Questair Technologies Inc.

G4 Insights Inc.

Xebec Adsorption Inc.

Other

Questor Industries Inc.

Air Products and Chemicals, Inc.

The Boc Group, Inc.

Questair Technology, Inc.

Quest Air Gases Inc.

Sofinoy Societte Financiere D'innovation Inc.

Seagold Industries Corporation

Bowie Gordon Keefer

Matthew L Babicki

Christopher R McLean

Brian G Sellars

Denis J Connor

David G Doman

Surajit Roy

Edson Ng

James A Sawada

Andrea C Gibbs

Alain Carel

Belinda C Larisch

Aaron M Pelman

Carl F Hunter

Michael J Brown

Frank R Fitch

Shanna Denine Knights

Jean St-Pierre

Erik Paul Johannes

Bernard H Hetzler

Kevin A Kaupert

Ian S D Shaw

Ian Shaw

Les Jeziorowski

David George Doman

Frederick K Lee

Alberto I LaCava

Steven Mitchell Kuznicki

Alan Otto Lebeck

Soheil Alizadeh-Khiavi

Christopher Gordon Stoner

Edward J Rode

Amy E Nelson

Michael Jamie McKerrow

Mark H Kirby

Alberto I IaCava

Andre Jason Joseph Boulet

David E Foster

Daniel K Mather

Todd Smith

Ian Spencer Parker

Marie-Claude Taponat

Kevin Arnold Kaupert

Michel P LeBlanc

Andre J J Boulet

Xiang Lu Kong

David G Dornan

Alan O Lebeck

Christopher R Mclean

Ian S Parker

Alberto I Lacava

Andre J Boulet

Steven M Kuznicki

Michael J Mckerrow

Alain A Carel

Doman David G G

Erik P Johannes

Disclosed embodiments provide a system and method for producing hydrocarbons from biomass. Certain embodiments of the method are particularly useful for producing substitute natural gas from forestry residues. Certain disclosed embodiments of the method convert a biomass feedstock into a product hydrocarbon by hydropyrolysis. Catalytic conversion of the resulting pyrolysis gas to the product hydrocarbon and carbon dioxide occurs in the presence of hydrogen and steam over a COsorbent with simultaneous generation of the required hydrogen by reaction with steam. A gas separator purifies product methane, while forcing recycle of internally generated hydrogen to obtain high conversion of the biomass feedstock to the desired hydrocarbon product. While methane is a preferred hydrocarbon product, liquid hydrocarbon products also can be delivered.

Sorption enhanced methanation of biomass

The present invention provides a system and method for producing hydrocarbons from biomass. The method is particularly useful for producing substitute natural gas from forestry residues. Certain disclosed embodiments convert a biomass feedstock into a product hydrocarbon by fast pyrolysis. The resulting pyrolysis gas is converted to the product hydrocarbon and carbon dioxide in the presence of hydrogen and steam while simultaneously generating the required hydrogen by reaction with steam under prescribed conditions for self-sufficiency of hydrogen. Methane is a preferred hydrocarbon product. A system also is disclosed for cycling the catalyst between steam reforming, methanation and regeneration zones.

Method and system for biomass hydrogasification

Certain aspects of the system and method concern producing hydrocarbons from biomass. The method is particularly useful for producing substitute natural gas from forestry residues. A biomass feedstock may be converted into a product hydrocarbon by fast pyrolysis. The resulting pyrolysis gas is converted to the product hydrocarbon and carbon dioxide in the presence of hydrogen and steam while simultaneously generating the required hydrogen by reaction with steam under prescribed conditions for self-sufficiency of hydrogen. Methane is a preferred hydrocarbon product. A system also is described for cycling the catalyst between steam reforming, methanation and regeneration zones.

A method for converting lignocellulosic biomass to a useful fuel is disclosed in a process sequence resulting in low levels of depositable tars in an output gas stream. One disclosed embodiment comprises performing a sequence of steps at elevated pressure and elevated hydrogen partial pressure, including fast (or flash) hydropyrolysis of a lignocellulosic biomass feed followed sequentially with catalytically enhanced reactions for the formation of methane operating at moderate temperatures of from about 400&#xb0; C. to about 650&#xb0; C. under moderately elevated pressure (about 5 atm to about 50 atm). A temperature rise in the catalyst above pyrolysis temperature is achieved without the addition of air or oxygen. Gas residence time at elevated temperature downstream of methane formation zones extends beyond the time required for methane formation. This sequence results in low tar deposit levels. The catalyst promotes preferential formation of methane and non-deposit forming hydrocarbons, and coke re-gasification.

