Ashland Oil, Inc.

The Ohio State University

Sherex Chemical Company, Inc.

Ashland Chemical Company

Billy M Culbertson

Omar Tiba

Larry K Post

Timothy A Tufts

Ann E Aulabaugh

Anil B Goel

Donald D Carlos

Marvin L Deviney, Jr

Theodore C Wilkinson

Gilbert M Gynn

Curtis Michael Graham

Dan Borgnaes

Elizabeth C Kao

Hans R Gabriel

Glass ionomer cements for dental restoratives with improved physical properties are produced by the present invention. Acryloyl and methacryloyl derivatives of amino acids are used in the invention to copolymerize with acrylic acid, methacrylic acid or various acrylic acid-comonomer mixtures to produce water soluble polycarboxylic acids.

Water soluble polymers containing amino acid residues for dental

A process for preparing a polymeric composition comprising reacting a mixture of at least one phenolic compound and at least one oxazoline compound in the presence of a catalytic amount of at least one ammonium salt and a tetracarbyl phosphonium salt, and optionally also in the presence of an alkyl halide is described.

Preparation of resins from phenolic compounds and oxazolines using

Thermoset resinous molding compositions are provided by essentially instantaneously combining and reacting three basic resin forming components. The latter include an oligomeric ester or polyester containing polymerizable unsaturation and free hydroxyl group(s); a polyisocyanate; and an aromatic polyamine. The indicated thermosetting resin systems are especially adapted for use in a reaction injection molding (RIM) operation.

Thermoset resinous molding compositions

Compositions have melting points below 100.degree. C. which are useful in the formation of resins by reaction with polyphenolic compounds consisting of a mixture of more than two compounds having the formula ##STR1## wherein A represents a cyclic or acyclic aliphatic or substituted cyclic or acyclic aliphatic moiety having from 1 to 20 carbon atoms or an aromatic mono- or multi-nuclear or aliphatic substituted aryl residue having from 6 to 20 carbon atoms,

Liquid aromatic bisoxazoline and disoxazine monomer mixtures cured with

A polymerizable thermosetting composition which is a flowable liquid at moderate temperatures which comprises a mixture of:

Thermosetting bis oxazoline-polyphenol based resins for resin transfer

The formation of structural composites having low smoke release and low heat release properties by forming a sandwich comprising a non-woven fiber mat between woven glass fiber mats and impregnating said sandwich with a mixture of a bisoxazoline and a polyphenolic compound to form a prepreg which can be formed and molded at elevated temperatures is described.

Low smoke and heat release glass fiber/carbon fiber/bisoxazoline resin

Compositions having melting points below 100.degree. C. which are useful in the formation of resins by reaction with polyphenolic compounds consisting of a mixture of more than two compounds having the formula ##STR1## wherein A represents a cyclic or acyclic aliphatic or substituted cyclic or acyclic aliphatic moiety having from 1 to 20 carbon atoms or an aromatic mono- or multi-nuclear or aliphatic substituted aryl residue having from 6 to 20 carbon atoms,

Liquid aromatic bisoxazoline and bisoxazine monomer mixtures and process

A process for the copolymerization of bis-2-oxazolines and polyphenolic compounds at greatly improved rates comprising carrying out the copolymerization in the presence of from about 0.5 to about 5% by weight of a phosphine catalyst is described.

Preparation of resin from phenolic and oxazoline using phosphine catalyst

The process for preparing a polymeric composition at improved rate comprising reacting an oxazoline compound and a phenolic compound in the presence of a catalytic amount of a phosphorous acid ester is described.

Resin from phenolic and oxazoline using phosphorous acid ester as

The disclosure is directed to thermoset resinous compositions having utility in the area of surface coating and molding applications, the latter including the preparation of high performance composites and the use in reaction injection molding processes. The contemplated compositions are obtained by polymerizing a reaction mixture comprising a polyfunctional 2-oxazoline compound, a compound or oligomer containing a plurality of aromatic hydroxyl groups and a polyfunctional epoxide.

Resinous molding compositions of a phenol, an oxazoline and an epoxy

Thermoplastic and thermoset polymeric compositions, having particular utility in the area of molding applications, are obtained by reacting a compound containing a plurality of oxazoline groups with a phenol or a phenolic resin each containing a plurality of aromatic hydroxyl groups.

Poly(ether-amide) polymeric compositions

A copolymer formed by reacting maleic anhydride or a maleimide or a mixture of these with an allylphenol, a methallylphenol, or substituted allyl or methallylphenol. The anhydride polymers are characterized as having a 1:1 molar ratio of maleic anhydride to phenol or substituted phenol. The maleic anhydride copolymers are water soluble materials, useful as epoxy resin modifiers and curatives, as ion exchange resins or membranes, laminates, and detergent additives and builders. The maleimide containing copolymers are also useful as epoxy resin modifiers and useful in the production of laminates, composites and coatings.

Polymers derived from allylphenol or substituted allylphenol and maleic

Copolymers and terpolymers formed by reacting either 4,7-dihydro-1,3-dioxepins or 6,7-dihydro-1,3-dioxepins with maleic anhydride and/or a maleimide. The copolymers are characterized as linear, low molecular weight, water soluble alternating copolymers. These copolymers are useful as a water soluble polymer, as epoxy resin modifies and curing agents. The copolymers formed from 4,7-dihydro-1,3-dioxepins and maleic anhydride can be rearranged to form a poly (.gamma.-crotonlactone) having the following general formula: ##STR1##

Copolymers derived from 1,3 dioxepins and maleic anhydride or maleimides

A novel polymer comprising the reaction product of a first vinyl monomer and a second vinyl monomer which is an alkenyl succinic anhydride having the formula: ##STR1## These polymers are useful as epoxy curatives, boiler scale removers, detergent builders, thickeners and coatings.

Anhydride containing polymers derived from alkenyl succinic anhydride

Pressure-sensitive adhesives having improved cohesive strength are formed by reacting an acrylic interpolymer with a metal alkoxide or chelated metal alkoxide such as a chelated ester of orthotitanic acid. The novel feature of this invention comprises the use of an interpolymer containing a vinyl monomer which contains both a carboxylic acid and a carbamate functional group.

Growing community of inventors

Worthington, OH, United States of America

Billy M Culbertson