Guardian Glass, LLC

Guardian Industries Corporation

Intermolecular, Inc.

Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.a. (c.r.v.c.)

Guardian Glass Holding S.p.c.

Guardian Europe S.a.r.l.

Guardian Glass Management Services W.l.l.

Brent Boyce

Guowen Ding

Minh Le

Yongli Xu

Daniel Schweigert

Muhammad Imran

Philip J Lingle

Jingyu Lao

Guizhen Zhang

Cesar Clavero

Francis Wuillaume

Yiwei Lu

Marcus Frank

Daniel Lee

Scott Jewhurst

Richard Blacker

Yu Wang

Bernd Disteldorf

Zhi-Wen Sun

Salah Boussaad

Richard Vernhes

Jean-Marc Lemmer

Jeremy Cheng

Mohd Fadzli Anwar Hassan

Uwe Kriltz

Hartmut Knoll

Afonso Kreling

Alexander Lorenz

Patricia Tucker

Kenneth Lord

Aritra Biswas

Allen Chu

Gregory Scott

Muniswami Naidu

Venkata Krishnaswamy Naidu Vantaku

Shashi Shah

Alexey Krasnov

Anton Dietrich

Jose Ferreira

Tong Ju

Gaurav Saraf

Leonard L Boyer, Jr

Phil Lingle

Donald V Jacobson

Bernd Disteldorft

Minh Lee

Minh Huu Le

Muniswami Nadidu

Krishna Swamynaidu

Muhammed Imran

A low-E coating has good color stability (a low &#x394;E* value) upon heat treatment (HT). Thermal stability may be improved by the provision of an as-deposited crystalline or substantially crystalline layer of or including zinc oxide, doped with at least one dopant (e.g., Sn), immediately under an infrared (IR) reflecting layer of or including silver; and/or by the provision of at least one dielectric layer of or including an oxide of zirconium. These have the effect of significantly improving the coating's thermal stability (i.e., lowering the &#x394;E* value). An absorber film may be designed to adjust visible transmission and provide desirable coloration, while maintaining durability and/or thermal stability. The dielectric layer (e.g., of or including an oxide of Zr) may be sputter-deposited so as to have a monoclinic phase in order to improve thermal stability.

Low-E matchable coated articles having absorber film and corresponding methods

A low-emissivity (low-E) coating on a substrate (e.g., glass substrate) includes at least first and second infrared (IR) reflecting layers (e.g., silver based layers) that are spaced apart by contact layers (e.g., NiCr based layers), a layer comprising silicon nitride, and an absorber layer of or including a material such as niobium zirconium which may be oxided and/or nitrided. The absorber layer is designed to allow the coated article to realize glass side reflective (equivalent to exterior reflective in an IG window unit when the coating is provided on surface #2 of an IG window unit) silver color. In certain example embodiments, the coated article (monolithic form and/or in IG window unit form) has a low visible transmission (e.g., from 15-45%, more preferably from 22-39%, and most preferably from 24-35%). In certain example embodiments, the coated article may be heat treated (e.g., thermally tempered and/or heat bent).

Silver colored coated article with low-E coating having absorber layer and low visible transmission

A low-emissivity (low-E) coating on a substrate (e.g., glass substrate) includes at least first and second infrared (IR) reflecting layers (e.g., silver based layers) that are spaced apart by contact layers (e.g., NiCr based layers), a layer comprising silicon nitride, and an absorber layer of or including a material such as niobium zirconium which may be oxided and/or nitrided. The absorber layer is designed to allow the coated article to realize glass side reflective (equivalent to exterior reflective in an IG window unit when the coating is on surface #2 of the IG unit) grey color. In certain example embodiments, the coated article (monolithic form and/or in IG window unit form) has a low visible transmission (e.g., from 20-45%, more preferably from 22-39%, and most preferably from 25-37%). In certain example embodiments, the coated article may be heat treated (e.g., thermally tempered and/or heat bent).

Grey colored coated article with low-E coating having absorber layer and low visible transmission

Certain example embodiments of this invention relate to coated articles having a metamaterial-inclusive layer, coatings having a metamaterial-inclusive layer, and/or methods of making the same. Metamaterial-inclusive coatings may be used, for example, in low-emissivity applications, providing for more true color rendering, low angular color dependence, and/or high light-to-solar gain. The metamaterial material may be a noble metal or other material, and the layer may be made to self-assemble by virtue of surface tensions associated with the noble metal or other material, and the material selected for use as a matrix. An Ag-based metamaterial layer may be provided below a plurality (e.g., 2, 3, or more) continuous and uninterrupted layers comprising Ag in certain example embodiments. In certain example embodiments, barrier layers comprising TiZrOx may be provided between adjacent layers comprising Ag, as a lower-most layer in a low-E coating, and/or as an upper-most layer in a low-E coating.