Method of hydrogasification of biomass to methane with low depositable tars

A typical rotary face seal employs a seal ring rotating relative to a sealing surface and also employs means to urge the seal ring towards the sealing surface in order to effect a seal. The seal ring may itself comprise a seal face bonded to a backing ring. In certain applications, the seal face may deform significantly as a result of the temperature variations experienced and an undesirable crowning of the seal face may occur. Such crowning may be reduced by employing an improved seal ring with anti-crowning features in which the thickness of an edge of the seal face is different from that in the middle of the seal face, or in which a relief slot is employed in the seal face. The improved seal ring is particularly suited for rotary face seals used in a rotary valve in a rotary gas separation device.

Rotary face seal with anti-crowning features

A system and method for converting biomass into fluid hydrocarbon products to minimize the use of fossil fuels, provide energy and chemical feedstock security, and sustainable and/or carbon neutral electric power, are disclosed. For example, fast pyrolysis can be performed on biomass to produce pygas and char using a maximum processing temperature of about 650&#xb0; C. The pygas is provided to an independent reactor without the addition of an oxidizing agent for catalytically converting the pygas to hydrocarbons using a maximum processing temperature of about 650&#xb0; C. A system comprising fast pyrolysis means producing a pygas and char, independent catalytic conversion means downstream of the fast pyrolysis for converting the pygas to hydrocarbons, and a hydrogen source, external to the system and/or produced by a steam reformer by steam reformation of at least a portion of the hydrocarbons, coupled to catalytic conversion means, also are described.

Process and system for thermochemical conversion of biomass

Embodiments of a thermochemical method to convert lignocellulosic biomass to a useful fuel are disclosed in a process sequence resulting in low levels of depositable tars in the output gas stream. One disclosed embodiment comprises performing a sequence of steps at elevated pressure and elevated hydrogen partial pressure, including fast (or flash) hydropyrolysis of a lignocellulosic biomass feed followed sequentially with catalytically enhanced reactions for the formation of methane operating at moderate temperatures of from about 400&#xb0; C. to about 650&#xb0; C. and under moderately elevated pressure (about 5 atm to about 50 atm). A temperature rise in the catalyst above pyrolysis temperature is achieved without the addition of air or oxygen. Gas residence time at elevated temperature downstream of methane formation zones is extended well beyond the time required for methane formation. This sequence results in low depositable tars in the output gas stream.

Power plant systems and processes are described that enable recovery of at least a portion of the fuel storage energy associated with a storage system for supplying fuel to the power plant systems. A first embodiment of an energy-recovery power plant system includes at least one fuel storage container and at least one expander that can receive fuel from the fuel storage container at a first pressure and provide the fuel to the power plant at a second pressure that is lower than the first pressure. A second embodiment of an energy-recovery power plant system includes a first conduit fluidly coupling the fuel storage container and the power plant for delivering fuel from the fuel storage container to the power plant and at least one regenerative thermodynamic cycle engine thermally coupled to the first conduit such that heat may be exchanged between the fuel and a working fluid for the regenerative thermodynamic cycle engine.

Power plant with energy recovery from fuel storage

Using zeolites as the active adsorbent, adsorbent laminates have been fabricated with various sheet supports. These adsorbent laminates have been successfully operated for oxygen enrichment at high PSA cycle frequencies, such as upwards of at least 150 cycles per minute. Methods for making suitable adsorbent laminates are described. The methods generally involve forming a slurry comprising a liquid suspending agent, an adsorbent and a binder. Laminates are made by applying the slurry to support material or admixing support material with the slurry. The slurry can be applied to support material using a variety of techniques, including roll coaters, split roll coaters, electrophoretic deposition, etc. One method for making laminates by mixing support material with the adsorbent slurry comprises depositing the slurry onto a foraminous wire, draining the slurry material, and pressing the material to form a ceramic adsorbent paper. Spacers can be formed on adsorbent laminates to space one laminate from another. The spacer dimensions can be uniform, or can vary along a laminate, such as increasing in height from a first end to a second end of the laminate. Gas flow-through apertures also can be formed on laminates. The laminates are adjacent one another to define flow channel between adjacent bodies, whereby a portion of a gas flowing through the flow channels flows through the apertures to facilitate pressure equalization in the adsorbent structure.

