L'air Liquide, Soci&#xe9;t&#xe9; Anonyme Pour L'etude Et L'exploitation Des Proc&#xe9;d&#xe9;s Georges Claude

Bertrand Demolliens

Antoine Hernandez

Jean-Marc Tsevery

Jean-Marc Peyron

Jean-Marc Bernhardt

Xavier Traversac

Guillaume Teixeira

Herve Le Bihan

Delphine Pichot

Rawia Ali Said

Manon Cortale

Hervé Le Bihan

In a process for the separation of a mixture containing hydrogen and carbon monoxide to produce gaseous hydrogen, the mixture is cooled down to a temperature below −180° C. and then separated at a temperature below −100° C. to produce a gas enriched in hydrogen and a fluid enriched in carbon monoxide, at least a part of the gas enriched in hydrogen is sent to a pressure swing adsorption separation apparatus operating at a temperature above 0° C. to produce a gas rich in hydrogen at a pressure of at least 20 bars, and at least a part of the gas rich in hydrogen is cooled in the heat exchanger down to a temperature below −100° C., reduced in pressure in a turbine down to a pressure of at least 8 bars and reheated in the heat exchanger to constitute a product rich in hydrogen at a pressure of at least 8 bars.

Process and apparatus for the separation of a mixture of hydrogen and carbon monoxide at low temperature

In a process of the separation of a mixture of carbon monoxide, hydrogen and methane, the mixture is sent to a scrubbing column, a bottom liquid withdrawn at the bottom of the scrubbing column is depleted in hydrogen with respect to the mixture and is sent to a stripping column, a bottom liquid from the stripping column is sent to a separation column and a liquid enriched in methane withdrawn from the bottom of the separation column is vaporized in order to form a final product.

Process and apparatus for the cryogenic separation of a mixture of carbon monoxide, hydrogen and methane for the production of CH4

Process for the combined production of a mixture of hydrogen and nitrogen, and of carbon monoxide by cryogenic distillation and cryogenic scrubbing, wherein a methane-rich liquid is introduced at a first intermediate level of a scrubbing column as first scrubbing liquid and at least one nitrogen-rich liquid is introduced at a level higher than the first level of the scrubbing column as second scrubbing liquid and a mixture of hydrogen and nitrogen is drawn off as overhead gas from the scrubbing column.

Process and plant for the combination production of a mixture of hydrogen and nitrogen and also of carbon monoxide by cryogenic distillation and cryogenic scrubbing

In a method for separating a synthesis gas containing carbon monoxide and hydrogen, a synthesis gas flow from a synthesis gas source is compressed in a compressor and separated into at least three gaseous products. If there is insufficient synthesis gas, at least three separation products are recycled in the compressor in order to separate said products.

Method and apparatus for separating a synthesis gas

The invention relates to a facility for producing liquid helium from a source gas mixture substantially comprising nitrogen and helium. The facility includes a cryogenic purifier including a system for separating the nitrogen from the source gas mixture with a view to producing helium at a temperature lower than the temperature of the source gas. The facility also includes a helium liquefier that subjects the helium to a work cycle including, in series: compressing the helium, cooling and decompressing the compressed helium, and reheating the cooled, decompressed helium. The facility includes a helium transfer pipe connecting an outlet of the purifier to an inlet of the liquefier in order to transfer helium produced by the purifier into the work cycle of the liquefier. The facility is characterized in that the cryogenic purifier includes a decompression system that includes an inlet to be connected to a source of pressurized nitrogen gas. Said system for decompressing the nitrogen gas exchanges heat with the separation system in order to transfer cold from the decompressed nitrogen gas to said separation system.

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Paris, France

Bertrand Demolliens