Eastman Chemical Company

Bradley James Helmer

Soumendra Kumar Basu

Marcus David Shelby

Matthew Davie Wood

Jos Simon De Wit

Chris Stanley Dagenhart

Carlo Antony Testa

Mark Dwight Clark

Haining An

Mark Arigo

Pruthesh Hariharrao Vargantwar

Glenn Lewis Shoaf

David L Murray

Charles H Foster

An elastomeric composition is provided comprising at least one elastomer, at least one cellulose ester additive, at least one methylene acceptor, at least one methylene donor, and optionally, at least one filler; wherein the cellulose ester additive comprises at least one cellulose ester. The cellulose ester additive can also comprise at least one compatibilizer and/or plasticizer.

Elastomeric compositions comprising cellulose ester additives

A process for producing elastomeric composition is provided comprising mixing at least one elastomer, at least one cellulose ester additive, at least one methylene acceptor, at least one methylene donor, and optionally, at least one filler; wherein the cellulose ester additive comprises at least one cellulose ester. The cellulose ester additive can also comprise at least one compatibilizer and/or plasticizer.

Process to produce elastomeric compositions comprising cellulose ester additives

An elastomeric composition is provided comprising at least one non-fibril cellulose ester, at least one non-nitrile primary elastomer, optionally a starch, and at least 70 parts per hundred rubber (phr) of one or more fillers, wherein the weight ratio of the cellulose ester to the starch is at least 3:1, wherein the cellulose ester is in the form of particles having an average diameter of not more than 10 &#x3bc;m.

Cellulose esters in highly-filled elastomeric systems

A process to produce an elastomeric composition is provided. The process comprises blending at least one cellulose ester, at least one non-nitrile primary elastomer, and at least 70 phr of one or more fillers to produce the elastomeric composition, wherein at least a portion of the blending occurs at a temperature exceeding the Tg of said cellulose ester, and wherein the elastomeric composition exhibits a Mooney viscosity at 100&#xb0; C. as measured according to ASTM D1646 of not more than 110 AU.

A tire component is provided comprising an elastomeric composition containing at least one non-fibril cellulose ester, at least one non-nitrile primary elastomer, optionally a starch, and at least 70 parts per hundred rubber (phr) of one or more fillers, wherein the weight ratio of the cellulose ester to the starch is at least 3:1, and wherein the cellulose ester is in the form of particles having an average diameter of not more than 10 &#x3bc;m.

Cellulose esters in pneumatic tires

A process for producing a tire component is provided. The process comprises: (a) blending at least one cellulose ester, at least one non-nitrile primary elastomer, and at least 70 phr of one or more fillers to produce an elastomeric composition, wherein at least a portion of the blending occurs at a temperature exceeding the Tg of the cellulose ester, wherein the elastomeric composition exhibits a Mooney viscosity at 100&#xb0; C. as measured according to ASTM D1646 of not more than 110 AU; and (b) forming the tire component with the elastomeric composition.

A tire is provided comprising a cellulose ester/elastomer composition wherein the cellulose ester/elastomer comprises at least one cellulose ester, at least one elastomer, and at least one additive selected from the group consisting of at least one compatibilizer and at least one plasticizer.

Tires comprising cellulose ester/elastomer compositions

A cellulose ester composition is provided comprising at least one cellulose ester and at least one additive selected from the group consisting of a compatibilizer, and a plasticizer. Processes for producing the cellulose ester composition are also provided. In another embodiment, a cellulose ester/elastomer composition is provided comprising at least one elastomer, at least one cellulose ester; and at least one additive; wherein the additive is at least one selected from the group consisting of a compatibilizer and a plasticizer. Processes for producing the cellulose ester/elastomer composition is also provided as well as articles comprising the cellulose ester/elastomer composition.

Processes for making cellulose ester compositions

Cellulose ester/elastomer compositions

A process is provided to produce an aqueous composition. The process comprises shearing a mixture to produce a mini-emulsion and polymerizing said mini-emulsion in the presence of an initiator to produce the aqueous composition; wherein said mixture comprises at least one tackifier, at least one ethylenically unsaturated monomer, at least one surfactant, and water. The aqueous composition can be utilized to produced various articles including, but not limited to, adhesives, coatings, and laminates.

Process to produce an aqueous composition

A water-based latex of an acrylic-modified waterborne alkyd or uralkyd dispersion in water is described. The acrylic-modified waterborne alkyd or uralkyd is a hybrid resin prepared by the polymerization of at least one latent oxidatively-functional (LOF) acrylic monomer in the presence of a waterborne alkyd or uralkyd. Alternatively, the acrylic-modified waterborne alkyd or uralkyd is a hybrid resin prepared by shearing a mini-emulsion based on a solvent-borne alkyd or uralkyd dissolved in at least one LOF acrylic monomer. Preparation of the latexes may be achieved by emulsion polymerization of at least one latent oxidatively-functional acrylic monomer in the presence of a waterborne alkyd or uralkyd whereby the latent oxidative functionality of the acrylic polymer survives polymerization. Water-based latexes may also be prepared by polymerizing a sheared mini-emulsion based on a solvent-borne alkyd or uralkyd dissolved in at least one LOF acrylic monomer such that the latent oxidative functionality of the acrylic polymer survives polymerization. Such acrylic-modified waterborne alkyd or uralkyds are useful in a variety of coating compositions.

Acrylic modified waterborne alkyd or uralkyd dispersions

The latex polymer compositions of the present invention exhibit latent crosslinking properties. Latent crosslinking in the polymers takes advantage of the fast reaction that occurs between amine-reactive carbonyl groups in the polymer component and carbonyl-reactive amine nitrogens in the crosslinking component, but controls the rate of crosslinking by protonating the amines with a volatile acid. Once the latex is coated onto a substrate, the volatile acid evaporates and the carbonyl reactive amine nitrogens react with the amine reactive carbonyl groups to form a crosslinked coating.

Protonated amines for controlled crosslinking of latex polymers

A water-based latex of an acrylic-modified waterborne alkyd dispersion in water is described. The acrylic-modified waterborne alkyd is a hybrid resin prepared by the polymerization of at least one latent oxidatively-functional (LOF) acrylic monomer in the presence of a waterborne alkyd. Preparation of the latexes may be achieved by emulsion polymerization of at least one latent oxidatively-functional acrylic monomer in the presence of a waterborne alkyd whereby the latent oxidative functionality of the acrylic polymer survives polymerization. Such acrylic-modified waterborne alkyds are useful in a variety of coating compositions.

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Kingsport, TN, United States of America

Bradley James Helmer