Lanxide Technology Company, LP

Other

Birol Sonuparlak

Christopher R Kennedy

John E Garnier

Ali S Fareed

Gerhard H Schiroky

Michael K Aghajanian

Dennis James Landini

Kenneth S Hatton

Sylvia J Canino

William B Johnson

Virgil Irick, Jr

Aspi N Patel

Ali Syed Fareed

Dennis J Landini

Gerhard Hans Schiroky

The present invention generally relates to mechanisms for preventing undesirable oxidation (i.e., oxidation protection mechanisms) in composite bodies. The oxidation protection mechanisms include getterer materials which are added to the composite body which gather or scavenge undesirable oxidants which may enter the composite body. The getterer materials may be placed into at least a portion of the composite body such that any undesirable oxidant approaching, for example, a fiber reinforcement, would be scavenged by (e.g., reacted with) the getterer. The getterer materials) may form at least one compound which acts as a passivation layer, and/or is able to move by bulk transport (e.g., by viscous flow as a glassy material) to a crack, and sealing the crack, thereby further enhancing the oxidation protection of the composite body. One or more ceramic filler materials which serve as reinforcements may have a plurality of super-imposed coatings thereon, at least one of which coatings may function as or contain an oxidation protection mechanism. Specifically, a coating comprising boron nitride which has been engineered or modified to contain some silicon exhibits improved corrosion resistance, specifically to oxygen and moisture. The coated materials may be useful as reinforcing materials in high performance composites to provide improved mechanical properties such as fracture toughness. The present invention also relates to improved composites which incorporate these materials, and to their methods of manufacture.

Composite materials comprising two jonal functions and methods for making the same

Coated ceramic filler materials comprised of ceramic particles, fibers, whiskers, etc. having at least two substantially continuous coatings thereon are provided. The coatings are selected so that the interfacial shear strength between the ceramic filler material and the first coating, between coatings, or between the outer coating and the surrounding matrix material, are not equal so as to permit debonding and pull-our when fracture occurs. The resultant, multi-coated ceramic filler materials may be employed to provide composites, especially ceramic matrix composites, with increased fracture toughness. The ceramic filler materials are designed to be particularly compatible with ceramic matrices formed by directed oxidation of precursor metals, but such ceramic filler materials are also adaptable for use in many other composite material systems. In a preferred embodiment, the coatings are applied to the ceramic fiber plies or preforms by CVD. Accordingly, coating depositions which are more uniform through the preform cross-section have been achieved by assembling the preform with exterior fabric plies having greater gas permeability than the fibrous preform or fabric plies located deeper in the preform interior. In another preferred embodiment, at least one additional filler material different in some respect from a first fibrous filler material is provided to the permeable mass to be infiltrated with matrix material. Specifically, the additional filler material is provided for the purpose of tailoring at least one additional property of the self-supporting composite body to be formed not already tailored by the first fibrous filler material.

Composite materials and methods for making the same

The present invention generally relates to mechanisms for preventing undesirable oxidation (i.e., oxidation protection mechanisms) of reinforcement materials in composite bodies. In a preferred embodiment of the invention, a coated ceramic filler material adaptable for use as a reinforcing component in a ceramic matrix composite is provided with a plurality of superimposed coatings. The coating system includes a first coating in substantially continuous contact with the ceramic filler material and one or more additional or outer coatings superimposed over the underlying coating and in substantially continuous contact therewith. Zonal junctions are formed between the filler and the first coating, between superimposed coatings, and between the outer coating and the ceramic matrix. The coatings are selected so that the interfacial shear strength of at least one of these several zones is weak relative to the other zones. Upon the application of fracture stress to the composite, the weak zone allows for debonding of the filler before the filler fractures, and pull-out or shear of the filler upon fracture of the filler. This debonding and friction pull-out enhances certain mechanical properties of the composite, and in particular, debonding improves the fracture toughness.

The present invention generally relates to mechanisms for preventing undesirable oxidation (i.e., oxidation protection mechanisms) of reinforcement materials in composite bodies. The oxidation protection mechanisms include getterer materials which are added to the composite body which gather or scavenge undesirable oxidants which may enter the composite body. The getterer materials may be placed into at least a portion of the matrix such that any desirable oxidant approaching, for example, a fiber reinforcement, would be scavenged by (e.g., reacted with) the getterer. Ceramic filler materials which serve as reinforcements may have a plurality of super-imposed coatings thereon, at least one of which coatings may function as a getterer. The coated materials may be useful as reinforcing materials in ceramic matrix composites to provide improved mechanical properties such as fracture toughness. The present invention also relates to improved composites which incorporate these materials, and to their methods of manufacture.

The present invention relates to methods for producing self-supporting ceramic and ceramic composite bodies having a protective surface region on at least a portion of the surface of the formed bodies, and bodies produced thereby. The protective surface region is formed upon reaction of at least two components of the ceramic or ceramic composite body.

Method of making ceramic composite bodies having a protective surface

The present invention relates to a novel process for removal of at least a portion of at least one metallic component of a metallic constituent from a multi-phase composite body. Particularly, by providing at least one of an infiltration enhancer or an infiltration enhancer precursor or an infiltrating atmosphere to be in communication with a permeable mass, which contacts at least a portion of a composite body, said metallic component of the composite body, when made molten, is caused to spontaneously infiltrate the permeable mass. Such spontaneous infiltration occurs without the requirement for the application of any pressure or vacuum. The metallic constituent is essentially leached or removed from the multi-phase body by spontaneous infiltration.

Removing metal from composite bodies and resulting products

The present invention relates to methods for producing self-supporting ceramic and ceramic composite bodies having a protective surface region on at least a portion of the surface of the formed bodies, and bodies produced thereby.

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Newark, DE, United States of America

Birol Sonuparlak