The Goodyear & Tire Rubber Company

Brent Kevin Larson

Dane Kenton Parker

Xiaoping Yang

Melissa Marie Beauvais

Glenn Ervin Gasner

This invention relates to preparation and use of nanocomposites formed in situ within an elastomer host wherein the nanocomposite is comprised of an elastomer matrix and a dispersion therein of at least partially exfoliated clay platelets. Rubber composites can be prepared by blending such nanocomposite with additional elastomer(s), additional reinforcing filler(s) and/or a coupling agent. The invention further relates to the preparation of articles of manufacture, including tires, having at least one component comprised of said nanocomposite or said rubber composite. Such a tire component may be selected from, for example, tire tread and tire innerliner.

Nanocomposite formed in situ within an elastomer and article having component comprised thereof

This invention relates to a rubber composition which contains intercalated and at least partially exfoliated organophillic clay reinforcement formed in situ within the elastomer host from a hydrophilic clay. The invention particularly relates to an in situ modification of a hydrophilic clay to compatibilize the clay with a diene-based elastomer. The clay is converted from being hydrophilic in nature to being more hydrophobic in nature and therefore more compatible with the elastomer by bulk blending the elastomer host with a smectite clay, preferably a montmorillonite or hectorite clay, and a hydrocarbyl onium salt, such as for example a quaternary ammonium salt, and particularly in the absence of water addition to the elastomer host. Therefore, such in situ procedure of intercalation and at least partially exfoliation relies upon a bulk blending thereof with an elastomer host at an elevated temperature and under high shear conditions in contrast to pre-intercalating the clay in an aqueous based medium and in contrast to simple low viscosity melt processing of a thermoplastic polymer. The invention also relates to articles of manufacture, including tires, having at least one component comprised of such rubber composition. Such tire component may be, for example, a tire tread.

Preparation of elastomer with exfoliated clay and article with composition thereof

A tire with at least one component of a rubber composition which contains oriented exfoliated platelets derived from an intercalated clay. Such tire component may be, for example, a rubber/cord laminate and, optionally, a sidewall insert and, optionally, an apex.

Tire with at least one of rubber/cord laminate, sidewall insert and apex of a rubber composition which contains oriented intercalated and/or exfoliated clay reinforcement

An electrically-conductive rubber composition and article of manufacture having a component thereof. In one aspect, such article of manufacture is a pneumatic rubber tire of a toroidal shape having a cavity designed to be substantially enclosed by the toroidal shape of the tire and its closure completed by a rigid rim onto which the tire is designed to be mounted. In another aspect, such pneumatic tire contains such rubber composition positioned on or within a rubber innerliner of the tire; wherein the innerliner is a surface of said cavity. In a further aspect, said rubber composition is an annular strip of an electrically-conductive rubber composition on or within such tire innerliner. The said annular strip is intended to be an antenna for having a capability of receiving electromagnetic waves from outside the tire and of transmitting electromagnetic waves from the inside of the tire to the outside of the tire.

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Fairlawn, OH, United States of America

Brent Kevin Larson