Exxon Research and Engineering Company

Exxonmobil Research and Engineering Company

Bruce N Perry

James M Brown

Robert J Chimenti

Azriel Zelig Genack

Alexander Stein

Robert J Pottorf

Patricia H Kalamaras

Paul Rabinowitz

The present invention is a method to determine models to predict physical or chemical properties of a petroleum fluid when such properties of such fluids cannot be measured by conventional analytical methods. The invention includes the steps of determining one or more models that predict one or more predetermined properties from a set of oils whose optical spectra and properties are known wherein a model corresponds to each predetermined property which is related to the spectrum, estimating the quality of the models, estimating the predictive quality for samples with unknown properties, augmenting the spectrum with shape parameters and/or properties that are predicted by the step above, and determining the quality and predictive quality of the models. The models are then used to predict properties of very small samples.

Bootstrap method for oil property prediction

The present invention includes a method and system of measuring alteration, alteration type, and alteration-causing species in process fluids and equipment and for controlling the process feeds and conditions to maximize the yields and equipment lifetime by minimizing the alteration. The invention includes an optical sensor comprising an optical fiber, a fiber grating written within the optical fiber, strain-tuned elements fixed to the optical fiber and an unaltered element, and an altered element fixed to the unaltered element.

Fiber optic, strain-tuned, material alteration sensor

The present invention is a method to determine the chemical concentration of one or more of a number of the constituent classes of a feed to a catalytic cracking process. These constituent classes which are referred to as 'lumps', include 14 different molecular types in 4 different boiling range fractions. A specific lump will include all individual molecular components which are expected to react in a similar way in the catalytic cracking unit.

Method of characterizing feeds to catalytic cracking process units

A method for determining a property or composition data of a test sample from a correlation between a calibration sample set and that property or composition data using the spectrum of the test sample, a linear prediction model and a non linear correction to the linear prediction.

Non linear multivariate infrared analysis method (LAW362)

A system for measuring fluorescence-suppressed Raman Scattering using intensity-modulated laser excitation, electro-optic demodulation of the emitted and scattered light, and a means to adjust the phase of optical transmission of the demodulator relative to the laser modulation.

Phase resolved modulation Raman spectrometer

A system is disclosed for monitoring the concentration of gaseous ammonia in flue gases by simultaneously measuring the temperature and optical transmission of a flue gas-ammonia mixture.

System for monitoring trace gaseous ammonia concentration in flue gases

A device is disclosed for producing a pair of synchronized intense 16 micron pulses in which stimulated rotational Raman scattering together with four wave mixing and pulse compression takes place in parahydrogen on an off-axis path between a pair of spherical mirrors.

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Flemington, NJ, United States of America

Bruce N Perry