Lg Chem, Ltd

Byoung-Bae Lee

Jae-Seung Oh

Sang-Hyun Lee

Sang-Ki Chun

Won-Jong Kwon

Suk-Ky Chang

Hyo-Jin Lee

Sang-Ho Kim

Dong-Su Kim

Ji-Won Park

Yeon-Suk Hong

Shin-Jung Choi

Jae-Duk Park

Jang-Bae Kim

Sang-Kyun Lee

Ji-Hye Yang

Bok-Kyu Choi

Kwon-Young Choi

Kyoung-Ho Kim

Jae Seung Oh

Jin-Young Park

Sei-Woon Oh

Shin Jung Choi

Bong-Hyun Jeong

Jae-Hoon Jung

Ki-Young Kwon

Young-Kyu Han

Dong-Han Kho

Ki-Seok Jang

Kyung-Hwan Jung

Hye-Yeong Sim

You-Jin Shim

Jiwon Park

Jaeduk Park

Jung-Bae Park

Su-Jin Mun

Disclosed is a non-aqueous electrolyte for a lithium secondary battery and a lithium secondary battery comprising the same. The non-aqueous electrolyte including an ionizable lithium salt and an organic solvent may further include (a) 1 to 10 parts by weight of a compound having a vinylene group or vinyl group per 100 parts by weight of the non-aqueous electrolyte, and (b) 10 to 300 parts by weight of a dinitrile compound having an ether bond per 100 parts by weight of the compound having the vinylene group or vinyl group. The lithium secondary battery comprising the non-aqueous electrolyte may effectively suppress the swelling and improve the charge/discharge cycle life.

Non-aqueous electrolyte for lithium secondary battery and lithium secondary battery comprising the same

The present disclosure relates to an electrode that may minimize an electrical resistance increase caused by a binder polymer or a conductive material used in the electrode and provide a high capacity, a method for manufacturing the same, and an electrochemical device comprising the electrode, and an electrode mix slurry is prepared using a high shearing mixing process for each step such that fine grained conductive material and a binder polymer are uniformly dispersed in an electrode mix, and a high capacity electrode active material is used in the electrode mix, to manufacture a high capacity electrochemical device.

Electrode for electrochemical device with low resistance, method for manufacturing the same, and electrochemical device comprising the electrode

Disclosed is an electrolyte comprising (a) a eutectic mixture of an amide compound represented by the following chemical formula 1 or 2 and an ionizable lithium salt; and (b) a nitrile compound. The eutectic mixture and the nitrile compound in the electrolyte contribute to excellent thermal and chemical stability and sufficiently low viscosity and high ion conductivity. The electrolyte can be usefully applied as an electrolyte of electrochemical devices.

Electrolyte having eutectic mixture and nitrile compound, and electrochemical device containing the same

An electrolyte includes an eutectic mixture composed of (a) a hetero cyclic compound having a predetermined chemistry figure, and (b) an ionizable lithium salt. An electrochemical device having the electrolyte. The eutectic mixture included in the electrolyte exhibits inherent characteristics of an eutectic mixture such as excellent thermal stability and excellent chemical stability, thereby improving the problems such as evaporation, ignition and side reaction of an electrolyte caused by the usage of existing organic solvents.

Electrolyte having eutectic mixture of hetero cyclic compound and lithium salt and electrochemical device containing the same

The present disclosure relates to a method for prelithiation, and in particular, to a method for prelithiation that predopes lithium into at least one unit cell uniformly in large amounts. According to an aspect of the present disclosure, there is provided a method for prelithiation including an preparing at least one unit cell, the unit cell comprising a cathode, an anode, and a separator interposed between the cathode and the anode, disposing the prepared at least one unit cell in a reaction tank, and connecting electrodes having the same polarity, adding an electrolyte solution into the reaction tank, disposing a lithium metal plate in the electrolyte solution, and connecting the lithium metal plate to the anode, and doping the anode.

Method for prelithiation, method for fabricating lithium secondary battery comprising the method, and lithium secondary battery fabricated from the fabricating method

The present disclosure relates to an anode active material-containing slurry, an anode using the slurry, and an electrochemical device comprising the anode. More specifically, the present disclosure relates to a slurry comprising an anode active material; a polymer binder comprising styrene butadiene rubber and potassium polyacrylate; a conductive material; and a dispersing medium, an anode using the slurry, and an electrochemical device comprising the anode. The anode active material-containing slurry according to one aspect of the present disclosure can relieve the volume expansion of an anode active material by the intercalation and disintercalation of lithium during cycles of electrochemical devices to improve the durability of an anode active material layer, thereby enhancing the life characteristics of the electrochemical devices, and can form an anode active material layer having a high peeling force even though potassium polyacrylate with a relatively lower weight-average molecular weight is used.

