % of the total amount of polymerizable monomers. Furthermore, the present invention relates to methods of preparing cross-linked polyrotaxanes and cross-linked polyrotaxanes which can be prepared using such methods. Thus, the present invention also relates to polyrotaxane and crosslinked polyrotaxanes. The invention also relates to products which contain the polyrotaxanes or cross-linked polyrotaxanes or which can be prepared from the polyrotaxanes or the cross-linked polyrotaxanes. The present invention further relates to the use of polyrotaxanes or cross-linked polyrotaxanes in various applications, such as the use as a self-healing material.

Method of preparing a polyrotaxane and polyrotaxane

Anisotropic zinc phosphate particles and zinc metal mixed phosphate particles having an orthorhombic crystal structure and a platelet-shaped particle morphology are obtained from a composition comprising at least one phosphate compound; at least one zinc compound and at least one chelate complexing agent having at least two oxygen-containing groups and at least one solvent.

Method for producing anisotropic zinc phosphate particles

A composition for producing a tribological composite material includes at least one platelet-shaped solid-state lubricant, at least one type of inorganic, platelet-shaped pigment particles, at least one surface-active compound which possesses at least one hydrophilic group and at least one hydrophobic group, and a curable binder system comprising at least one organic polymer or oligomer having one or more functional groups, or a precursor thereof.

Pigmented, Fine-Structured, Tribological Composite Material

The aim of the invention is to create a composition for coating electric conductors which is significantly more resistant to partial discharges than prior art compositions while the produced insulating layer is highly extensible. Said aim is achieved by a composition comprising 1 to 50 percent by weight of microparticles that have a specifically adjusted electronic defect structure in the crystal lattice, resulting in greater polarizability of the valence electrons, and an organic and/or organic-inorganic matrix. The microparticles that have a specifically adjusted electronic defect structure are composed of oxides, sulfides, selenides, tellurides of the elements which are part of the series encompassing silicon, zinc, aluminum, tin, boron, germanium, gallium, lead, the transition metals, lanthanides, and actinides, particularly from the series encompassing silicon, titanium, zinc, yttrium, cerium, vanadium, hafnium, zirconium, nickel, and/or tantalum, in such a way that the basic lattice is provided with vacant lattice positions by doping 4 the basic lattice with adequate low-valent or higher-valent elements, said vacant lattice positions increasing the electronic polarizability of the microparticles by means of defect chemistry (the defect structure).

Coating composition for electrical conductors and method of producing such a composition

The invention provides a composite composition comprising a cationically polymerizable organic resin, a cationic photoinitiator, a hydrolysate and/or condensate of at least one hydrolysable silane compound and inorganic nanoparticles. The composite composition is suitable for the preparation of patterned moulded articles or substrates having a patterned coating, in particular by photolithography. Micropatterns obtained show improved properties, such as a high shape stability and an excellent elastic modulus.

Composite composition for micropatterned layers

A polymerizable composite composition comprising a) a hydrolysate and/or condensate of at least one hydrolysable alkylsilane having at least one alkyl group, at least one hydrolysable arylsilane having at least one aryl group or at least one hydrolysable alkylarylsilane having at least one alkylaryl group, and at least one hydrolysable silane containing an epoxy group, b) at least one organic compound having at least 2 epoxy groups, and c) a cationic initiator, is suitable to provide, upon curing, substrates with a patterned coating or patterned molded articles. The patterned coatings and molded articles obtained show high relaxation ability, high chemical resistance and mechanical stability. Micropatterns can be obtained with high stability of shape.

Composite composition for micropatterned layers having high relaxation ability, high chemical resistance and mechanical stability

A composition comprising a blocked and/or unblocked isocyanate compound and surface-modified nanoscale solid particles that comprise on the surface thereof organic radicals which comprise groups with an active hydrogen or precursors of such groups.

Wear-resistant optical layers and moulded bodies

An ink jet head is formed with a nozzle surface having a liquid repellent characteristic. The nozzle surface comprises a condensation product made from a hydrolyzable silane compound having a fluorine containing group and a hydrolyzable silane compound having a cationic polymerizable group.

Ink jet head and its manufacture method

An ink jet recording head having a high durability and high ink resistance can enable high-quality image recording by employing a material capable of reducing the internal stress and having satisfactory patterning characteristics. Such an ink jet recording head can be produced with high precision. A cationically photopolymerizable resin composition containing a condensate of a hydrolysable organosilane compound, employed as a material for forming a flow path forming member, enables a reduction of internal stress and a highly precise pattern in the flow path forming member, thereby providing an ink jet recording head having high durability and high ink resistance and capable of high-quality printing over a prolonged time.

Ink jet recording head, producing method therefor and composition for ink jet recording head

A method for producing an ink jet recording head having high durability and high ink resistance can enabling enable high-quality image recording by employing a material capable of reducing the internal stress and having satisfactory patterning characteristics. Such an ink jet recording head can be produced with high precision. A cationically photopolymerizable resin composition containing a condensate of a hydrolysable organosilane compound, employed as a material for forming a flow path forming member, enables a reduction of internal stress and a highly precise pattern in the flow path forming member, thereby providing an ink jet recording head having high durability and high ink resistance and capable of high-quality printing over a prolonged time.

A cationically polymerizable composite coating composition comprising: a) a condensation product of at least one hydrolyzable silane having a fluorine-containing group, b) at least one cationically polymerizable organic resin, and c) a cationic initiator, provides, upon curing, substrates with an alkali-resistant, liquid-repellent coating. The composite coating composition may be used in pattern forming methods.

Liquid-repellent, alkali-resistant coating composition and coating suitable for pattern forming

A method for producing an ink jet recording head having high durability and high ink resistance can enable high-quality image recording by employing a material capable of reducing the internal stress and having satisfactory patterning characteristics. Such an ink jet recording head can be produced with high precision. A cationically photopolymerizable resin composition containing a condensate of a hydrolysable organosilane compound, employed as a material for forming a flow path forming member, enables a reduction of internal stress and a highly precise pattern in the flow path forming member, thereby providing an ink jet recording head having a high durability and a high ink resistance and capable of high-quality printing over a prolonged time.

Substrates with a biofilm-inhibiting coating comprising an inorganic condensate modified with organic groups, at least some of the organic groups of the condensate containing fluorine atoms and the coating comprising copper colloids or silver colloids.

Substrates having a biofilm-inhibiting coating

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Saarbruecken, Germany

Carsten Becker-Willinger