Phillips Petroleum Company

Brian K Conroy

Ted M Pettijohn

Paul D Smith

William K Reagen

Kenneth Farmer

Max P McDaniel

Joel L Martin

Shirley J Martin

William K Reagan

Willim K Reagen

Novel chromium-containing compounds, such as, for example, chromium pyrrolides, are prepared by forming a mixture of a chromium salt, a metal amide, and an electron pair donor solvent:, such as, for example, an ether. These novel chromium-containing, or chromium pyrrolide, compounds can be used either unsupported or supported on an inorganic oxide support to trimerize and/or polymerize olefins.

Process of polymerizing olefins in the presence of a chromium-containing

Novel chromium-containing compounds, such as, for example, chromium pyrrolides, are prepared by forming a mixture of a chromium salt, a metal amide, and an electron pair donor solvent, such as, for example, an ether. These novel chromium-containing, or chromium pyrrolide, compounds can be used either unsupported or supported on an inorganic oxide support to trimerize and/or polymerize olefins.

Chromium compounds and uses thereof

The compound (Cp*.sub.2 YCl).sub.2 wherein Cp* is pentamethylcyclopentadienyl and its preparation and use for the polymerization of olefins is disclosed.

Olefin polymerization catalyst and process

Olefin polymerization catalysts, processes for preparing the catalysts and processes for producing polyolefins utilizing the catalysts are provided. The catalysts are basically comprised of a trialkylsilylamide-chromium complex adsorbed on an activated inorganic compound.

Olefin polymerization catalysts and processes

Olefin polymerization catalysts, processes for preparing the catalysts and processes for producing polyolefins utilizing the catalysts are provided. The catalysts are basically comprised of a trialkylsilylamide-chromium complex adsorbed on an activated inorganic refractory compound.

A lanthanide base olefin polymerization catalyst and its use in polymerization are disclosed. The lanthanide based catalyst is prepared by contacting a lanthanide halide with an ether, then contacting the resulting lanthanide composition with an alkali or alkaline earth metal alkyl compound, and depositing the resulting lanthanide product on a particulate support.

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Batavia, IL, United States of America

Brian K Conroy