Euteco, S.p.a.

Carlo Collu

Renzo Invernizzi

Ferdinando Ligorati

Maurizio Fontanesi

A Ziegler catalytic system comprising an organometallic compound of a metal of Groups I to III of the Periodic Table and a compound of a heavy metal of Groups IV to VI supported on a carrier, the latter being an activated amorphous alumina or alumino-silicate containing from 0.3 to 30% by weight of salts of metals of Groups IIb, IIIa, VIb and VIII with oxygenated inorganic anions, or of a mixture of the latter with salts of said metals of Groups IIb, IIIa, VIb and VIII with non-oxygenated inorganic anions, said salts being introduced into the carrier by contacting the latter with one or more solutions of said salts and the carrier being then activated by calcination at 250.degree.-700.degree. C.

Ziegler catalysts

Ziegler catalytic system comprising an organo-metallic compound of a metal of Groups I to III of the Periodic System and a compound of a heavy metal of Groups IV to VI supported on an alumina carrier, the latter being an activated amorphous alumina containing from 0.3 to 30% by weight of salts of aluminum with oxygenated inorganic anions, or of a mixture of the latter with salts of aluminum with non-oxygenated inorganic anions, said carrier being prepared by precipitating an alumina gel at a pH value of 7-10, introducing the inorganic anions into said gel, drying said gel and calcining the resulting amorphous alumina at 250.degree.-700.degree. C.

Ziegler catalytic system comprising an organo-metallic compound of a metal of Groups I to III of the Periodic Table and a compound of a heavy metal of Groups IV to VI supported on a carrier, the latter being an activated amorphous alumina or alumino-silicate containing from 0.3 to 30% by weight of salts of aluminum with oxygenated inorganic anions, or of a mixture of the latter with salts of aluminum with non-oxygenated inorganic anions, said inorganic anions being introduced into the amorphous alumina or alumino-silicate by contacting the latter with one or more acid solutions of the inorganic anions and the carrier being then activated by calcination at 250.degree. - 700.degree. C.

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Milan, Italy

Carlo Collu