Eastman Chemical Company

Novamont S.p.a.

Candace Michele Tanner

Marcus David Shelby

Michael Eugene Donelson

Wesley Raymond Hale

Kenneth E Conley

Freddie Wayne Williams

Mark Elliott Tincher

Rondell Paul Little, Jr

Thomas Joseph Pecorini

Peter Borden Mackenzie

Scott Ellery George

Douglas Stephens McWilliams

Ted Germroth

Scott Clear

Spencer Allen Gilliam

Marc Alan Strand

Wayne Ken Shih

Jeffrey Todd Owens

Rodney Layne Piner

Gary Robert Robe

Kevin Douglas Horton

Joshua Seth Cannon

Andrew Joseph Matosky

Jennifer Lynne Stikeleather-Peavey

William LeRoy Wortman

David B Calvert

Ted Calvin Germroth

Self-corrugating laminates useful in the manufacture of thermoelectric devices are disclosed. The laminates include an upper and a lower shrinkable film layer and a non-shrinkable core with a thermoelectric pattern formed thereon bonded between said upper and lower shrinkable film along bond lines arranged parallel, substantially parallel, radially, or annularly. The bond lines that bond the upper shrinkable film layer to top surface of the nonshrinkable core are staggered relative to the bond lines that bond the lower shrinkable film layer to the bottom surface of the non-shrinkable core such that upon shrinkage of the shrinkable film layers, structural corrugations are formed in the non-shrinkable core. Thermoelectric modules or devices and methods for forming them from the self-corrugating laminates are also described.

Self-corrugating laminates useful in the manufacture of thermoelectric devices and corrugated structures therefrom

Disclosed are void-containing polyester shrink films which show excellent density retention upon exposures to high temperatures. The films have high shrinkage and retain their low density after processing under conditions of temperature and moisture used in typical recycling processes. The films are useful for sleeve label and other shrink film applications, and their lower density allows them to be readily separated from soft drink bottles, food containers and the like during recycling operations. Also disclosed is a process for void-containing polyester shrink films having high shrinkage and low density after exposure to elevated temperatures.

Void-containing polyester shrink film with improved density retention

Disclosed are hot-melt adhesives prepared from aromatic-aliphatic polyesters containing terephthalic acid in combination with adipic acid, glutaric acid, or a mixture thereof, as diacid components and a diol component containing 1,4-butanediol, 1,6-hexanediol, or a combination thereof. These adhesives set up rapidly within a well-defined temperature window. The hot-melt adhesives can be used in a variety of applications, but are especially suited as seaming adhesives for roll-applied labels. These adhesives have melting temperatures and crystallization properties that allow their application at temperatures cool enough to prevent curling and premature shrinkage of the shrink label during seaming, and yet produce strong label seams that can withstand the elevated temperatures of a shrink tunnel without sacrificing line speed. Also disclosed are labeled containers and a process for applying a roll-on, shrink label to a container using the hot-melt adhesives of the invention.

Aromatic-aliphatic polyester hot melt adhesives for roll-applied labels

Disclosed is a biaxially-oriented polyester film produced from a polyester comprising: (1) diacid residues comprising between about 95 and about 100 mole percent of terephthalic acid residues; (2) diol residues comprising between about 95 and about 100 mole percent of 1,4-cyclohexanedimethanol residues; and (3) about 0.5 to about 5 mole percent of another dicarboxylic acid or diol residue, wherein the polyester comprises a total of 100 mole percent diacid residues and a total of 100 mole percent diol residues. In one embodiment, the biaxially-oriented film has a thickness of 70 to 150 microns (3-5 mils). In another embodiment, the biaxially-oriented film undergoes not more than 3% shrinkage when immersed for 10 seconds in a solder bath preheated to 260&#xb0; C. The film can be made by stretching an essentially amorphous cast film of thickness between about 450-1800 micron (18-70 mil) at a ratio from about 2.5&#xd7;2.5 to 3.5&#xd7;3.5 while being held at a temperature between 90&#xb0; C. and 130&#xb0; C., and heat-setting the stretched film at an actual film temperature of from 260&#xb0; C. to Tm, where Tm is the melting point of the polyester as measured by differential scanning calorimetry (DSC), while maintaining the dimensions of the stretched film.

Biaxially oriented copolyester film and laminates thereof

This invention relates to a blend of biodegradable polymers comprising:

Polymer blends with improved rheology and improved unnotched impact strength

Disclosed are high clarity films produced from semicrystalline polyesters by calendering. These films unexpectedly develop a higher peak melting point, which leads to higher thermal resistance. The semicrystalline polyesters may be biodegradable. When these calendered films are oriented, they develop unexpectedly high physical strength or clarity in comparison to films that are prepared by conventional techniques.

High clarity films with improved thermal properties

Disclosed are blends of aliphatic-aromatic copolyesters with poly(ethylene-co-vinyl acetate) copolymers and shaped articles prepared therefrom. These blends have higher melt strength than the aliphatic-aromatic copolyester alone and exhibit increased melt strength and better processability. In addition, the blends and shaped articles show bio-disintegration and/or biodegradability in a composting environment.

Blends of aliphatic-aromatic copolyesters with ethylene-vinyl acetate copolymers

Polymer blends with improved notched impact strength

A compositional blend of from about 50 to about 99 weight percent of a polyester and from about 1 to about 50 weight percent of an essentially, linear, random aliphatic-aromatic copolyester or branched and/or chain extended copolyester thereof is useful as a heat-shrinkable film.

Polyester blends and heat shrinkable films made therefrom

A two-dimensional display having a three-dimensional visual appearance has printed on a substantially flat or planar surface a predetermined message or information. Superposed over the message is a lenticular lens. Adjacent to the message are a series of spaced apart lines which may either be coplanar or non-coplanar relative to the message. The spaced apart lines are arranged so that they are in a non-registration relationship with the spacing of individual lenticules forming the lenticular lens. The display produces an appearance of having the lines float or move as a viewer's focal angle or perspective of the display changes. A method for making such a display is also provided.

Multi-layer display having combination of visually moveable and stationary elements therefore

A reactor grade copolyester composition, as well as a heat-shrinkable film made therefrom, unexpectedly has higher ductility than a multi-component blend of copolyesters with the same monomer concentrations. The reactor grade copolyester composition is made from a diacid component of at least about 90 mole percent and a diol component of (a) about 72 to about 88 mole percent ethylene glycol, about 10 to about 15 mole percent 1,4-cyclohexanedimethanol, and about 2 to about 13 mole percent diethylene glycol, or (b) about 59 to about 77.5 mole percent ethylene glycol, about 15 to about 28 mole percent 1,4-cyclohexane-dimethanol, and about 7.5 to about 13 mole percent diethylene glycol. Further, the heat-shrinkable film may be produced to closely match the shrink characteristics of polyvinyl chloride by varying the amounts of the diol components of the reactor grade copolyester composition. Furthermore, a reactor grade copolyester composition has a b* color value of &minus;1.0 to less than 4.5, wherein the diacid component is at least about 90 mole percent terephthalic acid and the diol component is about 52 to about 88 mole percent ethylene glycol, about 10 to about 28 mole percent 1,4-cyclohexane-dimethanol, and about 2 to about 20 mole percent diethylene glycol.

Reactor grade copolyesters for shrink film applications

Display having combination of visually moveable and stationary elements and process for making the same

Growing community of inventors

Kingsport, TN, United States of America

Candace Michele Tanner