Ecolab Inc.

Ecolab USA Inc.

Burton M Baum

Steven Eugene Lentsch

Victor F Man

Michael Bartelme

Terence P Everson

Kim R Smith

Keith Edward Olson

Howie Kestell

Thomas R Oakes

Dale W Groth

Michael J Bartelme

Terrence Phillip Everson

Howie Kestel

A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. The relative amounts of the source of zinc ion and the source of aluminum ion can be controlled to reduce visible filming when the warewashing detergent composition is used in the presence of hard water. Methods for using and manufacturing a warewashing detergent composition are provided.

Warewashing composition comprising a Zn/Al corrosion inhibitor for use in automatic dishwashing machines

Warewashing composition for use in automatic dishwashing machines, and methods for manufacturing and using

A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use solution having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. Methods for using and manufacturing a warewashing detergent composition are provided.

Warewashing composition for use in automatic dishwashing machines comprising an aluminum/zinc ion mixture

Warewashing composition comprising zinc and aluminum ions for use in automatic dishwashing machines

Warewashing composition comprising a corrosion inhibitor with Al and Zn ions

Warewashing composition for use in automatic dishwashing machines, comprising a zinc ion and aluminum ion corrosion inhibitor

Warewashing composition for use in automatic dishwashing machines, comprising a mixture of aluminum and zinc ions

The invention includes compositions and methods for sanitizing ware without staining, spotting or corroding. In its most preferred mode, the method comprises the steps of washing the ware in an automated ware washing machine and rinsing the ware at either high or low temperatures with a sanitizing rinse composition. The destaining, sanitizing concentrate composition preferably comprises peroxyacetic acid, acetic acid, and hydrogen peroxide using higher levels of acetic and peroxyacetic acid and a lower level of hydrogen peroxide. The sanitizing rinse composition may preferably be used at a concentration of peroxyacetic acid of at least 30 ppm.

Precarboxylic acid rinse method

Nonionic surfactants comprising a mixture of fatty acid esters of sorbitol and sorbitol anhydrides comprising predominantly the mono, di- or tri ester condensed with approximately 15 or more moles of an alkylene oxide in combination with an effective defoamer and a water soluble diluent form surprisingly useful and effective low foaming rinse agent composition or concentrate. The rinse agent can achieve adequate sheeting in common aqueous rinses at typical rinse temperatures at a concentration of the nonionic sorbitan ester in water at concentrations about 500 parts of the fully formulated rise agent per million parts of water. The rinse agents can be used in a rinse cycle in common warewashing machines after washing with commonly available warewashing compositions. The rinse agents can take the form of thickened pourable or semi-pourable aqueous liquids or cast solid materials packaged within a disposable wrapper, capsule or other package. The preferred form of the rinse agent is a pourable or pumpable aqueous concentrate. The uniqueness of the invention relates to the fact that all components are not expected to be active as sheeting agents and are approved as food additives thereby eliminating any health concerns associated with residual deposits of the composition on cleaned ware.

Low foaming rinse agents comprising alkylene oxide modified sorbitol fatty acid ester and defoaming agent

The invention includes compositions and methods for sanitizing ware without staining or spotting. In its most preferred mode, the method comprises the steps of washing the ware in an automated ware washing machine and rinsing the ware at either high or low temperatures with a sanitizing rinse composition. The destaining, sanitizing concentrate composition preferably comprises peroxy acetic acid, acetic acid, and hydrogen peroxide. The sanitizing rinse composition may preferably be used at a concentration ranging from about 600 ppm to 4000 ppm.

Percarboxylic acid rinse method

Ethylene oxide/propylene oxide block copolymers having high cloud points, when compared to conventional rinse agent materials, have surprisingly been found to be useful in the manufacture of effective low foaming rinse aids. The rinse aids are prepared by combining the high cloud point copolymer with an effective defoamer and a water miscible diluent. The rinse aid composition can achieve adequate rinsing at common aqueous rinse temperatures at a concentration of the block copolymer in water less than 500 parts of the block copolymer per million parts of water. A liquid rinse agent concentrate can take the form of a low viscosity liquid, a thickened pourable or semi-pourable aqueous liquids. A solid rinse agent concentrate can be a cast solid material packaged within a soluble or disposable wrapper or capsule or other water soluble package. The rinse aids can be dispersed in a variety of ways by dilution with water to an aqueous final rinse composition. The uniqueness of the invention relates to the fact that all components are not expected to be active as sheeting agents and are approved as food additives thereby eliminating any health concerns associated with residual deposits of the composition on cleaned ware.

Low foaming rinse agents comprising ethylene oxide/propylene oxide block

A method of sanitizing and destaining ware, including silverware includes the steps of applying a sanitizing concentrate composition to silverware at a rate of 100 ppm to 2000 ppm, the sanitizing concentrate composition including from about 1 wt-% to 20 wt-% of peroxycarboxylic acid, from about 10 wt-% to 50 wt-% of carboxylic acid containing a mixture of acetic acid, and octanoic acid, the acetic acid and the octanoic acid present in a ratio ranging from about 10 to 1 to about 1 to 1, respectively, from about 3 wt-% to 35 wt-% of hydrogen peroxide, and a balance of carrier wherein said peroxycarboxylic acid is the reaction product of the acetic acid, octanoic acid, and hydrogen peroxide.

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Mendota Heights, MN, United States of America

Burton M Baum