3m Innovative Properties Company

Brian J Gates

Moses Mekala David

Robert J DeVoe

Brian Kenneth Nelson

Bryon J Cronk

James Francis Brennan, Iii

Craig R Sykora

Robert T Krasa

Dean Faklis

Dwayne L LaBrake

Seth M Kirk

Tzu-Chen Lee

Przemyslaw Pawel Markowicz

Gunter A Kohler

William H Esswein

Michael Nevin Miller

Fred Boyle McCormick

Trevor Wayne MacDougall

Raghunath Padiyath

Christopher Bland Walker, Jr

Louis C Haddad

Donald J McClure

Travis L Potts

Jeremy K Larsen

Bradford B Wright

David A Engler

Serge Wetzels

Jon E Ottman

Terry Lee Smith

James D Hansen

Jun-Ying Zhang

Nicholas A Lee

William Vogel Dower

Nestor O Farmiga

Charles A Marttila

Barry J Koch

David Adams Ender

Joel R Dufresne

Anthony William Gatica

Andrew Murnan

Ronald Phillip Pepin

Robert J Devoe

Stephen Paul LeBlanc

John T Cowher

David L Kordecki

Alexander J Huffman

Gareth A Hughes

Andrew J Murnan

Nester O Farmiga

The present disclosure provides a multiphoton imaging method. The method includes a) immersing a semi-submersible microscope objective in a liquid medium that is at least one of scattering or absorbing; b) directing laser light through the semi-submersible microscope objective and into the liquid medium in an image-wise manner under conditions such that multiphoton absorption by the multiphoton absorber occurs, and at least partial polymerization of the polymerizable compound occurs resulting in an article; and c) removing uncured polymerizable compound to clean the article. The liquid medium includes a polymerizable compound, a secondary component, and a multiphoton absorber. An article is also provided. The article includes a material defining one or more tortuous or arcuate channels, one or more internal architectural voids, one or more undercuts, one or more perforations, or combinations thereof, at least one of which exhibits a surface roughness of 1.0 micrometer Ror less.

Multiphoton imaging methods in a scattering and/or absorbing medium, and articles

A semi-submersible microscope objective includes a microscope objective having a protective barrel with an optical inlet and optical outlet, and a protective element affixed to the microscope objective, sealing the optical exit but not the optical inlet. A transparent portion of the protective element is aligned with the optical exit. The protective element is separable from the microscope objective without damaging the microscope objective. Use of the semi-submersible microscope objective in a multiphoton imaging method is also disclosed.

Semi-submersible microscope objective with protective element and use of the same in multiphoton imaging method

A method of fabricating a structure includes disposing a liquid photoreactive composition on a substrate, exposing a portion of the liquid photoreactive composition to laser light of sufficient intensity and wavelength to cause polymerization via two-photon excitation of the two-photon sensitizer and polymerization of a portion of the liquid photoreactive composition thereby providing an exposed composition; and developing the exposed composition to provide the structure. The liquid composition includes: at least one cationically polymerizable polyepoxide; at least one compound comprising free-radically polymerizable groups; an effective amount of a two-photon photoinitiator system, wherein the weight ratio of component (a) to component (b) is from 25:75 to 75:25, inclusive. The two-photon photoinitiator system includes a two-photon sensitizer and an aromatic onium salt. The liquid photoreactive composition may contain less than about one percent by weight of organic solvent.

Liquid photoreactive composition and method of fabricating structures

A semi-submersible microscope objective () includes a microscope objective having a protective barrel () with an optical inlet () and optical outlet (), and a protective element () affixed to the microscope objective, sealing the optical outlet () but not the optical inlet (). A transparent portion () of the protective element is aligned with the optical exit (). The protective element is separable from the microscope objective without damaging the microscope objective. Use of the semi-submersible microscope objective in a multiphoton imaging method is also disclosed.

An exposure system includes a light source emitting a beam along an optical axis that is capable of inducing a multi-photon reaction in a resin. The exposure system further includes a resin undergoing multiphoton reaction, as well as an automated system including a monitor that measures at least one property of the beam selected from power, pulse length, shape, divergence, or position in a plane normal to the optical axis. The monitor generates at least one signal indicative of the property of the beam, and a sub-system adjusts the beam in response to the signal from the monitor.

