Amoco Corporation

Brian A Stern

Richard Layton

Markus Matzner

Paul D Frayer

Paul J Huspeni

James W Cleary

Blends of liquid crystalline polymers of hydroquinone

This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the 'Description of the Invention.' The instant copolyesters display orientation in the molten state, good fiber ratings and high strength. Advantageously, the polymers of the present invention display a significant improvement in viscosity and moldability of the neat polymer. The polymers have excellent mechanical and surface properties including blister resistance, strength, toughness, and ability to vapor phase solder, and form strong fibers while still maintaining a high heat distortion temperature. They have melting points in the range of from about 250.degree. to about 360.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of up to 240.degree. C., when measured under a load of 264 psi. The polymers may be blended to tailor properties. These polymers and blends may be used advantageously in producing fibers and in electrical equipment, electronic components and other end uses requiring moderately high temperatures.

High strength polymers and blends of hydroquinone

High strength polymer of hydroquinone poly(iso-terephthalate) containing

Wholly aromatic polyester of isophthalic acid, terephthalic acid,

Process for preparing polyarylates comprising the steps of (a) prepolymerizing a diester of Bisphenol-A with at least one aromatic dicarboxylic acid to form a prepolymer having a melting point of at least about 200.degree. C. and being fluid at the polymerization temperature; followed by (b) polycondensing said prepolymer under agitation until it is substantially transformed into a powdery solid; maintaining said agitation to keep the powdery solid in a polydispersed solid state; and continuing the polymerization below the agglomeration temperature of the polymerizing solid, until the desired molecular weight is reached.

Process for preparing bisphenol polyarylates

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Evans, GA, United States of America

Brian A Stern