Basf Se Corporation

Basf Se (reitstötter, Kinzebach & Partner)

Carolin Limburg

Rocco Paciello

Hagen Wilmer

Torben Adermann

Daniel Loeffler

Falko Abels

Thomas Schaub

Marc Walter

Kerstin Schierle-Arndt

Felix Eickemeyer

Sean T Barry

Julia Strautmann

Florian Blasberg

Jan Gerkens

Sven Schneider

Monica Gill

Matthew Griffiths

Matthias Reiners

Daniel LÖFFLER

Séan Barry

The present invention is in the field of processes for the generation of thin inorganic films on substrates, in particular atomic layer deposition processes. The present invention relates to a process for the generation of inorganic films comprising depositing the compound of general formula (I) onto a solid substrate (I), wherein M is Mn, Ni or Co, X is a ligand which coordinates M, n is 0, 1, 2, 3, or 4, Ris an alkyl group, an alkenyl group, an aryl group, a halogen, or a silyl group, Ris an alkyl group, an alkenyl group, an aryl group, or a silyl group, p and q are 1 or 2, wherein p+q=3, and m is 1, 2, or 3.

Process for the generation of thin inorganic films

The present invention is in the field of processes for the generation of thin inorganic films on substrates, in particular atomic layer deposition processes. The present invention relates to a process comprising bringing a compound of general formula (I) into the gaseous or aerosol state and depositing the compound of general formula (I) from the gaseous or aerosol state onto a solid substrate, wherein R, R, R, and Rare independent of each other an alkyl group, an aryl group or a trialkylsilyl group, M is Mn, Ni or Co, X is a ligand which coordinates M, wherein at least one X is a neutrally charged ligand, m is 1, 2 or 3 and n is at least 1 wherein the molecular weight of the compound of general formula (I) is up to 1000 g/mol. 

The present invention is directed towards a catalyst which is obtainable by contacting in situ a ruthenium precursor and a phenol derivative. Furthermore, the present invention is directed towards the use of said catalyst in transfer hydrogenation reactions. In particular, the present invention is directed to a method for preparing menthone starting from isopulegol.

Ruthenium-phenol catalysts for transfer hydrogenation reactions

A process of bringing a compound of general formula (I) into the gaseous or aerosol state and depositing the compound of general formula (I) from the gaseous or aerosol state onto a solid substrate, wherein R, R, R, R, R, R, R, Rare independent of each other hydrogen, an alkyl group, an aryl group, or a trialkylsilyl group, R, R, R, Rare independent of each other an alkyl group, an aryl group, or a trialkylsilyl group, n is 1 or 2, M is a metal or semimetal, X is a ligand which coordinates M, and m is an integer from 0 to 3.

Ruthenium-phenol catalysts and method of preparing menthone from isopulegol

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Mannheim, Germany

Carolin Limburg