Petrochina Company Limited

East China University of Science

Buwei Yu

Yali Wang

Libo Wang

Sihan Wang

Xiuhui Wang

Fuling Huang

Xuemei Han

Tong Liu

Yan Jiang

Qian Chen

Xianming Xu

Yulong Wang

Baojun Zhang

Guizhi Wang

Hongling Chu

Shukun Sun

Deshun Zhang

Enhao Sun

Gang Wang

Jiabo Qu

Hongliang Huo

Yuanyuan Cao

Kecun Ma

Yu Wang

Min Liu

Ning Zhang

Sheng Xu

Han Gao

Peng Wei

Jianzhong Li

Hua Li

Huaiqi Shao

Fengrong Wang

Weihong Guan

Yunguang Han

Dongmei Niu

Wenchao Zhang

Gongchen Yan

Puke Mi

Jinhua Qian

Ruhai Lin

Panfeng Lu

Yuxin Gao

Ling Jiang

Lingting Fan

Guiyue Guo

Legang Feng

Zhonghua Yang

The present invention provides a low viscosity poly-&#x3b1;-olefin lubricating oil and a synthesis method thereof. The method comprises: (1) the &#x3b1;-olefin raw material is subjected to dehydration treatment so that the water content in the raw material is &#x2264;10 ppm; (2) a reaction of the dehydration treated &#x3b1;-olefin raw material is carried out in the presence of a complex catalyst and gaseous BFto obtain a reaction product, wherein the pressure of the gaseous BFis 0.01 to 1 MPa; (3) the reaction product obtained in step (2) is sequentially subjected to flash distillation, gas stripping, centrifugation, and washing treatment to obtain an intermediate product; (4) the intermediate product obtained in step (3) is subjected to distillation under reduced pressure to separate the unreacted &#x3b1;-olefin raw material and &#x3b1;-olefin dimers, and the remaining heavy fractions are subjected to hydrogenation saturation treatment followed by fractionation and cutting-off.

Low viscosity poly-a-olefin lubricating oil and synthesis method thereof

The present disclosure provides a method and a catalyst for selective oligomerization of ethylene. The raw material for the catalyst consists of a dehydropyridine annulene-type ligand, a transition metal compound, and an organometallic compound in a molar ratio of 1:0.5-100:0.1-5000. The present disclosure also provides a method for selective oligomerization of ethylene accomplished by using the above-mentioned catalyst. The catalyst for selective oligomerization of ethylene has high catalytic activity, high selectivity for the target products 1-hexene and 1-octene, and low selectivity for 1-butene and 1-C.

Method and catalyst for selective oligomerization of ethylene

A catalyst for synthesizing 1-hexene from ethylene trimerization and its application are provided. Said catalyst consists of (a) the compound containing P and N, (b) electron donor, (c) Cr compound, (d) carrier and (e) accelerator. The molar ratio of (a), (b), (c), (d) and (e) is 0.5-100:0.5-100:1:0.5-10:50-5000. The catalyst is prepared by mixing the components of (a)-(e) in an ethylene trimerization apparatus in situ and ethylene is introduced into the apparatus continuously. The prepared catalyst can be used to synthesize 1-hexene from ethylene trimerization in the inert solvents. The trimerization is performed at 30-150&#xb0; C. and 0.5-10.0 MPa for 0.1-4 hours. The catalyst has high catalytic activity and high 1-hexene selectivity. During the process of ethylene trimerization, by-product polyethylene does not stick to the apparatus.

Catalyst or synthesizing 1-hexene from ethylene trimerization and application thereof

A method for synthesis of 1-decene oligomer is provided, wherein 1-decene is polymerized at 80-120&#xb0; C., 0.8-1.4 MPa in the presence of aluminum trichloride catalyst supported on gamma-alumina and n-hexane solvent where the volume ratio of 1-decene to n-hexane is 3:8-4:1. The catalyst is treated as follows: impregnating gamma-alumina carrier in 0.5-2.0 M of hydrochloric acid, sulfuric acid, nitric acid or mixtures thereof, then vacuum drying at 80-100&#xb0; C. and calcining at 400-800&#xb0; C.; dissolving 5-10 g of anhydrous aluminum trichloride in 100 ml of tetrachloromethane, trichloromethane or dichloromethane solvent; adding the obtained solution into 10-20 g of activated alumina carrier and obtaining the catalyst after vacuum drying. The conversion of 1-decene is 50 wt % or more. The oligomer has a kinematic viscosity at 40&#xb0; C. of 6.0-25 mm/s and a viscosity index of 160-262.

Method for synthesis of 1-decene oligomer

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Beijing, China

Buwei Yu