Adsorbent coating compositions, laminates and adsorber elements

An electrical generating system consists of a fuel cell, and an oxygen gas delivery. The fuel cell includes and anode channel having an anode gas inlet for receiving a supply of hydrogen gas, a cathode channel having a cathode gas inlet and a cathode gas outlet, and an electrolyte in communication with the anode and cathode channel for facilitating ion exchange between the anode and cathode channel. The oxygen gas delivery system is coupled to the cathode gas inlet and delivers oxygen gas to the cathode channel. The electrical current generating system also includes gas recirculation means couple to the cathode gas outlet for recirculating a portion of cathode exhaust gas exhausted from the cathode gas outlet to the cathode gas inlet.

System that includes a fuel cell and an oxygen gas delivery system

A chemical reaction is performed with separation of the product(s) and reactant(s) by pressure swing adsorption (PSA), using an apparatus having a plurality of adsorbers cooperating with first and second valve assemblies in a PSA module. The PSA cycle is characterized by multiple intermediate pressure levels between higher and lower pressures of the PSA cycle. Gas flows enter or exit the PSA module at the intermediate pressure levels as well as the higher and lower pressure levels, entering from compressor stage(s) or exiting into exhauster or expander stages, under substantially steady conditions of flow and pressure. The PSA module comprises a rotor containing the adsorbers and rotating within a stator, with ported valve faces between the rotor and stator to control the timing of the flows entering or exiting the adsorbers in the rotor. The reaction may be performed within a portion of the rotor containing a catalyst.

Chemical reactor with pressure swing adsorption

A process and system for providing a hydrogen-containing gas stream to a fuel cell anode that includes providing a hydrogen-containing gas stream that includes carbon monoxide, introducing the hydrogen-containing gas stream into a pressure swing adsorption module that includes at least one carbon monoxide-selective adsorbent to produce a purified hydrogen-containing gas stream, and introducing the purified hydrogen-containing gas stream to the fuel cell anode. The pressure swing adsorption module can also include a second adsorbent and/or catalyst. Also disclosed is a fuel cell system coupled to an internal combustion engine and a fuel cell system that utilizes fuel cell waste heat for vaporizing a hydrocarbon/water mixture.

Systems and processes for providing hydrogen to fuel cells

Improved adsorbent sheet based parallel passage adsorbent structures for enhancing the kinetic selectivity of certain kinetic-controlled adsorption processes, such as PSA, TSA and PPSA processes, and combinations thereof, are provided. The enhancements in kinetic selectivity made possible through the implementation of the present inventive improved adsorbent structures may unexpectedly enable significant intensification of selected kinetic adsorption processes relative to attainable performance with conventional adsorbent materials in beaded or extruded form. Such process intensification enabled by the present inventive adsorbent structures may provide for increased adsorption cycle frequencies, and increased gas flow velocities within the adsorbent beds, which may increase the productivity and/or recovery of a kinetic adsorption system incorporating the inventive adsorbent structures.

Engineered adsorbent structures for kinetic separation

Enhanced high temperature fuel cell systems, such as solid oxide fuel cell systems and molten carbonate fuel cell systems are disclosed. Embodiments of the disclosure include solid oxide and molten carbonate fuel cell systems incorporating gas separation apparati facilitating the recycle of hydrogen fuel from fuel cell anode exhaust for supply to the fuel cell anode inlet, such systems capable of improved power densities and efficiencies of operation. Further embodiments of the disclosure include solid oxide and molten carbonate fuel cell systems incorporating inventive combinations of anode materials conducive to combination with enriched hydrogen fuel. Other embodiments of the disclosure include gas separation apparati for providing enriched oxygen feed to the cathode inlet of solid oxide and molten carbonate fuel cells.

High efficiency load-following solid oxide fuel cell systems

The present disclosure relates to solid oxide fuel cells (SOFCs) exploiting gas separation devices in which a first gas mixture including components A (for example hydrogen) and B (for example carbon dioxide) is to be separated so that a first product of the separation is enriched in component A, while component B is mixed with a third gas component C (for example air, oxygen-enriched air or oxygen-depleted air) contained in a displacement purge stream to form a second gas mixture including components B and C, and with provision to prevent cross contamination of component C into the first product containing component A, or of component A into the second gas mixture containing component C. The invention may be applied to hydrogen (component A) enrichment from fuel cell anode exhaust, where dilute carbon dioxide (component B) is to be rejected such as to the atmosphere by purging with cathode exhaust oxygen-depleted air (as component C).

Hydrogen recycle for solid oxide fuel cell

Growing community of inventors

Vancouver, Canada

Bowie Gordon Keefer