Multi-photon exposure system

A virtual image (VI) device displays an image that appears to lie above or below the plane of the device. A method of manufacturing a VI display device includes calculating an initial VI flux pattern based on an object and then fabricating a substrate having a VI array pattern based on the initial VI flux pattern. A plurality of lenses may then be applied over the VI array pattern. The VI substrate may be static or dynamic, and may show grey scale information. A photomask may be used as an intermediate element in the manufacture of the VI substrate, or may act as the VI substrate itself. A method of producing the initial VI flux pattern includes virtually tracing rays generated by different points of the object to an image plane and ii) summing the rays from the different points. The rays may be traced through a lens array.

Processes for producing optical elements showing virtual images

A sheeting and a method of forming a sheeting from a master tool are described where the sheeting has a composite image that floats above or below the sheeting. The method includes providing a first sheeting comprising a first array of microlenses and a photopolymerizable first material layer adjacent to the first array of microlenses. Another step is exposing the first sheeting to a radiation source to form a master tool comprising a plurality of polymerized first structured areas in the first material layer, wherein at least some of the first structured areas include a portion shape in common with at least some of the first structured areas and wherein each first structured area is associated with one of the first array of microlenses. Yet another step is replicating the plurality of first structured areas using a substance that conforms to the plurality of structured areas to form a second material layer having a plurality of replicated structured areas.

Methods for forming sheeting with a composite image that floats and a master tooling

A method includes scanning a radiation beam with respect to a multi-photon curable photoreactive composition. The radiation beam includes a power sufficient to at least partially cure a volume of the multiphoton curable photoreactive composition. The method further includes modifying a characteristic of the radiation beam as the radiation beam is scanned.

Method for making structures with improved edge definition

A system comprising a substrate having thereon a multiphoton curable photoreactive composition, a light source that emits a light beam comprising a plurality of wavelengths onto at least one region of the composition on the substrate, and a detector that detects a portion of light reflected from the composition to obtain a location signal with respect to the substrate, wherein the location signal is based at least on a wavelength of the reflected light.

Chromatic confocal sensor

The invention relates to a method of making an organic electronic device and articles.

Method of making an organic light emitting device

A glass article comprising a glass substrate and a diamond-like film deposited on the substrate is disclosed. The glass article is desirably responsive to actinic radiation, such as being capable of demonstrating a change in refractive index upon exposure to actinic radiation. The film permits passage of the actinic radiation through the film and into the substrate. In specific implementations, the film comprises at least about 30 atomic percent carbon, from about 0 to about 50 atomic percent silicon, and from about 0 to about 50 atomic percent oxygen on a hydrogen-free basis.

Radiation-transmissive films on glass articles

Optical and optoelectronic articles incorporating an amorphous diamond-like film are disclosed. Specifically, the invention includes optical or optoelectronic articles containing an amorphous diamond-like film overlying two or more proximate substrates, and to methods of making optical and optoelectronic articles. In certain implementations, the film comprises at least about 30 atomic percent carbon, from about 0 to about 50 atomic percent silicon, and from about 0 to about 50 atomic percent oxygen on a hydrogen-free basis. Another embodiment includes optical or optoelectronic articles containing an amorphous diamond-like film that is further coated with a metallic or polymeric material for attachment to a device package.

Optical and optoelectronic articles

The present invention provides a method for the formation of an organic coating on a substrate. The method includes: providing a substrate in a vacuum; providing at least one vaporized organic material comprising at least one component from at least one source, wherein the vaporized organic material is capable of condensing in a vacuum of less than about 130 Pa; providing a plasma from at least one source other than the source of the vaporized organic material; directing the vaporized organic material and the plasma toward the substrate; and causing the vaporized organic material to condense and polymerize on the substrate in the presence of the plasma to form an organic coating.

Flash evaporation-plasma coating deposition method

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Osceola, WI, United States of America

Brian J Gates