Xerox Corporation

3d Systems, Inc.

Bo Wu

Jule W Thomas, Jr

Jeffrey H Banning

Donald R Titterington

Jeffery H Banning

James McConnell Duff

Randall Ray Bridgeman

Stephan V Drappel

Trevor James Snyder

Rina Carlini

Wolfgang G Wedler

James Daniel Mayo

Patricia A Wang

Mark Raymond Parker

C Wayne Jaeger

Michael B Meinhardt

Nathan G Starr

C Geoffrey Allen

David Lyell Knierim

Paul Farrell Smith

Pingyong Xu

Steven V Korol

Jennifer Misae Miyamoto

Amy R Bartlett

Guerino G Sacripante

Gabriel Iftime

Raymond W Wong

Andrew V Hill

Christopher A Wagner

Kelley A Moore

Jian Yao

Paul Christopher Lucas

Mark Harris Tennant

Mary Ryan-Hotchkiss

Jesus Gonzalez, Jr

Harold R Frame

Don Titterington

Jeffrey Banning

Andrew W Hill

Jule W Thomas

John Brookfield

Mark H Tennant

Jr Jule W Thomas

Jule W Thomas Jr

Wayne C Jaeger

In one aspect, waxy build material inks are described herein which, in some embodiments, exhibit desirable print quality and associated mechanical properties for three-dimensional printing applications. A build material ink, in some embodiments, comprises 20-40 wt. % rosin component, 5-35 wt. % non-polar wax component, and 40-65 wt. % alcohol wax component comprising one or more waxes of the formula (CH)OH wherein n is an integer from 15 to 40. In another aspect, a build material ink comprises a eutectic mixture including rosin component, a non-polar wax component, and an alcohol wax component comprising one or more waxes of the formula (CH)OH wherein n is an integer from 15 to 40.

Waxy build materials for three-dimensional printing applications

Water dispersible support materials for use with a three-dimensional printing system are described herein. In some embodiments, a support material described herein comprises a phase change wax component and an ethoxylated polyethylene having the formula H—(CH)—(OCHCH)—OH, wherein m is an integer from 22 to 60 and n is an integer from 2 to 200. In some cases, the phase change wax component and the ethoxylated polyethylene are each present in the support material in an amount of 20-80% by weight.

Water dispersible support materials for 3D printing

In one aspect, build materials and support materials for use with a 3D printer are described herein. Such materials include a phosphor component in combination with other components. In some embodiments, the phosphor component of a build material or support material is present in the material in an amount of 0.001-0.5 wt. % and has a peak photoluminescence (PL) emission wavelength of 430-750 nm and a photoluminescence quantum yield (QY) of 0.10-1.

3D printing build materials and support materials comprising a phosphor

In one aspect, urethane waxes are described herein comprising a reaction product between monofunctional polyethylene oxide and polyisocyanate. In some embodiments, the urethane waxes are combined with other components to provide support materials for use in three-dimensional printing applications. A support material ink, for example, comprises a urethane wax comprising a reaction product between monofunctional polyethylene oxide and polyisocyanate. The support material ink, in some embodiments, further comprises monomeric curable material, oligomeric curable material, or mixtures thereof.

Water soluble waxy support materials for three-dimensional printing applications

A method of manufacturing a three dimensional article includes forming the three-dimensional article with three-dimensional printing, processing the three-dimensional article to remove support material ink, illuminating the three-dimensional article with electromagnetic radiation, inspecting the three dimensional article for photoluminescence that is responsive to the illumination, and verifying whether the support material has been sufficiently removed based upon the inspection. The support material ink includes a phosphor component that phosphorescently emits light in response to the illumination.