Matrix-embedded metamaterial coating, coated article having matrix-embedded metamaterial coating, and/or method of making the same

Coated articles include two or more functional infrared (IR) reflecting layers optionally sandwiched between at least dielectric layers. The dielectric layers may be of or including silicon nitride or the like. At least one of the IR reflecting layers is of or including titanium nitride (e.g., TiN) and at least another of the IR reflecting layers is of or including indium-tin-oxide (ITO).

Heat treatable coated article having titanium nitride and ITO based IR reflecting layers

A low-E coating has good color stability (a low &#x394;E* value) upon heat treatment (HT). Thermal stability may be improved by the provision of an as-deposited crystalline or substantially crystalline layer of or including zinc oxide, doped with at least one dopant (e.g., Sn), immediately under an infrared (IR) reflecting layer of or including silver; and/or by the provision of at least one dielectric layer of or including at least one of: (a) an oxide of silicon and zirconium, (b) an oxide of zirconium, and (c) an oxide of silicon. These have the effect of significantly improving the coating's thermal stability (i.e., lowering the &#x394;E* value).

Low-E matchable coated articles having doped seed layer under silver, and corresponding methods

A low-E coating has good color stability (a low &#x394;E* value) upon heat treatment (HT). The provision of an as-deposited crystalline or substantially crystalline layer of or including zinc oxide, doped with at least one dopant (e.g., Sn), immediately under an infrared (IR) reflecting layer of or including silver in a low-E coating has effect of significantly improving the coating's thermal stability (i.e., lowering the &#x394;E* value). One or more such crystalline, or substantially crystalline, layers may be provided under one or more corresponding IR reflecting layers comprising silver.

A coated article includes a low-emissivity (low-E) coating. The low-E coating includes at least one infrared (IR) reflecting layer of a material such as silver, gold, or the like, and a dielectric overcoat designed to increase solar heat gain coefficient (SHGC) of the coated article. A dielectric undercoat may also be designed to increase SHGC of the coated article in certain example embodiments. In certain example embodiments, the overcoat and/or undercoat are designed to increase SHGC while also providing for desirably high visible transmission (TY or T) and desirably low normal emittance (E).

Coated article with IR reflecting layer(s) and overcoat for improving solar gain and visible transmission

A coated article includes a silver (Ag) based infrared (IR) reflecting layer(s) on a glass substrate that is provided adjacent to and contacting at least one metallic or substantially metallic zinc (Zn) inclusive barrier layer in order to improve chemical durability characteristics of the low-E coating. In certain example embodiments, the silver based layer may be sandwiched between first and second metallic or substantially metallic barrier layers of or including zinc. The IR reflecting layer(s) and zinc based barrier layer(s) are part of a low emissivity (low-E) coating.

Coated article with low-E coating having IR reflecting system with silver and zinc based barrier layer(s)

A coated article includes a low emissivity (low-E) coating supported by a glass substrate. The low-E coating includes at least one silver (Ag) based infrared (IR) reflecting layer(s) that is provided adjacent to and contacting at least one protective metallic or substantially metallic doped silver layer in order to improve chemical durability characteristics of the low-E coating. The silver based IR reflecting layer and adjacent protective doped silver layer are part of a low emissivity (low-E) coating, and may be sandwiched between at least transparent dielectric layers. A barrier layer including Ni and/or Cr may be provided over and directly contacting the protective doped silver layer in order to further improve durability of the low-E coating.

Coated article with low-E coating having protective doped silver layer for protecting silver based IR reflecting layer(s), and method of making same

A low-E coating has good color stability (a low &#x394;E* value) upon heat treatment (HT). Thermal stability may be improved by the provision of an as-deposited crystalline or substantially crystalline layer of or including zinc oxide, doped with at least one dopant (e.g., Sn), immediately under an infrared (IR) reflecting layer of or including silver; and/or by the provision of at least one dielectric layer of or including at least one of: (a) an oxide of silicon and zirconium, (b) an oxide of zirconium, and (c) an oxide of silicon. These have the effect of significantly improving the coating's thermal stability (i.e., lowering the &#x394;E* value). An absorber film may be designed to adjust visible transmission and provide desirable coloration, while maintaining durability and/or thermal stability.

A method for making low emissivity panels, including control the composition of a barrier layer formed on a thin conductive silver layer. The barrier structure can include a ternary alloy of nickel, titanium, and niobium, which showed improvements in overall performance than those from binary barrier results. The percentage of nickel can be between 5 and 15 wt %. The percentage of titanium can be between 30 and 50 wt %. The percentage of niobium can be between 40 and 60 wt %.

Titanium nickel niobium alloy barrier for low-emissivity coatings

Coated articles include two or more functional infrared (IR) reflecting layers optionally sandwiched between at least dielectric layers. The dielectric layers may be of or including silicon nitride or the like. At least one of the IR reflecting layers is of or including titanium nitride (e.g., TIN) and at least another of the IR reflecting layers is of or including indium-tin-oxide (ITO).

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Novi, MI, United States of America

Brent Boyce