The Dow Chemical Company

Bobby R Ezzell

William P Carl

William A Mod

David A Babb

Katherine S Clement

Marius W Sorenson

W Frank Richey

Harry S Burney

Robert A Cipriano

John R Pimlott

Charles W Martin

Nobuyuki Ishibe

John D Weaver

Fred A Sherrod

Kevin P Darst

Wanda W Golding

Jacquelyn M Malone

Process for preparing a 2,3-dihaloperfluoropropionyl halide wherein an alkali metal chloride, bromide or iodide is contacted with a 3-haloperfluoropropene oxide in admixture in an inert liquid reaction medium.

Preparation of a 2,3-dihaloperfluorocarbonyl halide

A process for preparing a polymer having perfluorocyclobutane rings by the steps of (a) contacting monomers having aromatic polyester, aromatic polyamide, or polyimide groups or combination thereof, at least two dimerizable perfluorovinyl groups; and (b) exposing the monomers to sufficient heat and for a sufficient time that a polymer containing perfluorocyclobutane rings is formed. Chain extending oligomers of polymers having poor processing characteristics by this process results in polymers which are more easily processed. For instance, perfluorocyclobutane groups formed in an extruder to chain lengthen polyimide oligomers, in effect, render polyimides extrudable. The polymer formed by the method preferably has polyimide groups. New monomers and polymers having imide and perfluorovinyl or perfluorocyclobutane structures, respectively, are prepared.

Perfluorocyclobutane ring-containing polymers

Novel compounds have at least one perfluorocyclobutane ring and at least two functional groups suitable for forming condensation polymers. Preferably the compounds have a structures represented by Formula II: ##STR1## wherein R and R' independently represent optionally inertly substituted groups: X and X' represent any molecular structures which link R and R' with the perfluorocyclobutane ring; n and n' are the number of G and G' groups, respectively: and G and G' independently represent any reactive functional groups or any groups convertible into reactive functional groups. The compounds are preferably prepared by a process of thermally dimerizing trifluorovinyl compound to form a compounds of Formula I

Reactive compounds containing perfluorocyclobutane rings

A compound having at least one perfluorovinyl group and at least one functional group is suitable for reacting with and/or forming polymers. The compound is preferably of Formula I:

Reactive compounds containing perfluorovinyl groups

Compounds have a structure represented by Formula I:

Perfluorovinyl compounds

The present invention is a process for preparing a polymer having perfluorocyclobutane rings by the steps of (a) contacting monomers having at least two dimerizable perfluorovinyl groups; and (b) exposing the monomers to sufficient heat and for a sufficient time that a polymer containing perfluorocyclobutane rings is formed wherein at least about 0.05 mole percent of the monomer, have at least 3 dimerizable perfluorovinyl groups and polymers prepared thereby.

A process for preparing a polymer having perfluorocyclobutane rings by the steps of (a) contacting monomers having at least two dimerizable perfluorovinyl groups; and (b) exposing the monomers to sufficient heat and for a sufficient time that a polymer containing perfluorocyclobutane rings is formed. The invention includes polymers having a backbone comprising hydrocarbyl groups, perfluorocyclobutane rings and non-carbon atoms and polymers of at least 10,000 molecular weight having repeating units [O-(CFR.sub.f).sub.n -O-perfluorocyclobutane].

Novel compounds have at least one perfluorocyclobutane ring and at least two functional groups suitable for forming condensation polymers. Preferably the compounds have a structures represented by Formula II: ##STR1## wherein R and R' independently represent optionally inertly substituted groups; X and X' represent any molecular structures which link R and R' with the perfluorocyclobutane ring; n and n' are the number of G and G' groups, respectively; and G and G' independently represent any reactive functional groups or any groups convertible into reactive functional groups. The compound are preferably prepared by a process of thermally dimerizing trifluorovinyl compound to form a compounds of Formula I

The invention is a sulfonic fluoropolymer having a fluoropolymer backbone having pendant groups attached thereto and represented by the general formula:

Low equivalent weight sulfonic fluoropolymers

A composite comprising a functional fluoropolymer having pendant groups which terminate with a second reacting group and a first substrate having a first reacting groups, wherein at least a portion of the first reacting groups and at least a portion of the second reacting groups have reacted with each other to form covalent or ionic bonds.

Reactive bonding method

Novel vinyl ethers are prepared in decarboxylation reactions of novel acid fluoride compounds according to the following reaction: ##STR1## wherein a is 0 or an integer greater than 0;

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Lake Jackson, TX, United States of America

Bobby R Ezzell