Method of verifying integrity of a post-process removal of support material

A method manufacturing a three-dimensional article having readable indicia includes three-dimensionally printing the article and post-processing that following the printing. The three-dimensional printing forms the three-dimensional article in a layer-by-layer manner. The resultant three-dimensional article includes an outer portion of build material defining a plurality of enclosed internal channels, an encapsulated support material containing a phosphor component defining the indicia disposed within the channels, and unencapsulated support material that provides structural support to otherwise unsupported portions of the build material during the three-dimensional printing. The post-processing removes the unencapsulated support material form the build material but leaves the encapsulated build material.

Three-dimensional article having permanent phosphor indicia formed from sacrificial support material

In one aspect, inks for use with a 3D printer are described herein. In some embodiments, an ink described herein comprises a cyclic carbonate monomer and an amine monomer. Further, in some instances, an ink described herein also comprises an ethylenically unsaturated monomer such as a (meth)acrylate. Additionally, an ink described herein, in some cases, further comprises a colorant, such as a molecular dye, a particulate inorganic pigment, or a particulate organic colorant. An ink described herein may also comprise one or more additives selected from the group consisting of inhibitors, stabilizing agents, photoinitiators, and photosensitizers.

Non-isocyanate polyurethane inks for 3D printing

In one aspect, water removable compositions are described herein, including for use in various printing applications. In some embodiments, a composition described herein comprises 50-95% by weight alcohol wax having the formula CH(CH)OH, wherein n is an integer from 15 to 40; 5-50% by weight tackifier; and 0.5-5% by weight colorant. In other instances, a composition described herein comprises 50-95% by weight carboxylic acid wax having the formula CH(CH)COOH, wherein m is an integer from 14 to 40; 5-50% by weight tackifier; and 0.5-5% by weight colorant. Additionally, in some cases, the tackifier of a composition described herein comprises a rosin acid, a rosin ester, a rosin alcohol, or a mixture or combination thereof. Further, the solubility of a colorant in a composition described herein can be characterized by a spectral strength delta value of 5% or less or 3% or less.

Water removable compositions and applications thereof

Phase change ink compositions having a phase change carrier composition containing a wax and a wax-soluble near-infrared (NIR) dye having an absorption maximum in the wavelength region from about 700 nm to about 1400 nm. Near-infrared prints prepared with such phase change ink compositions. Methods of producing a layer of such a phase change ink on the surface of a substrate.

Phase change inks containing wax-soluble near-infrared dyes

In one aspect, methods of printing a three-dimensional article are described herein. In some embodiments, a method described herein comprises jetting an ink at a temperature T1 onto a substrate at a temperature T2 to form a layer of the ink on the substrate. The method further comprises subsequently curing the layer of the ink. In some embodiments, T1 is greater than T2 and the ink in an uncured state has a liquid-gel transition temperature below T1 and above T2. Further, the layer of the ink is deposited on the substrate at a rate R1 in mg/s/inthat is within 60% of a gelation rate R2 of the ink in inverse minutes in an uncured state at T2. The ink can comprise a curable material and a gellant.

Inks comprising gellants for 3D printing

A phase change ink composition for printing on ophthalmic lenses including a straight chain hydrocarbon wax and a branched hydrocarbon wax; an amide, wherein the amide is present in an amount of greater than about 25 percent by weight based on the total weight of the ink composition; a rosin ester; and a colorant. A phase change ink composition for printing on ophthalmic lenses including a straight chain hydrocarbon wax and a branched hydrocarbon wax; an amide, wherein the amide comprises a combination of at least two members of the group consisting of monoamide, triamide, and tetra-amide; a rosin ester; and a colorant. An ink jet printer stick or pellet comprising the phase change ink composition.

Phase change ink for ophthalmic lens marking

The present disclosure provides an encapsulated dye dispersion and an inkjet ink comprising an ink vehicle and an encapsulated dye dispersion thereof. In particular, the encapsulated dye dispersion includes a fluorescent and/or photochromic dye. The present disclosure also provides a process for producing the encapsulated dye dispersion.

Encapsulated fluorescent and photochromic dye polyurethane dispersion

Growing community of inventors

Wilsonville, OR, United States of America

Bo Wu