Anode active material-containing slurry, anode using the slurry and electrochemical device comprising the anode

The present disclosure relates to a binder solution for an anode, comprising a thermally cross-linkable polymer binder that is cross-linked by heat, and a solvent for dissolving the thermally cross-linkable polymer binder, and exhibiting a concentration of hydrogen ions corresponding to pH 2.5 to pH 4.5; an active material slurry for an anode, comprising the binder solution; an anode using the slurry; and an electrochemical device comprising the anode. The binder solution for an anode according to one aspect of the present disclosure can relieve the volume expansion of an anode active material by the intercalation and disintercalation of lithium during cycles of electrochemical devices to improve the durability of an anode active material layer, thereby enhancing the life characteristics of the electrochemical devices, and also can provide good dispersibility to the active material slurry for an anode, thereby improving the coating stability of an anode active material layer.

Binder solution for anode, active material slurry for anode comprising the binder solution, anode using the slurry and electrochemical device comprising the anode

Disclosed is a method for preparing a dinitrile compound. The method includes reacting an alcohol compound with a nitrile compound having a terminal carbon-carbon unsaturated bond under anhydrous conditions. A potassium alkoxide having 1 to 5 carbon atoms is used as a catalyst in the course of the reaction. According to the method, a high-purity dinitrile compound can be prepared in a simple manner within a short reaction time indicating high productivity.

Method for preparing dinitrile compound

Provided are an electrolyte comprising an amide compound of a specific structure, in which an alkoxy group is substituted with an amine group, and an ionizable lithium salt, and an electrochemical device containing the same. The electrolyte may have excellent thermal and chemical stability and a wide electrochemical window. Also, the electrolyte may have a sufficiently low viscosity and a high ionic conductivity, and thus, may be usefully applied as an electrolyte of electrochemical devices using various anode materials.

Electrolyte comprising amide compound and electrochemical device containing the same

An electrolyte includes a eutectic mixture comprising (a) an alkoxy alkyl group-containing amide compound having a specific chemistry formula 1 or 2: 

Electrolyte having eutectic mixture and electrochemical device containing the same

Disclosed is a non-aqueous electrolyte solution for a lithium secondary battery. The non-aqueous electrolyte solution includes a lithium salt, an organic solvent and additives. The additives include: 1 to 10% by weight of a mixture of a particular halogenated cyclic carbonate and a compound containing a vinylene or vinyl group; and 0.1 to 9% by weight of a nitrile compound having a C-Calkoxyalkyl group. A lithium secondary battery including the non-aqueous electrolyte solution is also disclosed. The lithium secondary battery is protected from catching fire when overcharged and is prevented from swelling during storage at high temperature.

Non-aqueous electrolyte solution for lithium secondary battery and lithium secondary battery including the same

Disclosed is an electrolyte for a secondary battery, comprising an eutectic mixture consisting of: (a) am amide group-containing compound with at least one EDG introduced into the N-position thereof; and (b) an ionizable lithium salt. Also, provided are a secondary battery comprising such an electrolyte, and a method of adjusting an electrochemical stability window of an eutectic mixture consisting of an amide group-containing compound and a lithium salt by regulating electron donating properties of at least one substituent group introduced into the N-position of the amide group-containing compound.

Electrolyte comprising eutectic mixture and secondary battery using the same

Disclosed is an electrolyte. The electrolyte includes an amide compound and an ionizable lithium salt. The amide compound has a specific structure in which an amine group is substituted with at least one alkoxyalkyl group and at least one halogen atom is present. The electrolyte has good thermal and chemical stability, a low resistance and a high ionic conductivity. In addition, the electrolyte has a high upper limit of electrochemical window due to its improved oxidation stability. Therefore, the electrolyte can be useful for the fabrication of an electrochemical device. Further disclosed is an electrochemical device including the electrolyte.

Electrolyte including amide compound and electrochemical device including the same

Disclosed is a secondary battery including a cathode, an anode, a separator, and an electrolyte, wherein the electrolyte includes a ternary eutectic mixture prepared by adding (c) a carbonate-based compound to a eutectic mixture containing (a) an amide group-containing compound and (b) an ionizable lithium salt, and the carbonate-based compound is included in an amount of less than 50 parts by weight based on 100 parts by weight of the electrolyte. The use of the disclosed ternary eutectic mixture having flame resistance, chemical stability, high conductivity, and a broad electrochemical window, as the electrolyte material, improves both the thermal stability and quality of the battery.

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Daejeon, South Korea

Byoung-Bae Lee