Occidental Research Corporation

Brij M Moudgil

David F Messenger

Booker W Morey

John G Roeschlaub

A method for the separation of limestone from a particulate limestone ore containing particles of limestone and gangue which comprises conditioning the limestone ore with at least one coupling agent selected from saturated and unsaturated carboxylic acids containing from about 4 to about 22 carbon atoms, or at least one coupling agent selected from the group consisting of aliphatic amines containing from about 8 to about 22 carbon atoms, and beta amines containing from about 7 to about 21 carbon atoms, to selectively coat the limestone or the gangue in the ore to the substantial exclusion of the other in combination with providing at least one fluorescent dye to said coupling agent; radiating the conditioned ore to excite and induce fluorescence of the fluorescent dye to a degree sufficient to distinguish the coated particles from the non-coated particles and separating the fluorescing, coated particles from the non-fluorescing, non-coated particles.

Separation of limestone from limestone ore

Apparatus and method for selective wetting of particles includes sizing of particles to a preselected size for enabling optical discrimination between desired particles having a relatively large surface area receptive to coating by a preselected wetting agent and undesired particles having a relatively small surface area receptive to coating by the preselected wetting agent. The particles are fed into a conditioning zone defined by the spray of wetting agent from at least one spray means, the spray of wetting agent being in sufficient quantity to impact and coat substantially all of the surface areas of the particles receptive to coating by the wetting agent. The means for feeding the particles into the conditioning zone is disposed outside the conditioning zone and preferably feeds the particles in an unsupported state into the conditioning zone.

Apparatus for selective wetting of particles

A method is disclosed for the separation of oil shale from run of mine (ROM) oil shale containing particles of oil shale and refuse, which comprises conditioning the ROM oil shale with a coupling agent capable of selectively coating the kerogen hydrocarbons in the particulate oil shale to the substantial exclusion of coating the non-hydrocarbonaceous refuse, which coupling agent is one or more compounds selected from the group consisting of an alcohol, at least one carboxylic acid, preferably containing from about 5 to about 28 carbon atoms and a ketone. Combined with said coupling agent is a fluorescent dye in a quantity to make the coated particles of oil shale fluoresce upon excitation to a degree sufficient to distinguish the coated oil shale particles from the substantially non-coated refuse. Exciting (e.g. as with ultraviolet light) the fluorescent dye coupled to the oil shale particles induces fluorescence and enables separating the fluorescing, coated oil shale particles from substantially non-fluorescing, non-coated refuse particles.

Process for separating oil shale waste material

An apparatus and a method for concentrating an ore to recover valuable minerals from the ore is disclosed. The apparatus is based upon flotation separation techniques and comprises a trough into which is fed a slurry of ore particles which have been conditioned with a flotation reagent. The trough has a side extending outwardly forming a downwardly sloping flat table. The slurry of conditioned ore particles flows out of the trough and downwardly along the sloping table. Positioned along the sloping table is a disperser for dispersing larger particles up and into the slurry, which larger particles are generally along the surface of the sloping table. The sloping table is equipped with at least one aerator positioned along the flow path of the slurry, downstream of the disperser which aerates the conditioned ore slurry. The particles coated with the flotation reagent form agglomerates with gas bubbles produced by the aerator. These agglomerates float at a higher level within the slurry than the non-coated, non-agglomerating ore particles. A splitter is positioned near an open end of the sloping table. The splitter height above the surface of the sloping table is adjustable for intersecting the conditioned ore slurry at differing levels. The splitter separates the agglomerative, coated particles floating at a higher level from the non-agglomerative, non-coated particles floating at a lower level in the slurry.

Apparatus for the float concentration of ore

A method of separating a mineral component from particulate ore consisting of many components, such as oxides, silicates, carbonates, sulfides etc. is disclosed. The particulate ore is conditioned with a surface-active agent capable of selectively coating one of the components of the ore to the substantial exclusion of coating the other components. A coloring agent having an affinity towards the coating of surface active agent is combined with the surface active agent, providing the coated ore particles with a distinguishable color from the non-coated ore particles. The distinguishable color-coated ore particles are separated from the non-coated ore particles.

Method of separating a mixture of ore particles

A method is disclosed for the separation of coal from run of mine (ROM) coal containing particles of coal and refuse, which comprises conditioning the ROM coal with a coupling agent capable of selectively coating the particulate coal to the substantial exclusion of coating the refuse, which coupling agent is at least one alcohol containing from about 6 to about 22 carbon atoms. Combined with said coupling agent is a fluorescent dye in a quantity to make the coated particles of coal fluoresce upon excitation to a degree sufficient to distinguish the coated coal particles from the substantially non-coated refuse. Exciting (e.g. as with ultraviolet light) the fluorescent dye coupled to the coal particles induces fluorescence and enables separating the fluorescing, coated coal particles from substantially non-fluorescing, non-coated refuse particles.

Separation of coal from waste material

A method for the separation of limestone from a particulate limestone ore containing particles of limestone and gangue which comprises conditioning the limestone ore with at least one coupling agent selected from saturated and unsaturated carboxylic acids containing from about 4 to about 22 carbon atoms, or at least one coupling agent selected from the group consisting of aliphatic amines containing from about 8 to about 22 carbon atoms, and beta amines containing from about 7 to about 21 carbon atoms, to selectively coat the limestone or the gangue in the ore to the substantial exclusion of the other in combination with providing at least one fluorescent dye to said coupling agent; radiating the conditioned ore to excite and induce fluorescence of the fluorescent dye to a degree sufficient to distinguish the coated particles from the non-coated particles and separating the fluorescing, coated particles from the nonfluorescing, non-coated particles.

A method for the separation of magnesite from a particulate ore containing particles relatively rich in magnesite and particles relatively rich in dolomite and/or calcite, which comprises conditioning the ore with at least one coupling agent selected from saturated and unsaturated carboxylic acids containing from about 4 to about 22 carbon atoms, to selectively coat the calcite and/or dolomite in the ore to the substantial exclusion of the magnesite, in combination with providing at least one fluorescent dye to said coupling agent; radiating the conditioned ore to excite and induce fluorescence of the fluorescent dye to a degree sufficient to distinguish the coated particles from the non-coated particles and separating the fluorescing, coated particles from the non-fluorescing, non-coated particles.

Separation of magnesite from ores which also contain calcite or dolomite

A method is disclosed for the separation of shale from run of mine (ROM) shale containing particles of shale and refuse, which comprises conditioning the ROM shale with a coupling agent capable of selectively coating the kerogen hydrocarbons in the particulate shale to the substantial exclusion of coating the non-hydrocarbonaceous refuse, which coupling agent is at least one carboxylic acid, preferably containing from about 5 to about 28 carbon atoms and a ketone. Combined with said coupling agent is a fluorescent dye in a quantity to make the coated particles of shale fluoresce upon excitation to a degree sufficient to distinguish the coated shale particles from the substantially non-coated refuse. Exciting (e.g. as with ultraviolet light) the fluorescent dye coupled to the shale particles induces fluorescence and enables separating the fluorescing, coated shale particles from substantially non-fluorescing, non-coated refuse particles.

Growing community of inventors

Ontario, CA, United States of America

Brij M Moudgil