Henkel Corporation

National Distillers and Chemical Corporation

Cognis Corporation

Emery Industries, Inc.

Ethyl Corporation

Bruce J Beimesch

Eugene R Zehler

Nicholas E Schnur

Stephen C Lakes

Henry G Stoeppel, Ii

James Lamont

Clarence E Clark, Jr

Robert D Aylesworth

Clarence J Hughes, Jr

James E Davis

A method of improving performance of refrigerant systems such as refrigerators and air conditioners that utilize a refrigerant working fluid. The working fluid consists essentially of a heat transfer fluid and a lubricant that is miscible and is otherwise compatible with the heat transfer fluid at all operating temperatures of the refrigerant system. The method is directed particularly to chlorine-free fluoro-group organic fluids and more particularly to hydrofluorocarbon heat transfer fluids. The preferred lubricants comprise polyol ester basestocks and compounded polyol esters that are highly miscible with such hydrofluorocarbon heat transfer fluids.

Method of improving performance of refrigerant systems

Lubricant compositions comprising biodegradable ester base stocks are provided for water-cooled or air-cooled two-cycle engines.

Biodegradable two-cycle engine oil compositions and ester base stocks

Ester base stocks for two-cycle gasoline engine lubricant compositions are disclosed which produce lower amounts of observable smoke in the exhaust emitted as a result of combustion in a two-cycle gasoline engine, require no miscibility-enhancing solvents, have a viscosity of 3.0 cSt to 20.0 cSt at 100&deg; C. and a smoke index of at least 75. Some of the esters are biodegradable.

Smokeless two-cycle engine lubricants

Diesel fuels, particularly low sulfur diesel fuels, contain additives which increase the lubricity in the fuel and reduce the amount of smoke in the exhaust. These additives are esters having a viscosity of 3.0 cSt to 20.0 cSt at 100.degree. C. and a smoke index of at least 75.

Lubricants for diesel fuel

Ester base stocks for two-cycle gasoline engine lubricant compositions are disclosed which produce lower amounts of observable smoke in the exhaust emitted as a result of combustion in a two-cycle gasoline engine, require no miscibility-enhancing solvents, have a viscosity of 3.0 cSt to 20.0 cSt at 100.degree. C. and a smoke index of at least 75. Some of the esters are biodegradable.

Non-polymer thickened multigrade engine oils based on synthetic basestocks are provided. The SAE 5W-30, SAE 10W-30 and SAE 15W-40 engine oils are derived from hydrogenated decene-1 oligomer mixtures wherein the oligomers range from C.sub.30 up to C.sub.70+ and are present in specified proportions. Synthetic esters may be combined with the polyalphaolefin oligomer mixture. The synthetic basestocks are formulated with appropriate performance additives to obtain engine oils which meet the desired API Service Requirements for gasoline and/or diesel engine usage. In addition to specified oligomer distributions, the polyalphaolefins have specified viscosities, molecular weights and branching.

Multigrade hydrogenated decene-1 oligomer engine oils

Improved mist lubricant compositions containing specific synthetic esters and a mixture of polyisobutylene polymers having different molecular weights are provided. Synthetic esters employed for the compositions are polyol esters, trimellitate esters, and polymeric fatty acid esters.

Mist lubricant compositions

Highly useful hydraulic fluids based on synthetic hydrocarbon basestocks and having improved low temperature properties, good shear stability, and capable of substantially meeting the rigid Denison HF-O standards are provided. The products of this invention are comprised of specific proportions of a two centistoke synthetic hydrocarbon oil obtained from the oligomerization of alpha-olefins, particularly 1-decene, specific polymethacrylate viscosity index improvers, and a zinc-based universal/multifunctional additive package. The hydraulic fluids have a maximum viscosity of 1400 centistokes at -40.degree. F. and minimum viscosity of 5.5 centistokes at 210.degree. F.

Hydraulic fluids based on two centistoke synthetic hydrocarbons

Useful hydraulic fluids having low temperature properties comparable to MIL-H-5606 fluids but exhibiting markedly superior fire resistance due to their higher flash points are obtained by blending a two centistoke synthetic hydrocarbon oil obtained from the oligomerization of alpha-olefins with a mono- or diester and polymethacrylate viscosity index improver. The fluids of this invention typically have -65.degree. F. viscosities less than 3000 centistokes, 210.degree. F. viscosities of 3.45 or above, and flash points above 320.degree. F. and are readily formulated with conventional additives.

Low temperature hydraulic fluids based on two centistoke synthetic

Dipentaerythritol and tripentaerythritol esters of isostearic acid are disclosed. The polyol ether esters of this invention exhibit low volatility and good oxidative and thermal stability and are useful lubricants for high temperature applications.

Di- and tripentaerythritol esters of isostearic acid

Beta deuterated 2-ethylhexanol and derivatives thereof, particularly esters of 2-d-2-ethylhexanol and mono- or dicarboxylic acids which are useful as lubricants, are provided. Improved resistance to oxidation is obtained with the deuterated ester products.

Beta deuterated 2-ethylhexanol and derivatives

Polyester plasticizers having improved low temperature properties are obtained by terminating the polyester with mixed chain-terminating agents. Mixtures of monobasic acids and monofunctional alcohols are employed for this purpose. The polyesters of this invention find particular utility as plasticizers for PVC homopolymers and copolymers.

Growing community of inventors

Crescent Springs, KY, United States of America

Bruce J Beimesch