Halliburton Energy Services, Inc.

Paramount Design LLC

Brad Todd

Gary P Funkhouser

Loren C Swor

Keith A Frost

B Raghava Reddy

Dale E Jamison

Rajesh Kumar Saini

Robert J Murphy

Janette Cortez

Bessie “Nita” Q Citrowske

A downhole tool comprising magnesium is placed in a well bore in a subterranean formation for performance of a downhole operation. After performance of the downhole operation, rather than mechanically retrieving or removing the tool, at least a portion of the magnesium in the downhole tool is dissolved by contacting the downhole tool with an aqueous ammonium chloride solution.

Methods and systems for degrading downhole tools containing magnesium

Methods and compositions for use in a wellbore penetrating a subterranean formation are provided. In one embodiment, the method of servicing a wellbore may comprise preparing a wellbore servicing fluid comprising a degradation accelerator wherein the degradation accelerator comprises an alkanolamine, an oligomer of aziridine, a polymer of aziridine, a diamine, or combinations thereof; and placing the wellbore servicing fluid comprising a degradation accelerator into the wellbore, the subterranean formation or both wherein the degradation accelerator contacts the degradable polymer.

Wellbore servicing methods and compositions comprising degradable polymers

In one embodiment, the present invention provides a method of reducing the viscosity of a viscosified treatment fluid comprising contacting the viscosified treatment fluid with an acid generated from an orthoester composition that comprises an orthoester. In another embodiment, the present invention provides a method of reducing the pH of a viscosified treatment fluid comprising providing an orthoester composition that comprises an orthoester; contacting the viscosified treatment fluid with the orthoester composition; allowing the orthoester to generate a generated acid; and allowing the generated acid to at least partially reduce the pH of the viscosified treatment fluid. Embodiments of fracturing and gravel packing methods also are disclosed.

Orthoester compositions and methods for reducing the viscosified treatment fluids

The present invention relates to methods and compositions for treating subterranean formations, and more specifically, to improved methods and compositions for generating acids for use downhole, for example, to at least partially degrade the acid-soluble portions of filter cakes deposited in subterranean formations. In one embodiment, the present invention provides a method of degrading an acid-soluble portion of a filter cake comprising contacting the acid-soluble portion of the filter cake with an acid generated from an orthoester.

Orthoester compositions and methods of use in subterranean applications

A method and apparatus for determining the effectiveness and reaction time of a breaker fluid in breaking a filter cake on the wall of a wellbore penetrating a subterranean formation is disclosed. The method comprises employing an apparatus, such as for example the apparatus of the invention with a filter medium and the capability of applying differential pressure or dynamic conditions to form a filter cake on the filter medium with drilling mud. Breaker fluid is then substituted for the drilling mud, preferably without damage to the filter cake. The quantity of breaker fluid passing across the filter medium under static conditions is monitored over time. An increase in the rate of fluid passing across or through the medium indicates break-up of the filter cake.

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Duncan, OK, United States of America

Brad Todd