Snamprogetti S.p.a.

Agip Petroli S.p.a.

Carlo Rescalli

Luigi Gazzi

Alessandro Vetere

Alessandro Ginnasi

Antonio Pacifico

Giancarlo Cotone

Flavio Cianci

Roberto D'Ambra

Roberto Di Cintio

Domenico Sanfilippo

Alberto Paggini

Ivano Miracca

Gianfraco Soldati

Adriano Scazzosi

Riziero Ricci

Rocco Faraci

Stefano Catini

Ugo Melis

Maria A Scaramucci

Gianfranco Soldati

Process for the production of synthesis gas, by means of catalytic partial oxidation or autothermal reforming of light hydrocarbons, which comprises partially oxidizing the hydrocarbon with oxygen coming from the reduction of at least one metal oxide selected from hexavalent chromium oxide, supported on an inert carrier and modified with an alkaline and/or earth-alkaline metal, and metal oxides capable of autonomously sustaining the catalytic partial oxidation reaction by means of redox cycles.

Process for the production of synthesis gas

Improved yield process for urea synthesis by starting from ammonia and carbon dioxide, comprising a reaction zone under high pressure and temperature conditions, a section wherein a portion of unreacted ammonia and carbon dioxide are stripped and recycled to the reactor, which section operates under substantially the same reactor pressure, and a subsequent section, operating under medium and/or low pressure conditions, for urea purification and simultaneous recovery of residual carbon dioxide and a portion of residual ammonia contained in the effluent stream from the stripping section, as an aqueous solution of ammonium carbamate, in which said aqueous ammonium carbamate solution is either totally or partially fed to said stripping section. Said process makes it possible a conversion of carbon dioxide into urea to be obtained in the reactor which is higher than 70%.

High yield process for urea synthesis

The process claimed enables three separate streams to be obtained, from mixtures containing methanol, ethanol, n-propanol, isobutanol, water and other both low- and high-boiling compounds, of which one is anhydrous basically consisting of methanol and ethanol (I), one containing most of the n-propanol present in the mixture fed (II), together with small quantities of methanol, ethanol, isobutanol and water, and one containing most of the isobutanol and high-boiling compounds present in the above mixture (III), by the use of three rectifying columns, stream (I) being taken from a lateral point of the first column, stream (II) obtained from the head of the second column, stream (III) obtained from the bottom of the second column.

Process for obtaining separate streams of methanol and ethanol,

A process for the synthesis of urea starting from ammonia and carbon dioxide, comprising a reaction step carried out in at least two distinct operating zones basically at the same pressure, but having a different operating temperature, the difference being preferably between 5.degree. and 60.degree. C., and subsequent separation steps of the non-converted reagents, wherein a gaseous stream is transferred from the first zone, at a higher temperature, to the second zone, at a lower temperature, and a liquid stream, containing urea and/or ammonium carbamate, is transferred from the second zone to the first, so that said gaseous stream is preferably at least 5% by weight with respect to the stream effluent from the first zone to the subsequent separation steps. This process allows a ratio urea/(urea+carbamate), in the stream leaving said reaction step, of more than 70%, to be obtained.

Process for the synthesis of urea comprising two separate reaction zones

From a mixture containing methanol, ethanol, n-propanol, isobutanol water and other high-boiling and low-boiling compounds, the claimed process enables three separate streams to be obtained, one an anhydrous stream of methanol or methanol and ethanol (I), one containing most of the n-propanol present in the feed mixture (II), and one containing most of the isobutanol present in the feed mixture (III), by using three fractionating columns.

Process for separating alcohols from mixtures of alcohols, water and

A cryogenic process for the removal of acidic gases from natural or synthetic gases comprising preliminary cooling of the gas to condense a portion of the acidic gases contained in the gas, and contacting the cooled gas with a mixture of one or more organic selective solvents such as low molecular weight esters, alcohols and ethers and one or more organic compounds such as

Cryogenic process for the removal of acidic gases from mixtures of gases

A process is disclosed for the dehydration of a mixture of methanol and higher alcohols, containing 20 to 80% by weight of methanol, 1 to 60% by weight of at least a higher alcohol selected from those containing from 2 to 10 carbon atoms, 1 to 50% by weight of water and 0.1 to 10% by weight of hydrocarbons and/or of oxygen-containing organic compounds different from alcohols, which process comprises the following steps: p0 (a) feeding to a first rectification tower the mixture of methanol and higher alcohols to be dehydrated, a gaseous stream being discharged from the tower head, which contains a portion of the hydrocarbons and/or of the oxygen-containing organic compounds different from the alcohols; from a side point at a level higher than 2/3 of the tower height, a stream containing methanol and possibly ethanol being drawn; and from the tower bottom a stream being obtained with a methanol, and possibly ethanol, and having a content not larger than 10% by weight;

Process for dehydrating a mixture of methanol and higher alcohols

Cryogenic process for the removal of acidic gases from natural gases or from synthesis gases essentially comprising the absorption in one or more towers in order to reduce the content of acidic gases, a cooling carried out, in the case of one single absorber tower, upstream the same tower, or, in case of two absorber towers, between the same towers, a regeneration of the solvent or of the solvents used in the absorption, the solvent or the solvents used being selected among low molecular weight esters, alcohols and ethers, characterized in that with the solvent or solvents the gas outcoming from one or more of the absorber towers is mixed once or more times, the mixtures thus formed being then cooled, the solvent being thus separated from the same gas.

A cryogenic process is disclosed for the selective removal of acidic gases from natural gases or from synthesis gases by adsorption in two towers and cooling of the gas outcoming from the first tower to the purpose of condensing a portion of CO.sub.2 contained in the same gas, which is characterized in that in it a mixture is used constituted by one or more selective solvents selected among low molecular weight esters, alcohols and ethers.

Cryogenic process for the selective removal of acidic gases from

A process for removing acid gases from natural or synthesis gases by absorption, comprising the following stages:

Cryogenic process for removing acid gases from gas mixtures by means of

A cryogenic process for removing acid gases from natural or synthesis gases, comprising the following stages:

Cryogenic process for the selective removal of acid gases from gas

There is disclosed a process for selectively separating hydrogen sulfide from gaseous mixtures which also contain carbon dioxide by chemical absorption with a substantially anhydrous solution of a tertiary amine, such as methyl diethanolamine, and an auxiliary organic solvent, such as sulfolane.

Process of selective separation of hydrogen sulfide from gaseous

A process is described for stripping acidic gases, mainly hydrogen sulphide and carbon dioxide, from natural gas or synthesis gas, especially when the percentages of such acidic gases are high and the conventional processes become economically objectionable. The process is based on the use of a number of selective solvents, generally belonging to the class of esters, ethers, mixed ester-ethers and lactones, in combination with sequential absorbing cycles which start from the stripping of hydrogen sulphide, and comprise the regeneration of the solvents used by several expansion cycles: H.sub.2 S and CO.sub.2 are recovered and the regenerated solvents recycled.

Cryogenic process for fractionally removing acidic gases from gas

Low temperature treatments are combined with solvent treatments using particularly selective solvents for stripping acidic gases such as carbon dioxide and hydrogen sulphide from natural gas or from synthetic gases. The preferred solvents are a wide range of compounds having an esteric or an etheric function in their molecule, but there are also examples of compounds which have the two functions simultaneously. The stripping process is comparatively simple, is efficient, especially for high contents of acidic gases in the raw gas streams, and is economically acceptable.

Growing community of inventors

San Donato Milanese, Italy

Carlo Rescalli